di(chlorobenzyl) carbonate | 94026-30-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di(chlorobenzyl) carbonate
• 英文别名: chlorobenzyl carbonate；Bis[(2-chlorophenyl)methyl] carbonate
• CAS: 94026-30-9
• 化学式: C₁₅H₁₂Cl₂O₃
• 分子量: 311.164
• InChiKey: FTQAIYYLQQYODI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  di(chlorobenzyl) carbonate 、 L-苯丙氨酸甲酯盐酸盐 在 盐酸 、 碳酸氢钠 作用下， 生成 N-(苄氧羰基)-L-苯丙氨酸甲酯
  参考文献：
  名称：

  USE OF AEROGELS FOR PREPARING A MATERIAL FOR THERMAL INSULATION

  摘要：

  热隔离材料包括通过将公式（I）的伪肽链制备的有机凝胶干燥而得到的气凝胶。其中R代表氨基酸的侧链，R1代表（C1-C8）烷基，（C1-C8）烷氧基，芳基，芳氧基或糖苷基，n=1或2，A代表一个带有一个或多个环的芳基。

  公开号：

  US20120097884A1

文献信息

• PROCESS FOR PRODUCING ISOCYANATES USING DIARYL CARBONATE
  申请人：Shinohata Masaaki

  公开号：US20110054211A1

  公开（公告）日：2011-03-03

  An object of the present invention is to provide a process that enables isocyanate to be produced stably over a long period of time and at high yield without encountering problems of the prior art during production of isocyanate without using phosgene. The present invention provides an isocyanate production process including the steps of: obtaining a reaction mixture containing an aryl carbamate having an aryl group originating in a diaryl carbonate, an aromatic hydroxy compound originating in a diaryl carbonate, and a diaryl carbonate, by reacting a diaryl carbonate and an amine compound in the presence of a reaction solvent in the form of an aromatic hydroxy compound; transferring the reaction mixture to a thermal decomposition reaction vessel; and obtaining isocyanate by applying the aryl carbamate to a thermal decomposition reaction, wherein the reaction vessel in which the reaction between the diaryl carbonate and the amine compound is carried out and the thermal decomposition reaction vessel for the aryl carbamate are different.

  本发明的一个目的是提供一种能够在生产异氰酸酯时在长时间内稳定地且高产率地生产异氰酸酯的方法，而不使用光气时遇到先前技术问题的方法。本发明提供了一种异氰酸酯生产方法，包括以下步骤：通过在反应溶剂形式的芳香羟基化合物存在下，通过反应二芳基碳酸酯和胺化合物得到含有源自二芳基碳酸酯的芳基碳酸酯、源自二芳基碳酸酯的芳香羟基化合物和二芳基碳酸酯的反应混合物；将反应混合物转移至热分解反应容器；通过将芳基碳酸酯应用于热分解反应来获得异氰酸酯，其中进行二芳基碳酸酯和胺化合物之间的反应的反应容器和用于芳基碳酸酯的热分解反应的反应容器是不同的。
• INDUSTRIAL PROCESS FOR PRODUCTION OF HIGH-PURITY DIARYL CARBONATES
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1961731A1

  公开（公告）日：2008-08-27

  It is an object of the present invention to provide a specific process that enables a high-purity diaryl carbonate required for producing a high-quality high-performance aromatic polycarbonate to be produced industrially in a large amount (e.g. not less than 1 ton / hr) stably for a prolonged period of time (e.g. not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours) from a cyclic carbonate and an aromatic monohydroxy compound. When producing a high-purity diaryl carbonate from a cyclic carbonate and an aromatic monohydroxy compound, the above object can be attained by carrying out a process of the present invention which comprises the steps of: (I) producing a dialkyl carbonate and a diol using a reactive distillation column having a specified structure; (II) producing a diaryl carbonate using two reactive distillation columns each having a specified structure; and (III) purifying the diaryl carbonate so as to obtain a high-purity diaryl carbonate.

  本发明的目的是提供一种特定工艺，使得可以在工业上大量稳定地生产所需用于生产高质量高性能芳香族聚碳酸酯的高纯度二芳基碳酸酯（例如，每小时不少于1吨），并且可以在较长时间内（例如，不少于1000小时，最好不少于3000小时，更好不少于5000小时）从环状碳酸酯和芳香族单羟基化合物中生产。当从环状碳酸酯和芳香族单羟基化合物生产高纯度二芳基碳酸酯时，可以通过执行本发明的工艺步骤来实现上述目的，该工艺步骤包括：（I）使用具有特定结构的反应精馏塔生产二烷基碳酸酯和二醇；（II）使用具有特定结构的两个反应精馏塔生产二芳基碳酸酯；和（III）纯化二芳基碳酸酯以获得高纯度二芳基碳酸酯。
• INDUSTRIAL PROCESS FOR PRODUCTION OF AROMATIC CARBONATE
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1961732A1

  公开（公告）日：2008-08-27

  It is an object of the present invention to provide a specific process that enables an aromatic carbonate required for producing a high-quality high-performance aromatic polycarbonate to be produced industrially in a large amount (e.g. not less than 1 ton / hr) stably for a prolonged period of time (e.g. not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours) from a cyclic carbonate and an aromatic monohydroxy compound. When producing an aromatic carbonate from a cyclic carbonate and an aromatic monohydroxy compound, the above object can be attained by carrying out a step of: (I) producing a dialkyl carbonate and a diol using a reactive distillation column having a specified structure, and (II) producing the an aromatic carbonate using a first reactive distillation column having a specified structure.

  本发明的目的是提供一种特定的工艺，使得可以从环状碳酸酯和芳香单羟基化合物中稳定地大量（例如不少于1吨/小时）工业化生产所需用于生产高质量高性能芳香聚碳酸酯的芳香碳酸酯，且在较长时间内（例如不少于1000小时，更好地不少于3000小时，更好地不少于5000小时）。当从环状碳酸酯和芳香单羟基化合物生产芳香碳酸时，可以通过进行以下步骤实现上述目的：（I）使用具有特定结构的反应精馏塔生产二烷基碳酸酯和二元醇，以及（II）使用具有特定结构的第一反应精馏塔生产芳香碳酸。
• PROCESS FOR PRODUCING HIGH-PURITY DIPHENYL CARBONATE ON AN INDUSTRIAL SCALE
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1964831A1

  公开（公告）日：2008-09-03

  It is an object of the present invention to provide a specific process that enables a high-purity diphenyl carbonate required for producing a high-quality high-performance aromatic polycarbonate to be produced industrially in a large amount (e.g. not less than 1 ton / hr) stably for a prolonged period of time (e.g. not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours) from a cyclic carbonate and a phenol. When producing, from a cyclic carbonate and a phenol, a high-purity diphenyl carbonate required for producing a high-quality high-performance aromatic polycarbonate, the above object can be attained by carrying out a process according to the present invention which comprises steps of: (I) producing a dialkyl carbonate and a diol using a reactive distillation column having a specified structure; (II) producing a diphenyl carbonate using two reactive distillation columns each having a specified structure, and (III) obtaining a high-purity diphenyl carbonate from the diphenyl carbonate using a high boiling point material separating column A and a diphenyl carbonate purifying column B.

  本发明的目的是提供一种特定工艺，使得可以从环状碳酸酯和酚中稳定地大量（例如不少于1吨/小时）工业化生产所需用于生产高质量高性能芳香族聚碳酸酯的高纯度二苯碳酸酯，且生产时间持续较长（例如不少于1000小时，最好不少于3000小时，更好地不少于5000小时）。在从环状碳酸酯和酚中生产所需用于生产高质量高性能芳香族聚碳酸酯的高纯度二苯碳酸酯时，可以通过进行本发明的工艺步骤来实现上述目的，包括以下步骤：（I）使用具有特定结构的反应精馏塔生产二烷基碳酸酯和二元醇；（II）使用具有特定结构的两个反应精馏塔生产二苯碳酸酯；以及（III）通过使用高沸点物分离塔A和二苯碳酸酯纯化塔B从二苯碳酸酯中获得高纯度二苯碳酸酯。
• [EN] METHOD AND APPARATUS FOR THE PRODUCTION OF DIARYL CARBONATE<br/>[FR] PROCÉDÉ ET APPAREIL DE PRODUCTION DE CARBONATE DE DIARYLE
  申请人：SABIC GLOBAL TECHNOLOGIES BV

  公开号：WO2016151508A1

  公开（公告）日：2016-09-29

  The present application describes a method for producing diaryl carbonate. The method includes a step of reacting dialkyl carbonate, aromatic alcohol and a catalyst precursor in a first distillation column to give rise to diaryl carbonate. The method includes a step for reacting, in the first distillation column, the aromatic alcohol with the catalyst precursor to produce a catalyst. The method also includes a step of recovering from the first distillation column a first top stream that comprises an alkyl alcohol evolved in the first distillation column. The present application also describes a system for the production of diaryl carbonate. The system includes a first distillation column including one or more inlets.

  本申请描述了一种生产二苯基碳酸酯的方法。该方法包括在第一蒸馏塔中反应二烷基碳酸酯、芳香醇和催化剂前体的步骤，以产生二苯基碳酸酯。该方法包括在第一蒸馏塔中将芳香醇与催化剂前体反应以产生催化剂的步骤。该方法还包括从第一蒸馏塔中回收包含在第一蒸馏塔中产生的烷基醇的第一顶部流的步骤。本申请还描述了一种用于生产二苯基碳酸酯的系统。该系统包括一个第一蒸馏塔，其中包括一个或多个进料口。