1'-tosylspiro[fluorene-9,4'(1'H)-indeno[1,2-b]pyrrole] | 1203957-28-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 1'-tosylspiro[fluorene-9,4'(1'H)-indeno[1,2-b]pyrrole]
• 英文别名: 1'-(4-Methylphenyl)sulfonylspiro[fluorene-9,4'-indeno[1,2-b]pyrrole]；1'-(4-methylphenyl)sulfonylspiro[fluorene-9,4'-indeno[1,2-b]pyrrole]
• CAS: 1203957-28-1
• 化学式: C₃₀H₂₁NO₂S
• 分子量: 459.568
• InChiKey: BEXQSWWLEFZGBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  34
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  47.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1'-tosylspiro[fluorene-9,4'(1'H)-indeno[1,2-b]pyrrole] 在 水 、 sodium hydroxide 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 3.0h， 以99%的产率得到spiro[fluorene-9,4'(1'H)-indeno[1,2-b]pyrrole]
  参考文献：
  名称：

  Highly Fluorescent BODIPY Dyes Modulated with Spirofluorene Moieties

  摘要：

  A new type of structurally rigid BODIPY dye having spirofluorene moieties has been synthesized. These structurally constrained BODIPY dyes with spirofluorene moieties exhibit an intense bathochromic fluorescence. The solvent dependence of fluorescence ON/OFF switching of a BODIPY dye having an amino moiety was observed.

  DOI：

  10.1021/ol902631d
• 作为产物：
  描述：

  9-(2-bromophenyl)-9-(N-tosylpyrrol-3-yl)-9H-fluorene 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 20.0h， 以63%的产率得到1'-tosylspiro[fluorene-9,4'(1'H)-indeno[1,2-b]pyrrole]
  参考文献：
  名称：

  Highly Fluorescent BODIPY Dyes Modulated with Spirofluorene Moieties

  摘要：

  A new type of structurally rigid BODIPY dye having spirofluorene moieties has been synthesized. These structurally constrained BODIPY dyes with spirofluorene moieties exhibit an intense bathochromic fluorescence. The solvent dependence of fluorescence ON/OFF switching of a BODIPY dye having an amino moiety was observed.

  DOI：

  10.1021/ol902631d

文献信息

• Highly Fluorescent BODIPY Dyes Modulated with Spirofluorene Moieties
  作者：Toshiyuki Kowada、Shuhei Yamaguchi、Kouichi Ohe

  DOI：10.1021/ol902631d

  日期：2010.1.15

  A new type of structurally rigid BODIPY dye having spirofluorene moieties has been synthesized. These structurally constrained BODIPY dyes with spirofluorene moieties exhibit an intense bathochromic fluorescence. The solvent dependence of fluorescence ON/OFF switching of a BODIPY dye having an amino moiety was observed.