N,N′-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(S,S)-ethane-1,2-diamine) | 116948-66-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: N,N′-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(S,S)-ethane-1,2-diamine)
• 英文别名: N-[(1S,2S)-1,2-diphenyl-2-(pyridin-2-ylmethylideneamino)ethyl]-1-pyridin-2-ylmethanimine
• CAS: 116948-66-4
• 化学式: C₂₆H₂₂N₄
• 分子量: 390.487
• InChiKey: SSFMGYFYFVMPLN-UIOOFZCWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  50.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  erbium(III) chloride hexahydrate 、 N,N′-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(S,S)-ethane-1,2-diamine) 以 甲醇 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Chiral mononuclear lanthanide complexes derived from chiral Schiff bases: Structural and magnetic studies

  摘要：

  A new family of mononuclear lanthanide complexes with formula [Ln(III)(L)Cl-3] (Ln = Eu (1), Tb (2), Dy (3), Er (4), Yb (5)) and L = N,N'-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(R,R/S,S)-ethane-1,2-diamine has been obtained employing enantiomerically pure Schiff bases. The complexes have been structurally characterized using X-ray single crystal and powder diffraction. Their dynamic magnetic properties have been studied showing that this family presents slow relaxation of the magnetization under certain conditions and confirms the different behavior of each Ln(III) cations in isostructural complexes: only the Er one possibly relaxing via an overbarrier Orbach process, while Raman process dominates for Dy and Yb derivative. (C) 2019 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2019.05.051
• 作为产物：
  描述：

  吡啶-2-甲醛 、 (1S,2S)-1,2-二苯基乙二胺 以 甲醇 为溶剂， 反应 3.0h， 生成 N,N′-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(S,S)-ethane-1,2-diamine)
  参考文献：
  名称：

  Chiral mononuclear lanthanide complexes derived from chiral Schiff bases: Structural and magnetic studies

  摘要：

  A new family of mononuclear lanthanide complexes with formula [Ln(III)(L)Cl-3] (Ln = Eu (1), Tb (2), Dy (3), Er (4), Yb (5)) and L = N,N'-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(R,R/S,S)-ethane-1,2-diamine has been obtained employing enantiomerically pure Schiff bases. The complexes have been structurally characterized using X-ray single crystal and powder diffraction. Their dynamic magnetic properties have been studied showing that this family presents slow relaxation of the magnetization under certain conditions and confirms the different behavior of each Ln(III) cations in isostructural complexes: only the Er one possibly relaxing via an overbarrier Orbach process, while Raman process dominates for Dy and Yb derivative. (C) 2019 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2019.05.051
• 作为试剂：
  描述：

  1-萘甲醛 在 tetrachlorobis(tetrahydrofuran)titanium(IV) 锰 、 三甲基氯硅烷 、 N,N′-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(S,S)-ethane-1,2-diamine) 作用下， 以 乙腈 为溶剂， 反应 12.0h， 生成 (1R,2R)-1,2-di(naphthalen-1-yl)ethane-1,2-diol 、 meso-1,2-di-naphthalen-1-yl-ethane-1,2-diol 、 (S,S)-(?)-1,2-二(1-萘基)-1,2-乙二醇
  参考文献：
  名称：

  Asymmetric pinacol coupling of aromatic aldehydes catalyzed by a new titanium–Schiff base complex

  摘要：

  A new Schiff-base with two stereogenic centers has been prepared and its titanium complex applied to catalyze the pinacol coupling of aldehydes, which afforded pinacols in high yield, excellent diastereoselectivi ties, and high enantioselectivities. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2004.04.012

文献信息

• Single-Ion Anisotropy and Intramolecular Interactions in Ce^III and Nd^III Dimers
  作者：Júlia Mayans、Lorenzo Tesi、Matteo Briganti、Marie-Emmanuelle Boulon、Mercè Font-Bardia、Albert Escuer、Lorenzo Sorace

  DOI：10.1021/acs.inorgchem.1c00647

  日期：2021.6.21

  2-diamine), L1, of general formula [Ln2(RR-L1)2(Cl6)]·MeOH·1.5H2O, (Ln = Ce (1) or Nd (2)). Multifrequency electron paramagnetic resonance (EPR), cantilever torque magnetometry (CTM) measurements, and ab initio calculations allowed us to determine single-ion magnetic anisotropy and intramolecular magnetic interactions in both compounds, evidencing a more important role of the anisotropic exchange for the

  本文报道了两种基于手性配体N , N '-双((1,2-二苯基-(吡啶-2-基)亚甲基) 的同构分子磁体的合成、表征、结构描述以及磁性和光谱性质-( R , R / S , S )-乙烷-1,2-二胺)， L1 ，通式为[Ln 2 ( RR - L1 ) 2 (Cl 6 )] · MeOH · 1.5H 2 O，(Ln = Ce( 1 )或Nd( 2 ))。多频电子顺磁共振 (EPR)、悬臂扭矩磁力测定 (CTM) 测量和从头计算使我们能够确定两种化合物中的单离子磁各向异性和分子内磁相互作用，证明 Nd III 的各向异性交换的更重要作用衍生物。实验和理论数据的比较表明，在主要为菱形镧系离子的情况下，从头计算可能无法确定最弱组分的方向，但可以可靠地确定其主值。然而，它们对于在合理的基础上进行 EPR 和 CTM 分析仍然至关重要，从而获得这些系统中磁相互作用的非常精确的图像。最后，通过这种
• Chiral mononuclear lanthanide complexes derived from chiral Schiff bases: Structural and magnetic studies
  作者：J. Mayans、L. Sorace、M. Font-Bardia、A. Escuer

  DOI：10.1016/j.poly.2019.05.051

  日期：2019.9

  A new family of mononuclear lanthanide complexes with formula [Ln(III)(L)Cl-3] (Ln = Eu (1), Tb (2), Dy (3), Er (4), Yb (5)) and L = N,N'-bis((1,2-diphenyl-(pyridine-2-yl)methylene)-(R,R/S,S)-ethane-1,2-diamine has been obtained employing enantiomerically pure Schiff bases. The complexes have been structurally characterized using X-ray single crystal and powder diffraction. Their dynamic magnetic properties have been studied showing that this family presents slow relaxation of the magnetization under certain conditions and confirms the different behavior of each Ln(III) cations in isostructural complexes: only the Er one possibly relaxing via an overbarrier Orbach process, while Raman process dominates for Dy and Yb derivative. (C) 2019 Elsevier Ltd. All rights reserved.