4,4,5,5-Tetramethyl-2-[4-[2,3,5,6-tetrakis[4-(3,7-dimethyloctyl)phenyl]-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]phenyl]phenyl]-1,3,2-dioxaborolane | 1012859-87-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4,5,5-Tetramethyl-2-[4-[2,3,5,6-tetrakis[4-(3,7-dimethyloctyl)phenyl]-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]phenyl]phenyl]-1,3,2-dioxaborolane
• 英文别名: 4,4,5,5-tetramethyl-2-[4-[2,3,5,6-tetrakis[4-(3,7-dimethyloctyl)phenyl]-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]phenyl]phenyl]-1,3,2-dioxaborolane
• CAS: 1012859-87-8
• 化学式: C₉₄H₁₃₂B₂O₄
• 分子量: 1347.7
• InChiKey: OPOMFAJORWSWTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.87
• 重原子数：
  100
• 可旋转键数：
  36
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  异丙醇频哪醇硼酸酯 、 1,4-bis(4-bromophenyl)-2,3,5,6-tetrakis[4-(3,7-dimethyloctyl)phenyl]benzene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以82%的产率得到4,4,5,5-Tetramethyl-2-[4-[2,3,5,6-tetrakis[4-(3,7-dimethyloctyl)phenyl]-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]phenyl]phenyl]-1,3,2-dioxaborolane
  参考文献：
  名称：

  Two-Dimensional Graphene Nanoribbons

  摘要：

  A new synthetic strategy toward novel linear two-dimensional graphene nanoribbons up to 12 nm has been established. The nanoribbons are characterized by MS, UV/vis, and scanning tunneling microscopy (STM). Various microscopic studies of these novel structures showed a high tendency to self-assemble.

  DOI：

  10.1021/ja710234t