2-mercapto-N-[2-(methylthio)phenyl]ethanamide | 221051-00-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-mercapto-N-[2-(methylthio)phenyl]ethanamide
• 英文别名: N-[2-(Methylsulfanyl)phenyl]-2-sulfanylacetamide；N-(2-methylsulfanylphenyl)-2-sulfanylacetamide
• CAS: 221051-00-9
• 化学式: C₉H₁₁NOS₂
• mdl: MFCD24388593
• 分子量: 213.324
• InChiKey: PUCALJVGIDKMGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.222
• 拓扑面积：
  55.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-氨基茴香硫醚 、 巯基乙酸 反应 2.0h， 以15%的产率得到2-mercapto-N-[2-(methylthio)phenyl]ethanamide
  参考文献：
  名称：

  Designer ligands. Part 3. Synthesis of pgm-specific bidentate and tridentate ligands

  摘要：

  Bidentate and tridentate, sulfur-containing, mono-amide ligands, designed to exhibit specificity for platinum group metals (pgm), have been prepared. Preliminary extraction studies indicate that the tridentate ligands exhibit selectivity for palladium(II) in the presence of base metals. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)01077-1

文献信息

• Designer ligands. Part 3. Synthesis of pgm-specific bidentate and tridentate ligands
  作者：Justin P. Hagemann、Perry T. Kaye

  DOI：10.1016/s0040-4020(98)01077-1

  日期：1999.1

  Bidentate and tridentate, sulfur-containing, mono-amide ligands, designed to exhibit specificity for platinum group metals (pgm), have been prepared. Preliminary extraction studies indicate that the tridentate ligands exhibit selectivity for palladium(II) in the presence of base metals. (C) 1998 Elsevier Science Ltd. All rights reserved.