1,6-Di-(2-thienyl)hexane | 21010-14-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 1,6-Di-(2-thienyl)hexane
• 英文别名: 1,6-Bis--hexan；1,6-Bis-<2-thienyl>-hexan；2,2'-hexane-1,6-diyl-bis-thiophene；2-(6-Thiophen-2-ylhexyl)thiophene
• CAS: 21010-14-0
• 化学式: C₁₄H₁₈S₂
• 分子量: 250.429
• InChiKey: SBVGKGVAYIKUNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,6-Di-(2-thienyl)hexane 在 正丁基锂 、 3 A molecular sieve 作用下， 以 乙醇 为溶剂， 反应 16.0h， 生成 1,6-Bis<5-(N-4-butylphenylimino)methylidene-2-thienyl>hexane
  参考文献：
  名称：

  Kossmehl, Gerhard; Hoppe, Frank Dirk; Hirsch, Barbara, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1993, vol. 48, # 6, p. 826 - 843

  摘要：

  DOI：
• 作为产物：
  描述：

  噻吩 、 1,6-二溴己烷 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以35 %的产率得到1,6-Di-(2-thienyl)hexane
  参考文献：
  名称：

  二聚体受体采用灵活的连接体用于高效耐用的有机太阳能电池

  摘要：

  设计并合成了一种带有柔性接头的二聚体受体，它不仅可以作为第三种成分来增强分子间堆积，还可以通过抑制分子扩散来稳定形态。因此，基于 PM6:Y6:  d T9TBO 的有机太阳能电池表现出 18.41% 的高功率转换效率以及出色的热/光稳定性和机械性能。

  DOI：

  10.1002/anie.202303066

文献信息

• Preparations and properties of polymers containing 3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene]-1,2-di(2-thienyl)cyclobutene moieties
  作者：Kozo Toyota、Junichi Ujita、Subaru Kawasaki、Keita Abe、Naoki Yamada、Masaaki Yoshifuji

  DOI：10.1016/j.tetlet.2004.08.108

  日期：2004.10

  6-tri-t-butylphenyl)phosphinoethynyl}-2-thienyl]octane with butyllithium followed by treatment with 1,2-dibromoethane afforded a new polymer containing 3,4-bis[(2,4,6-tri-t-butylphenyl)phosphinidene]-1,2-di(2-thienyl)cyclobutene units. The polymer was allowed to react with bis(benzonitrile)dichloropalladium to give the polymer complex. A Sonogashira coupling reaction between ethynyltrimethylsilane and 4-bromonitrobenzene

  的1,8-双反应[5 - （2,4,6-三-吨丁基苯基）phosphinoethynyl} -2-噻吩基]辛烷与丁基锂，接着用1,2-二溴乙烷处理，得到含有3新的聚合物， 1,4-双[（2,4,6-三-吨丁基苯基）亚膦基] -1,2-二（2-噻吩基）环丁烯单元。使聚合物与双（苄腈）二氯钯反应，得到聚合物络合物。乙炔基三甲基硅烷和4-溴硝基苯之间的Sonogashira偶联反应在DMF中于100°C下进行，在聚合物配合物CuI和三乙胺存在下得到4-硝基（三甲基甲硅烷基乙炔基）苯。
• Actuator device utilizing a conductive polymer gel
  申请人：——

  公开号：US20030156953A1

  公开（公告）日：2003-08-21

  A valve actuator based on a conductive polymer gel is disclosed. A nonconductive housing is provided having two separate chambers separated by a porous frit. The conductive polymer is held in one chamber and an electrolyte solution, used as a source of charged ions, is held in the second chamber. The ends of the housing a sealed with a flexible elastomer. The polymer gel is further provide with electrodes with which to apply an electrical potential across the gel in order to initiate an oxidation reaction which in turn drives anions across the porous frit and into the polymer gel, swelling the volume of the gel and simultaneously contracting the volume of the electrolyte solution. Because the two end chambers are sealed the flexible elastomer expands or contracts with the chamber volume change. By manipulating the potential across the gel the motion of the elastomer can be controlled to act as a “gate” to open or close a fluid channel and thereby control flow through that channel.

  本发明公开了一种基于导电聚合物凝胶的阀门执行器。它有一个不导电的壳体，壳体内有两个独立的腔室，由多孔熔块隔开。一个腔室中装有导电聚合物，第二个腔室中装有作为带电离子源的电解质溶液。外壳的两端用柔性弹性体密封。聚合物凝胶上还装有电极，用于在凝胶上施加电势，以启动氧化反应，进而驱动阴离子穿过多孔熔块进入聚合物凝胶，使凝胶体积膨胀，同时收缩电解质溶液的体积。由于两个末端腔体是密封的，因此柔性弹性体会随着腔体体积的变化而膨胀或收缩。通过操纵凝胶上的电位，可以控制弹性体的运动，使其成为打开或关闭流体通道的 "闸门"，从而控制流经该通道的流量。
• Complementary Semiconducting Polymer Blends: The Influence of Conjugation-Break Spacer Length in Matrix Polymers
  作者：Xikang Zhao、Yan Zhao、Qu Ge、Kamal Butrouna、Ying Diao、Kenneth R. Graham、Jianguo Mei

  DOI：10.1021/acs.macromol.6b00050

  日期：2016.4.12

  The concept of complementary semiconducting polymer blends (c-SPBs) for efficient charge transport was recently proposed and established by our group. In this study, we aim to reveal the influence of the length of conjugation-break spacers (CBSs) on charge transport properties of the matrix polymers and their corresponding complementary polymer blends. A series of 11 DPP-based semiconducting polymers DPP-Cm (m = 2-12) that incorporate CBSs of 2-12 methylene units along the polymer backbones were prepared and characterized. The UV vis spectra and the ultraviolet photoelectron spectroscopy (UPS) measurements show that the CBS length has marginal influence on the polymer absorption spectra, energy levels, and band gaps. It also has little impact on polymer decomposition temperatures. However, the CBS length has a profound influence on polymer phase transition and the heat of fusion. As for the melt transitions, an odd even effect is observed from DPP-C2 to DPP-C7, in which polymers with even-numbered CBSs show higher melting points than their adjacent odd-numbered derivatives. The trend is opposite for heat of fusion. The polymers with odd-numbered CBSs exhibit larger heat of fusion, indicating higher ordering and crystallinity. The odd even effect is also found in surface morphologies of the polymers by atomic force microscopy (AFM). The polymers with the even CBSs have a more interconnected feature that appear more fibrillar than the polymers with the odd linkages. As far as charge carrier mobility is concerned, the average number drops from 0.023 cm2 V-1 s(-1) to 7.9 X 10(-6) cm(2) V-1 s(-1) as the CBS moves from C2 to C12. It is intriguing to observe that even-numbered polymers outperform the adjacent odd-numbered polymers, despite the fact that the latter show higher ordering and crystallinity in thin films. When these polymers are mixed with fully conjugated DPP-CO (2 wt %, designated as tie chain polymer), the obtained cSPBs witness a dramatic increase (2-4 orders of magnitude) in charge carrier mobility. Interestingly, the odd even effect is not found for charge transport in the c-SPBs. This work reveals that the length of CBSs plays a significant role in charge transport properties of the matrix polymers and reconfirms that efficient charge transport properties of the c-SPB result from the interactions between matrix polymers and tie chain polymers. This begins to provide guidelines as to what spacer lengths may be utilized to offer the best balance between processing and charge transport properties.
• KURSANOV D. N.; PARNES Z. N.; BOLESTOVA G. I.; BELENKII L. I., TETRAHEDRON <TETR-AB>, 1975, 31, NO 4, 311-315
  作者：KURSANOV D. N.、 PARNES Z. N.、 BOLESTOVA G. I.、 BELENKII L. I.

  DOI：——

  日期：——
• SEMICARBAZONES HAVING CNS ACTIVITY AND PHARMACEUTICAL PREPARATIONS CONTAINING SAME
  申请人：University of Saskatchewan Technologies Inc.

  公开号：EP0836591B1

  公开（公告）日：2001-09-26