dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester | 1554323-97-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester
• CAS: 1554323-97-5
• 化学式: C₆₄H₇₆O₈S₂
• 分子量: 1037.43
• InChiKey: GUCHIHBUUYGMLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.84
• 重原子数：
  74.0
• 可旋转键数：
  28.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  105.2
• 氢给体数：
  0.0
• 氢受体数：
  10.0

反应信息

• 作为产物：
  描述：

  1,7-di(2-thienyl)-perylene-3,4,9,10-tetracarboxylic tetra(2-ethylhexyl)ester 在 碘 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以80%的产率得到dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester
  参考文献：
  名称：

  Synthesis and optoelectronic properties of a novel molecular semiconductor of dithieno[5,6-b:11,12-b′]coronene-2,3,8,9-tetracarboxylic tetraester

  摘要：

  A facile procedure for the synthesis of dithieno[5,6-b:11,12-b']coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester (DTCTTE-EH) from readily available perylene-3,4,9,10-tetracaroboxylic dianhydride is described. The electronic properties of DTCTTE-EH were elucidated on the basis of UV-vis spectra, emission spectrum and electrochemical measurement, which demonstrate that DTCTTE is a new class of components for promising semiconducting materials. (C) 2013 Sheng-Qiang Xiao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2013.09.006