1,7-dibromoperylene-3,4,9,10-tetracarboxylic tetra(2-ethylhexyl)ester | 1422421-95-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,7-dibromoperylene-3,4,9,10-tetracarboxylic tetra(2-ethylhexyl)ester
• 英文别名: Tetrakis(2-ethylhexyl) 1,7-dibromoperylene-3,4,9,10-tetracarboxylate；tetrakis(2-ethylhexyl) 1,7-dibromoperylene-3,4,9,10-tetracarboxylate
• CAS: 1422421-95-1
• 化学式: C₅₆H₇₄Br₂O₈
• 分子量: 1035.01
• InChiKey: XPQFZGIBGHPPHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.1
• 重原子数：
  66
• 可旋转键数：
  32
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,7-dibromoperylene-3,4,9,10-tetracarboxylic tetra(2-ethylhexyl)ester 在 四(三苯基膦)钯 、 碘 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 2.0h， 生成 dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester
  参考文献：
  名称：

  Synthesis and optoelectronic properties of a novel molecular semiconductor of dithieno[5,6-b:11,12-b′]coronene-2,3,8,9-tetracarboxylic tetraester

  摘要：

  A facile procedure for the synthesis of dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester (DTCTTE-EH) from readily available perylene-3,4,9,10-tetracaroboxylic dianhydride is described. The electronic properties of DTCTTE-EH were elucidated on the basis of UV-vis spectra, emission spectrum and electrochemical measurement, which demonstrate that DTCTTE is a new class of components for promising semiconducting materials. (C) 2013 Sheng-Qiang Xiao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2013.09.006
• 作为产物：
  描述：

  perylene-3,4,9,10-tetracarboxylic tetra(2-ethylhexyl)ester 在 溴 、 potassium carbonate 作用下， 以 二氯甲烷 为溶剂， 以64%的产率得到1,7-dibromoperylene-3,4,9,10-tetracarboxylic tetra(2-ethylhexyl)ester
  参考文献：
  名称：

  Synthesis and optoelectronic properties of a novel molecular semiconductor of dithieno[5,6-b:11,12-b′]coronene-2,3,8,9-tetracarboxylic tetraester

  摘要：

  A facile procedure for the synthesis of dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester (DTCTTE-EH) from readily available perylene-3,4,9,10-tetracaroboxylic dianhydride is described. The electronic properties of DTCTTE-EH were elucidated on the basis of UV-vis spectra, emission spectrum and electrochemical measurement, which demonstrate that DTCTTE is a new class of components for promising semiconducting materials. (C) 2013 Sheng-Qiang Xiao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2013.09.006

文献信息

• Synthesis and optoelectronic properties of a novel molecular semiconductor of dithieno[5,6-b:11,12-b′]coronene-2,3,8,9-tetracarboxylic tetraester
  作者：Chun Zhan、You-Yu Jiang、Ming-Yan Yang、Lu-Hua Lu、Sheng-Qiang Xiao

  DOI：10.1016/j.cclet.2013.09.006

  日期：2014.1

  A facile procedure for the synthesis of dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester (DTCTTE-EH) from readily available perylene-3,4,9,10-tetracaroboxylic dianhydride is described. The electronic properties of DTCTTE-EH were elucidated on the basis of UV-vis spectra, emission spectrum and electrochemical measurement, which demonstrate that DTCTTE is a new class of components for promising semiconducting materials. (C) 2013 Sheng-Qiang Xiao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.