4,4'-bis(3-chlorophthalimido)diphenyl ether | 51877-50-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis(3-chlorophthalimido)diphenyl ether
• 英文别名: 2,2'-[Oxydi(4,1-phenylene)]bis(4-chloro-1H-isoindole-1,3(2H)-dione)；4-chloro-2-[4-[4-(4-chloro-1,3-dioxoisoindol-2-yl)phenoxy]phenyl]isoindole-1,3-dione
• CAS: 51877-50-0
• 化学式: C₂₈H₁₄Cl₂N₂O₅
• 分子量: 529.336
• InChiKey: WGQYSDCOPXQXGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  37
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  84
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-氯苯酐 、 4,4'-二氨基二苯醚 在 溶剂黄146 作用下， 反应 24.0h， 以90%的产率得到4,4'-bis(3-chlorophthalimido)diphenyl ether
  参考文献：
  名称：

  Syntheses of Biphenyl Polyimides via Nickel-Catalyzed Coupling Polymerization of Bis(chlorophthalimide)s

  摘要：

  A facile method for the synthesis of biphenyl polyimides, which involves the nickel-catalyzed coupling of aromatic dichlorides containing imide structure in the presence of zinc and triphenylphosphine, has been developed. The polymerizations proceeded smoothly under mild conditions and produced biphenyl polyimides with inherent viscosities of 0.13-0.98 dL/g. The polymerizations of bis(4-chlorophthalimide)s with bulky side substituents gave high molecular weight polymers. Low molecular weight polymers from bis(4-chlorophthalimide)s containing rigid diamine moieties and bis(3-chlorophthalimide)s were obtained because of the formations of polymer precipitate and cyclic oligoimides, respectively. The effects of various factors, such as amount of catalyst, solvent volume, ligand, reaction temperature, and time, on the polymerization were studied. The random copolymerization of two bis(chlorophthalimide)s in varying proportions produced medium molecular weight material. The TgS of prepared polyimides were observed at 245-311 degreesC, and the thermogravimetry of polymers showed 10% weight loss in nitrogen at 470-530 degreesC.

  DOI：

  10.1021/ma034036y

文献信息

• METHODS OF MANUFACTURE OF POLYETHERIMIDES
  申请人：SABIC Global Technologies B.V.

  公开号：EP3131949A1

  公开（公告）日：2017-02-22
• [EN] METHODS OF MANUFACTURE OF POLYETHERIMIDES<br/>[FR] PROCÉDÉS DE FABRICATION DE POLYÉTHERIMIDES
  申请人：SABIC GLOBAL TECHNOLOGIES BV

  公开号：WO2015160933A1

  公开（公告）日：2015-10-22

  A method of manufacture of a polyetherimide composition includes contacting a substituted phthalic anhydride and an organic diamine in the presence of diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing solvents at a temperature of greater than 130°C to provide a bis(phthalimide) composition comprising diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing solvents and a bis(phthalimide); and polymerizing the bis(phthalimide) and an alkali metal salt of a dihydroxy aromatic compound in the presence of diphenyl sulfone, sulfolane, or a combination comprising at least one of the foregoing to form a polyetherimide. The method does not require any catalyst either for the imidization or the polymerization.
• Syntheses of Biphenyl Polyimides via Nickel-Catalyzed Coupling Polymerization of Bis(chlorophthalimide)s
  作者：Changlu Gao、Suobo Zhang、Lianxun Gao、Mengxian Ding

  DOI：10.1021/ma034036y

  日期：2003.7.1

  A facile method for the synthesis of biphenyl polyimides, which involves the nickel-catalyzed coupling of aromatic dichlorides containing imide structure in the presence of zinc and triphenylphosphine, has been developed. The polymerizations proceeded smoothly under mild conditions and produced biphenyl polyimides with inherent viscosities of 0.13-0.98 dL/g. The polymerizations of bis(4-chlorophthalimide)s with bulky side substituents gave high molecular weight polymers. Low molecular weight polymers from bis(4-chlorophthalimide)s containing rigid diamine moieties and bis(3-chlorophthalimide)s were obtained because of the formations of polymer precipitate and cyclic oligoimides, respectively. The effects of various factors, such as amount of catalyst, solvent volume, ligand, reaction temperature, and time, on the polymerization were studied. The random copolymerization of two bis(chlorophthalimide)s in varying proportions produced medium molecular weight material. The TgS of prepared polyimides were observed at 245-311 degreesC, and the thermogravimetry of polymers showed 10% weight loss in nitrogen at 470-530 degreesC.