4,4'-([1,1'-biphenyl]-4,4'-diylbis((4-formylphenyl)azanediyl))bis(2-methylbenzaldehyde) | 1204829-14-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4'-([1,1'-biphenyl]-4,4'-diylbis((4-formylphenyl)azanediyl))bis(2-methylbenzaldehyde)
• 英文别名: 4-(4-formyl-N-[4-[4-(4-formyl-N-(4-formyl-3-methylphenyl)anilino)phenyl]phenyl]anilino)-2-methylbenzaldehyde
• CAS: 1204829-14-0
• 化学式: C₄₂H₃₂N₂O₄
• 分子量: 628.727
• InChiKey: GILXZKKZQTWFJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  48
• 可旋转键数：
  11
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-[N,N'-di-(p-tolyl)amino]benzyl(triphenyl)phosphonium bromide 、 4,4'-([1,1'-biphenyl]-4,4'-diylbis((4-formylphenyl)azanediyl))bis(2-methylbenzaldehyde) 在 potassium tert-butylate 、 碘 作用下， 以 四氢呋喃 为溶剂， 反应 8.0h， 以69%的产率得到N,N-di(phenyl)-N',N'-di(4-(4-N,N-di(4-(4-methoxyphenyl)amino)phenyl)ethenyl)-1,1'-biphenyl-4,4'-diamine
  参考文献：
  名称：

  不含钙的低成本分子“蜂”空穴传输材料，用于高效，稳定的钙钛矿太阳能电池

  摘要：

  随着钙钛矿太阳能电池（PSC）的功率转换效率（PCE）的迅猛发展，器件的使用寿命引起了广泛的研究兴趣和关注。为了提高器件的耐用性，开发高性能的无掺杂空穴传输材料（HTM）是一种有前途的策略。这里，用三个新HTMS Ñ，Ñ N'-二苯基Ñ，Ñ ' -二（米-甲苯基）联苯胺（TPD）的核心：TPD-4MeTPA，TPD-4MeOTPA和TPD-4EtCz被设计并合成，表现出合适的能量水平和优异的成膜性能。基于原始TPD-4MeOTPA， PCE达到15.28％作为HTM，它比p掺杂的2,2'，7,7'-四（-N，N-二-4-甲氧基苯基氨基）-9,9'-螺双芴（螺-OMeTAD ）的设备（17.26％）。重要的是，与基于螺旋-OMeTAD的设备相比，基于新HTM的设备在黑暗中相对湿度为30％的环境空气中老化时，显示出相对更高的稳定性。

  DOI：

  10.1039/c7tc03931j
• 作为产物：
  描述：

  1-[2-[4-[4-[4-[4-[1,3-bis(2,2,2-trifluoroacetyl)-2H-imidazol-2-yl]-N-[4-[1,3-bis(2,2,2-trifluoroacetyl)-2H-imidazol-2-yl]-3-methylphenyl]anilino]phenyl]-N-[4-[1,3-bis(2,2,2-trifluoroacetyl)-2H-imidazol-2-yl]-3-methylphenyl]anilino]phenyl]-3-(2,2,2-trifluoroacetyl)-2H-imidazol-1-yl]-2,2,2-trifluoroethanone 在 盐酸 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以93%的产率得到4,4'-([1,1'-biphenyl]-4,4'-diylbis((4-formylphenyl)azanediyl))bis(2-methylbenzaldehyde)
  参考文献：
  名称：

  不含钙的低成本分子“蜂”空穴传输材料，用于高效，稳定的钙钛矿太阳能电池

  摘要：

  随着钙钛矿太阳能电池（PSC）的功率转换效率（PCE）的迅猛发展，器件的使用寿命引起了广泛的研究兴趣和关注。为了提高器件的耐用性，开发高性能的无掺杂空穴传输材料（HTM）是一种有前途的策略。这里，用三个新HTMS Ñ，Ñ N'-二苯基Ñ，Ñ ' -二（米-甲苯基）联苯胺（TPD）的核心：TPD-4MeTPA，TPD-4MeOTPA和TPD-4EtCz被设计并合成，表现出合适的能量水平和优异的成膜性能。基于原始TPD-4MeOTPA， PCE达到15.28％作为HTM，它比p掺杂的2,2'，7,7'-四（-N，N-二-4-甲氧基苯基氨基）-9,9'-螺双芴（螺-OMeTAD ）的设备（17.26％）。重要的是，与基于螺旋-OMeTAD的设备相比，基于新HTM的设备在黑暗中相对湿度为30％的环境空气中老化时，显示出相对更高的稳定性。

  DOI：

  10.1039/c7tc03931j

文献信息

• Electrophilic aromatic substitution with diacyl imidazolium
  申请人：Xerox Corporation

  公开号：US07652148B1

  公开（公告）日：2010-01-26

  Polyimidazoline molecules and methods of making them are provided. A representative polyimidazoline has a structure: wherein: X is trifluoroacetyl or trifluoromethanesulfonyl; R1, R2, and R3 are each independently selected from a hydrogen, C1-C4 alkyl, C3-C7 cyclic alkyl, C1-C4 alkoxy, alcohol, and halogen; and n is 1 to 3.

  提供了聚咪唑啉分子及其制备方法。代表性的聚咪唑啉具有以下结构：其中：X为三氟乙酰基或三氟甲磺酰基；R1、R2和R3分别独立选择自氢、C1-C4烷基、C3-C7环烷基、C1-C4烷氧基、醇基和卤素；n为1至3。
• THIOL GROUP-CONTAINING CHARGE TRANSPORTING MATERIAL, THIOL GROUP-CONTAINING CHARGE TRANSPORTING MATERIAL-DISSOLVING SOLUTION, PHOTOELECTRIC CONVERSION DEVICE, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, IMAGE FORMING APPARATUS, AND PROCESS CARTRIDGE
  申请人：NUKADA Katsumi

  公开号：US20120196215A1

  公开（公告）日：2012-08-02

  Provided is a thiol group-containing charge transporting material represented by the following general formula (1): F-[(G) a1 -(X) a2 —Y—SH] b (1) wherein F represents an organic group derived from a charge transporting compound, G represents a divalent organic group having 1 to 5 carbon atoms, X represents a group selected from a —CO—O— group, an —O—CO— group, and an —O— group, Y represents a divalent organic group having 1 to 5 carbon atoms, a1 and a2 each independently represent 0 or 1, and b represents an integer of 1 or more and 6 or less.
• FLUORINE-CONTAINING RESIN PARTICLE DISPERSION, METHOD FOR PREPARING FLUORINE-CONTAINING RESIN PARTICLE DISPERSION, COATING LIQUID WHICH CONTAINS FLUORINE-CONTAINING RESIN PARTICLES, METHOD FOR PREPARING COATING FILM WHICH CONTAINS FLUORINE-CONTAINING RESIN PARTICLES, COATING FILM WHICH CONTAINS FLUORINE-CONTAINING RESIN PARTICLES, MOLDED BODY, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, METHOD FOR PREPARING ELECTROPHOTOGRAPHIC PHOTORECEPTOR, IMAGE FORMING APPARATUS, AND PROCESS CARTRIDGE
  申请人：NUKADA Katsumi

  公开号：US20120231379A1

  公开（公告）日：2012-09-13

  Provided is a fluorine-containing resin particle dispersion including: fluorine-containing resin particles, a resin which is not dissolved in at least one solvent in a group of hydroxyl group-containing solvents including an alcohol-based solvent having 1 to 10 carbon atoms, containing no aromatic ring in the molecule structure, and a water-based medium, and which is adhered on the surface of the fluorine-containing resin particles, and at least one solvent, in which the resin is not dissolved, in the group of hydroxyl group-containing solvents, in which the fluorine-containing resin particles having the resin adhered on the surface thereof are dispersed.
• US7652148B1
  申请人：——

  公开号：US7652148B1

  公开（公告）日：2010-01-26
• US8748070B2
  申请人：——

  公开号：US8748070B2

  公开（公告）日：2014-06-10