2,2',3,3',4,5,5',6,6'-nonafluoro-4'-bromodiphenylamine | 3756-37-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2',3,3',4,5,5',6,6'-nonafluoro-4'-bromodiphenylamine
• 英文别名: 2,2',3,3',4, 5,5',6,6'-nonafluoro-4'-diphenylamine；<4-Brom-tetrafluor-phenyl>-pentafluorphenyl-amin；N-(4-bromo-2,3,5,6-tetrafluorophenyl)-2,3,4,5,6-pentafluoroaniline
• CAS: 3756-37-4
• 化学式: C₁₂HBrF₉N
• 分子量: 410.036
• InChiKey: DVFVVLWNNHRTQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  2,2',3,3',4,5,5',6,6'-nonafluoro-4'-bromodiphenylamine 、 以 二甲基亚砜 为溶剂， 生成 9H-芴-9-羧酸甲酯 、
  参考文献：
  名称：

  Vlasov, V. M.; Terekhova, M. I.; Petrov, E. S., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, # 10, p. 1807 - 1813

  摘要：

  DOI：

文献信息

• Nitrogen-containing group-13 anionic compounds for olefin polymerization
  申请人：——

  公开号：US20030083515A1

  公开（公告）日：2003-05-01

  The invention addresses an composition of matter comprising a cation [Ct] + and an anion [A] − , the anion comprises a core Group-13 element bound to partially or completely fluorinated fluoroaryl ligands, at least one of the fluoroaryl ligands is substituted with a Group-15 element that has been rendered essentially inert for subsequent chemical reaction through its unbonded electron pair by substituting an electron-withdrawing group on it. [Ct] + may be selected from anilinium and ammonium cations, trityl carbenium cations, Group-11 metal cations, silylium cations, the cations of the hydrated salts of Group-1 or -2 metals, and derivatives of the foregoing anilinium, ammonium, trityl carbenium, and silylium cations containing C 1 -C 20 hydrocarbyl, hydrocarbylsilyl, or hydrocarbylamine substituents for one or more hydrogen atoms of said cations. The compositions can be used to activate olefin polymerization catalysts, and can be prepared to dissolve in aliphatic solvents. Syntheses and polymerization are illustrated.

  本发明涉及一种由阳离子 [Ct&rsqb； 和阴离子 和阴离子 [A&rsqb； - 其中阴离子包括与部分或完全氟化的氟芳基配位体结合的核心 13 族元素，氟芳基配位体中至少有一个被 15 族元素取代，该 15 族元素通过取代其上的无键电子对上的一个吸电子基团而使其在随后的化学反应中基本呈惰性； &plus； 可选自氨和铵阳离子、氨三苄阳离子、第 11 族金属阳离子、水铵阳离子、第 1 或第 2 族金属的水合盐阳离子，以及上述氨、铵、氨三苄和水铵阳离子的衍生物，这些衍生物含有 C 1 -C 20 烃基、烃基硅基或烃基胺取代基的阳离子衍生物。这些组合物可用于活化烯烃聚合催化剂，并能溶解在脂肪族溶剂中。图解说明了合成和聚合过程。
• NITROGEN-CONTAINING GROUP-13 ANIONIC COMPOUNDS FOR OLEFIN POLYMERIZATION
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：EP1268575B1

  公开（公告）日：2004-06-09
• POLYOLEFINS MADE BY CATALYST COMPRISING A NONCOORDINATING ANION AND ARTICLES COMPRISING THEM
  申请人：ExxonMobil Chemical Patents, Inc.,A Corporation of the State of Delaware

  公开号：EP1406761A2

  公开（公告）日：2004-04-14
• Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
  申请人：Pehlert James George

  公开号：US20050123778A1

  公开（公告）日：2005-06-09

  Polymers made by transition metal catalyst systems comprising a bulky noncoordinating anion (NCA) as cocatalyst component. In comparison to polymers containing a conventional NCA, these polymers show a considerably lower dielectric loss, making them suitable for insulation applications such as for power cable.
• US6809209B2
  申请人：——

  公开号：US6809209B2

  公开（公告）日：2004-10-26