2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone | 1257659-05-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone
• 英文别名: 2,3-Bis(chloromethyl)-1,4,9,10-anthracenetetrone；2,3-bis(chloromethyl)anthracene-1,4,9,10-tetrone
• CAS: 1257659-05-4
• 化学式: C₁₆H₈Cl₂O₄
• 分子量: 335.143
• InChiKey: BIEHXPKXABJFDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  68.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,3-dimethylanthracene-1,4,9,10-tetraone 在 溴 、 lead(IV) tetraacetate 、 lithium chloride 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone
  参考文献：
  名称：

  Influence of Silver Nanoparticles on 2,3-Bis(Chloromethyl)Anthracene-1,4,9,10-Tetraone

  摘要：

  利用光学吸收和荧光发射技术研究了纳米银粒子的尺寸对 2,3-双（氯甲基）蒽-1,4,9,10-四酮（BCMAT）光物理性质的影响。通过两种不同的方法制备了不同大小的银 NPs。研究发现，BCMAT 的荧光淬灭随银 NPs 尺寸的减小而增加。此外，还计算了斯特恩-沃尔默淬灭常数。

  DOI：

  10.1007/s10895-009-0533-4

文献信息

• Surface-Enhanced Infrared Spectral Investigations of 2,3-Bis(chloromethyl)anthracene-1,4,9,10-tetraone on Copper Nanoparticles
  作者：M. Umadevi、S. Jeyaseeli、M. Anuratha、P. Vanelle、T. Terme

  DOI：10.1080/00387010.2011.635173

  日期：2012.9

  Surface-enhanced infrared (IR) absorption spectroscopic technique has been employed to investigate the orientation of 2,3-bis(chloromethyl) anthracene-1,4,9,10-tetraone (BCMAT) on copper nanoparticles (NPs). Copper NPs have been prepared by the chemical reduction method. The observed ring stretching modes show higher downshifts, broader bandwidths, and higher enhancement. The observed features in out-of-plane and in-plane CH deformation modes indicate that the BCMAT molecules may be adsorbed in a "flat-on" orientation on the copper NPs. The observed lower enhancement factor of the in-plane C=O deformation mode and C=O stretching mode and the higher enhancement factor of out-of-plane C=O deformation mode elucidate that the BCMAT molecules are adsorbed on the copper NPs in a "flat-on" orientation. All these observations show that BCMAT is adsorbed on copper NPs through the pi-anthraquinone ring system in a "flat-on" orientation.
• Influence of Silver Nanoparticles on 2,3-Bis(Chloromethyl)Anthracene-1,4,9,10-Tetraone
  作者：Mahalingam Umadevi、N. A. Sridevi、A. S. Sharmila、Beulah J. M. Rajkumar、M. Briget Mary、P. Vanelle、T. Terme、O. Khoumeri

  DOI：10.1007/s10895-009-0533-4

  日期：2010.1

  Size effect of silver nano particles on the photophysical properties of 2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone (BCMAT) have been investigated using optical absorption and fluorescence emission techniques. Silver NPs of different sizes have been prepared by two different methods. Quenching of fluorescence of BCMAT has been found to increase with decrease in the size of the silver NPs. Stern–Volmer quenching constants have also been calculated.

  利用光学吸收和荧光发射技术研究了纳米银粒子的尺寸对 2,3-双（氯甲基）蒽-1,4,9,10-四酮（BCMAT）光物理性质的影响。通过两种不同的方法制备了不同大小的银 NPs。研究发现，BCMAT 的荧光淬灭随银 NPs 尺寸的减小而增加。此外，还计算了斯特恩-沃尔默淬灭常数。