1,3-bis(3',5'-diphenylphenylsulfonyl)benzene | 1208234-52-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-bis(3',5'-diphenylphenylsulfonyl)benzene
• 英文别名: 1-[3-(3,5-diphenylphenyl)sulfonylphenyl]sulfonyl-3,5-diphenylbenzene
• CAS: 1208234-52-9
• 化学式: C₄₂H₃₀O₄S₂
• 分子量: 662.83
• InChiKey: JUAOJQOBSOLOCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  48
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  85
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3,5-二氯苯硫酚 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三环己基膦 potassium phosphate 、 copper(l) iodide 、 potassium carbonate 、 间氯过氧苯甲酸 作用下， 以 1,4-二氧六环 、 二氯甲烷 、 N,N-dimethylimidazolidinone 、 水 为溶剂， 反应 46.0h， 生成 1,3-bis(3',5'-diphenylphenylsulfonyl)benzene
  参考文献：
  名称：

  ORGANIC SULFUR COMPOUND, PROCESS FOR PRODUCTION OF THE SAME, AND ORGANIC ELECTROLUMINESCENCE ELEMENT UTILIZING THE SAME

  摘要：

  公开号：

  EP2332907B1

文献信息

• ORGANOSULFUR COMPOUND, PROCESS FOR PRODUCING THE SAME, AND ORGANIC ELECTROLUMINESCENCE ELEMENT USING THE SAME
  申请人：Kido Junji

  公开号：US20110140044A1

  公开（公告）日：2011-06-16

  Disclosed is an organosulfur compound denoted by a general formula (a1): in which A denotes —S—, —S(O)— or —S(O) 2 —; Z 1 and Z 4 denote a trivalent aromatic hydrocarbon group or the like; Z 2 and Z 3 denote a bivalent aromatic hydrocarbon group or the like; Ar 1 , Ar 2 , Ar 3 and Ar 4 denote an aromatic hydrocarbon group or the like; and n is 0 or 1, or a general formula (b1): in which A denotes the same meaning as aforesaid; Z 5 denotes a trivalent aromatic hydrocarbon group or the like; Ar denotes a m-valent aromatic hydrocarbon group or the like; Ar 1 and Ar 2 denote the aforesaid meaning; and m is 2 or 3. This compound is useful as an electron transport material, a hole blocking material or a host material of an organic electroluminescence element.

  本发明公开了一种有机硫化合物，其通式为（a1）：其中A表示—S—、—S(O)—或—S(O)2—；Z1和Z4表示三价芳香烃基或类似物；Z2和Z3表示二价芳香烃基或类似物；Ar1、Ar2、Ar3和Ar4表示芳香烃基或类似物；n为0或1，或通式为（b1）：其中A表示如上所述的相同含义；Z5表示三价芳香烃基或类似物；Ar表示m价芳香烃基或类似物；Ar1和Ar2表示如上所述的含义；m为2或3。该化合物可用作电子传输材料、阻挡孔洞材料或有机电致发光元件的主体材料。
• Organosulfur compound, process for producing the same, and organic electroluminescence element using the same
  申请人：Kido Junji

  公开号：US08597799B2

  公开（公告）日：2013-12-03

  Disclosed is an organosulfur compound denoted by a general formula (a1): in which A denotes —S—, —S(O)— or —S(O)2—; Z1 and Z4 denote a trivalent aromatic hydrocarbon group or the like; Z2 and Z3 denote a bivalent aromatic hydrocarbon group or the like; Ar1, Ar2, Ar3 and Ar4 denote an aromatic hydrocarbon group or the like; and n is 0 or 1, or a general formula (b1): in which A denotes the same meaning as aforesaid; Z5 denotes a trivalent aromatic hydrocarbon group or the like; Ar denotes a m-valent aromatic hydrocarbon group or the like; Ar1 and Ar2 denote the aforesaid meaning; and m is 2 or 3. This compound is useful as an electron transport material, a hole blocking material or a host material of an organic electroluminescence element.

  本发明公开了一种有机硫化合物，其通式为（a1）：其中A表示—S—，—S（O）—或—S（O）2—；Z1和Z4表示三价芳香烃基或类似物；Z2和Z3表示二价芳香烃基或类似物；Ar1，Ar2，Ar3和Ar4表示芳香烃基或类似物；n为0或1；或通式（b1）：其中A的含义与前述相同；Z5表示三价芳香烃基或类似物；Ar表示m价芳香烃基或类似物；Ar1和Ar2表示前述含义；m为2或3。该化合物可用作有机电致发光元件的电子传输材料、空穴阻挡材料或主体材料。
• US8597799B2
  申请人：——

  公开号：US8597799B2

  公开（公告）日：2013-12-03
• ORGANIC SULFUR COMPOUND, PROCESS FOR PRODUCTION OF THE SAME, AND ORGANIC ELECTROLUMINESCENCE ELEMENT UTILIZING THE SAME
  申请人：Ube Industries, Ltd.

  公开号：EP2332907B1

  公开（公告）日：2015-07-01