N-(5-氯-2-羟基苯基)氨基甲酸异丙酯 | 27898-06-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-(5-氯-2-羟基苯基)氨基甲酸异丙酯
• 英文名称: (2-Hydroxy-5-chlorophenyl)carbamic acid isopropyl ester
• 英文别名: Isopropyl-2-hydroxy-5-chlorphenylcarbaminat；Isopropyl-5-chlor-2-hydroxycarbanilat；Carbamic acid, (5-chloro-2-hydroxyphenyl)-, 1-methylethyl ester；propan-2-yl N-(5-chloro-2-hydroxyphenyl)carbamate
• CAS: 27898-06-2
• 化学式: C₁₀H₁₂ClNO₃
• 分子量: 229.663
• InChiKey: UMISYNRSBYIDTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  58.6
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 海关编码：
  2924299090

反应信息

• 作为产物：
  描述：

  氯苯胺灵 生成 氨基甲酸异丙酯 、 N-(5-氯-2-羟基苯基)氨基甲酸异丙酯 、 Isopropyl-3-chlor-5-hydroxycarbanilat 、 3-氯苯胺
  参考文献：
  名称：

  Ultrasonic and photochemical degradation of chlorpropham and 3-chloroaniline in aqueous solution

  摘要：

  Sonolysis and photolysis are compared for the transformation of chlorpropham, a systemic herbicide belonging to the carbamate group, and 3-chloroaniline, the main intermediate often observed in the degradation of chlorpropham. In both cases the ultrasonic degradation is much more efficient at 482 kHz than at 20 kHz. The main identified sonoproducts formed in the degradation of chlorpropham are 3-chloroaniline, formic acid, carbon monoxide and dioxide and chloride ions. The degradation of 3-chloroaniline also leads to Cl-, CO and CO2 but chlorohydroquine was also detected as an intermediate. Two different mechanisms are involved in the ultrasonic transformation: pyrolysis resulting from the implosion of cavitation microbubbles and oxidation by hydroxyl radicals formed by sonolysis of water. Photolysis is more specific: 3-chloroaniline is initially quantitatively transformed into 3-aminophenol. A heterolytic mechanism is suggested. Resorcinol and some unidentified phoroproducts are formed in a second stage. The same type of reaction is involved in the photo-transformation of chlorpropham, but the reaction is not so specific. Ln both cases the photolysis at 254 nm leads to a complete disappearance of phenolic and quinonic compounds. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0043-1354(97)00477-6

文献信息

• Compositions for the oxidation dyeing of keratinous fibers comprising at least one coupler, and dyeing methods
  申请人：——

  公开号：US20010034914A1

  公开（公告）日：2001-11-01

  Compositions for oxidation dyeing keratinous fibers, for example, human keratinous fibers such as hair, comprising at least one oxidation base and at least one coupler chosen from N-(2-hydroxybenzene)carbamate and N-(2-hydroxybenzene)urea compounds and their acid addition salts of formula (I) and processes comprising such compositions.

  氧化染角蛋白纤维（例如人类角蛋白纤维，如头发）的组合物，包括至少一种氧化剂和至少一种从式（I）中选择的偶联剂，该式中的化合物为N-(2-羟基苯基) 聚氨酯和N-(2-羟基苯基)脲化合物及其酸加成盐，并且包括使用这种组合物的方法。
• Oxidation dyeing composition for keratinous fibres comprising a n-(2-hydrobenzene)-carbamate or a n-(2-hydroxy-benzene)-urea and a pyrazolopyrimine, dyeing methods
  申请人：——

  公开号：US20020178512A1

  公开（公告）日：2002-12-05

  The subject of the invention is a composition for the oxidation dyeing of keratinous fibers, and in particular human keratinous fibers such as hair, comprising at least one oxidation base, chosen from the pyrazolopyrimidines, and, as coupler, at least one N-(2-hydroxybenzene)carbamate or one N-(2-hydroxy-benzene)urea of formula (I), their use as coupler for the oxidation dyeing of keratinous fibers, and the oxidation dyeing methods using them.

  本发明涉及一种用于氧化染色角蛋白纤维，特别是人类角蛋白纤维（如头发）的组合物，包括至少一种氧化剂，所述氧化剂选择自吡唑嘧啶类化合物，并且，作为偶联剂，至少包括公式（I）中的一种N-(2-羟基苯基)氨基甲酸酯或N-(2-羟基苯基)脲，其作为氧化染色角蛋白纤维的偶联剂，以及使用它们的氧化染色方法。
• US6635091B2
  申请人：——

  公开号：US6635091B2

  公开（公告）日：2003-10-21
• Ultrasonic and photochemical degradation of chlorpropham and 3-chloroaniline in aqueous solution
  作者：B. David、M. Lhote、V. Faure、P. Boule

  DOI：10.1016/s0043-1354(97)00477-6

  日期：1998.8

  Sonolysis and photolysis are compared for the transformation of chlorpropham, a systemic herbicide belonging to the carbamate group, and 3-chloroaniline, the main intermediate often observed in the degradation of chlorpropham. In both cases the ultrasonic degradation is much more efficient at 482 kHz than at 20 kHz. The main identified sonoproducts formed in the degradation of chlorpropham are 3-chloroaniline, formic acid, carbon monoxide and dioxide and chloride ions. The degradation of 3-chloroaniline also leads to Cl-, CO and CO2 but chlorohydroquine was also detected as an intermediate. Two different mechanisms are involved in the ultrasonic transformation: pyrolysis resulting from the implosion of cavitation microbubbles and oxidation by hydroxyl radicals formed by sonolysis of water. Photolysis is more specific: 3-chloroaniline is initially quantitatively transformed into 3-aminophenol. A heterolytic mechanism is suggested. Resorcinol and some unidentified phoroproducts are formed in a second stage. The same type of reaction is involved in the photo-transformation of chlorpropham, but the reaction is not so specific. Ln both cases the photolysis at 254 nm leads to a complete disappearance of phenolic and quinonic compounds. (C) 1998 Elsevier Science Ltd. All rights reserved.