5H-naphtho[2,3-c]phenothiazine-8,13-dione | 6937-82-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 5H-naphtho[2,3-c]phenothiazine-8,13-dione
• CAS: 6937-82-2
• 化学式: C₂₀H₁₁NO₂S
• 分子量: 329.379
• InChiKey: RSCAZJBRAXOOMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.5
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-azido-1-phenylthioanthraquinone 在 氢氧化钾 作用下， 以 二甲基亚砜 为溶剂， 反应 1.0h， 以100%的产率得到5H-naphtho[2,3-c]phenothiazine-8,13-dione
  参考文献：
  名称：

  摘要：

  Thermolysis of 1-arylthio-2-azidoanthraquinones in DMSO at 150 degreesC afforded substituted 5H-naphtho[2,3-c]phenothiazine-8,13-diones. These compounds were also formed upon photolysis of azides at 77 K and were prepared in quantitative yields by the reactions of 1-arylthio-2-azidoanthraquinones with KOH in DMSO at 20 degreesC.

  DOI：

  10.1023/a:1011321114174

文献信息

• ——
  作者：L. S. Klimenko、E. A. Pritchina、N. P. Gritsan

  DOI：10.1023/a:1011321114174

  日期：——

  Thermolysis of 1-arylthio-2-azidoanthraquinones in DMSO at 150 degreesC afforded substituted 5H-naphtho[2,3-c]phenothiazine-8,13-diones. These compounds were also formed upon photolysis of azides at 77 K and were prepared in quantitative yields by the reactions of 1-arylthio-2-azidoanthraquinones with KOH in DMSO at 20 degreesC.