[(IPr=CH2)*P(Cl)N(PCl2N)2] | 1338672-13-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(IPr=CH2)*P(Cl)N(PCl2N)2]
• 英文别名: 2-[[1,3-Bis[2,6-di(propan-2-yl)phenyl]imidazol-2-ylidene]methyl]-2,4,4,6,6-pentachloro-1,3,5-triaza-2lambda5,4lambda5,6lambda5-triphosphacyclohexa-1,3,5-triene；2-[[1,3-bis[2,6-di(propan-2-yl)phenyl]imidazol-2-ylidene]methyl]-2,4,4,6,6-pentachloro-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
• CAS: 1338672-13-1
• 化学式: C₂₈H₃₇Cl₅N₅P₃
• 分子量: 713.822
• InChiKey: MPWNMJSOBRTJTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.5
• 重原子数：
  41
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  43.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  [(IPr=CH2)*P(Cl)N(PCl2N)2] 在 盐酸 、 1,2,3,4,5,6,7,8-八硫杂环辛烷 作用下， 以 甲苯 为溶剂， 生成 [IPr*(S)PN(PCl2N)2]
  参考文献：
  名称：

  Interaction of Carbene and Olefin Donors with [Cl₂PN]₃: Exploration of a Reductive Pathway toward (PN)₃

  摘要：

  The iminophosphine-phosphazene [P-III-P-V] heterocyclic adduct [IPr center dot PN(PCl2N)(2)] was prepared via reduction of the cyclic phosphazene [Cl2PN](3) in the presence of the carbene donor IPr {IPr = [(HCNDipp)(2)C:], where Dipp = 2,6-(Pr2C6H3)-Pr-1}. By contrast, the treatment of [Cl2PN](3) with the N-heterocydic olefin IPr=CH2 yielded the olefin-grafted phosphazene ring [(IPr=CH)P(Cl)N(PCl2N)(2)].

  DOI：

  10.1021/ic201812a

文献信息

• Interaction of Carbene and Olefin Donors with [Cl₂PN]₃: Exploration of a Reductive Pathway toward (PN)₃
  作者：S. M. Ibrahim Al-Rafia、Michael J. Ferguson、Eric Rivard

  DOI：10.1021/ic201812a

  日期：2011.11.7

  The iminophosphine-phosphazene [P-III-P-V] heterocyclic adduct [IPr center dot PN(PCl2N)(2)] was prepared via reduction of the cyclic phosphazene [Cl2PN](3) in the presence of the carbene donor IPr IPr = [(HCNDipp)(2)C:], where Dipp = 2,6-(Pr2C6H3)-Pr-1}. By contrast, the treatment of [Cl2PN](3) with the N-heterocydic olefin IPr=CH2 yielded the olefin-grafted phosphazene ring [(IPr=CH)P(Cl)N(PCl2N)(2)].