[1,3';1',1'';3'',1''';3''',1'''']Quinquephenyl-2''-carbonitrile | 142273-88-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1,3';1',1'';3'',1''';3''',1'''']Quinquephenyl-2''-carbonitrile
• 英文别名: 2,6-Bis(3-phenylphenyl)benzonitrile
• CAS: 142273-88-9
• 化学式: C₃₁H₂₁N
• 分子量: 407.514
• InChiKey: XRNNUSKFSCROFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-联苯硼酸 、 2,6-diiodobenzonitrile 在 四(三苯基膦)钯 作用下， 以 乙二醇二甲醚 为溶剂， 以89%的产率得到[1,3';1',1'';3'',1''';3''',1'''']Quinquephenyl-2''-carbonitrile
  参考文献：
  名称：

  Directed ortho metalation - suzuki cross coupling connections. Convenient regiospecific routes to functionalized m- and p-teraryls and m-quinquearyls

  摘要：

  Rapid access to a variety of substituted m- and p- teraryls and m- quinquearyls (Table) via Pd-catalyzed, one-pot, sequential and 1:2 cross coupling of aryl halides with aryl boronic acids, both available by metal-halogen exchange or directed ortho metalation tactics, is described.

  DOI：

  10.1016/s0040-4039(00)78854-x

文献信息

• Organic electroluminescent device
  申请人：Sano Satoshi

  公开号：US20070202358A1

  公开（公告）日：2007-08-30

  An organic electroluminescent device, which comprises: a pair of electrodes; and an organic compound layer including a light-emitting layer between the pair of electrodes, wherein the organic compound layer comprises a compound represented by formula (I): wherein Z 1 , Z 2 , Z 3 and Z 4 each independently represents an atom selected from the group consisting of carbon, nitrogen, sulfur and oxygen and necessary for forming an unsaturated 6-membered ring skeleton, the atom may have a hydrogen atom or a substituent; a bond in the unsaturated 6-membered ring indicates a single bond or a double bond; and R 1 represents a substituent.
• Directed ortho metalation - suzuki cross coupling connections. Convenient regiospecific routes to functionalized m- and p-teraryls and m-quinquearyls
  作者：Cathleen M. Unrau、Michael G. Campbell、Victor Snieckus

  DOI：10.1016/s0040-4039(00)78854-x

  日期：1992.5

  Rapid access to a variety of substituted m- and p- teraryls and m- quinquearyls (Table) via Pd-catalyzed, one-pot, sequential and 1:2 cross coupling of aryl halides with aryl boronic acids, both available by metal-halogen exchange or directed ortho metalation tactics, is described.