N-[(1E)-1-氨基亚乙基]苯甲酰胺 | 5692-19-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-[(1E)-1-氨基亚乙基]苯甲酰胺
• 英文名称: N-benzoylacetamidine
• 英文别名: N-Benzoyl-acetamidin；N-(1-aminoethylidene)benzamide；N-ethanimidoylbenzamide
• CAS: 5692-19-3
• 化学式: C₉H₁₀N₂O
• 分子量: 162.191
• InChiKey: QUDWTEHEXMAGLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-[(1E)-1-氨基亚乙基]苯甲酰胺 在 盐酸 作用下， 生成 N-乙酰基-苯甲酰胺
  参考文献：
  名称：

  Mikhailov,B.M. et al., Journal of general chemistry of the USSR, 1972, vol. 42, p. 1545 - 1549

  摘要：

  DOI：
• 作为产物：
  描述：

  3-甲基-5-苯基-1,2,4-噁二唑 在 palladium on activated charcoal 氢气 作用下， 生成 N-[(1E)-1-氨基亚乙基]苯甲酰胺
  参考文献：
  名称：

  Palazzo,G. et al., Gazzetta Chimica Italiana, 1961, vol. 91, p. 1085 - 1096

  摘要：

  DOI：

文献信息

• A metal-free tandem approach to prepare structurally diverse N-heterocycles: synthesis of 1,2,4-oxadiazoles and pyrimidinones
  作者：Puneet K. Gupta、Mohd. Kamil Hussain、Mohd. Asad、Ruchir Kant、Rohit Mahar、Sanjeev K. Shukla、Kanchan Hajela

  DOI：10.1039/c4nj00361f

  日期：——

  N-heterocycles, namely 1,2,4-oxadiazoles and 2,6 disubstituted pyrimidin-4-ones, have been synthesised in one pot via carboxamidation of amidines with aryl carboxylic acids and aryl propargylic acids under metal-free conditions.

  N-杂环化合物，即1,2,4-噁二唑和2,6-二取代嘧啶-4-酮，已经在无金属条件下通过酰胺与芳香羧酸和芳香丙炔酸的一锅法合成。
• [EN] BLUE LUMINESCENT COMPOUNDS<br/>[FR] COMPOSÉS LUMINESCENTS BLEUS
  申请人：DU PONT

  公开号：WO2013151989A1

  公开（公告）日：2013-10-10

  There is provided a compound having Formula (I). In the formula: R1 can be alkyl, aryl, alkylaryl, or deuterated analogs thereof; R2 can be alkyl or deuterated alkyl; R3 can be H, D, aryl, or deuterated aryl; and R4-R6 are the same or different and can be H, D, alkyl, or deuterated alkyl. In the formula, at least one of the following conditions is met: (i) R1 is a secondary alkyl, a tertiary alkyl, aryl, alkylaryl, or deuterated analog thereof; (ii) R3 is aryl or deuterated aryl; (iii) at least one of R3-R6 is D.

  提供了一种具有式（I）的化合物。在该式中：R1可以是烷基，芳基，烷基芳基或其氘代物；R2可以是烷基或氘代烷基；R3可以是H，D，芳基或氘代芳基；而R4-R6相同或不同，可以是H，D，烷基或氘代烷基。在该式中，至少满足以下条件之一：（i）R1是二级烷基，三级烷基，芳基，烷基芳基或其氘代物；（ii）R3是芳基或氘代芳基；（iii）R3-R6中至少有一个是D。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• Acylation of dibasic compounds containing amino amidine and aminoguanidine functions
  作者：Peter L. Barker、Paul L. Gendler、Henry Rapoport

  DOI：10.1021/jo00325a006

  日期：1981.6