sodium 3-[2-(acryloyloxy)ethoxy]-3-oxopropyl(phenyl)phosphinate | 1391721-91-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium 3-[2-(acryloyloxy)ethoxy]-3-oxopropyl(phenyl)phosphinate
• 英文别名: Sodium;[3-oxo-3-(2-prop-2-enoyloxyethoxy)propyl]-phenylphosphinate；sodium;[3-oxo-3-(2-prop-2-enoyloxyethoxy)propyl]-phenylphosphinate
• CAS: 1391721-91-7
• 化学式: C₁₄H₁₆O₆P*Na
• 分子量: 334.241
• InChiKey: YNLNPVVGSHCLHU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.38
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  92.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-羟基苯基磷酰丙酸 、 丙烯酸羟乙酯 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 、 sodium hydroxide 作用下， 以 水 为溶剂， 生成 sodium 3-[2-(acryloyloxy)ethoxy]-3-oxopropyl(phenyl)phosphinate
  参考文献：
  名称：

  Synthesis of surface-functionalized polystyrene sub-micron spheres using novel amphiphilic comonomer

  摘要：

  A facile "one-pot" emulsion polymerization is reported to prepare surface-functionalized sub-micron spheres using novel amphiphilic comonomer as the reactive emulsifier. Specifically, amphiphilic 3-[2-(acryloyloxy)ethoxy]-3-oxopropyl(phenyl) phosphinic sodium (AEOPS) was used not only as a comonomer, but also as a good emulsifier for the polymerization due to the relatively long chain of amphiphilic structure. Nearly monodisperse polystyrene sub-micron spheres with tunable sizes and zeta potentials were obtained. The phosphinic group-functionalized surfaces were demonstrated by the use of these particles to remove heavy metal ions (such as Cd2+, Pb2+) from water with a high efficiency. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2012.05.058

文献信息

• Synthesis of surface-functionalized polystyrene sub-micron spheres using novel amphiphilic comonomer
  作者：Xiaodi Pan、Jinxin Cao、Yingjie Wang、Wei Huang、Daoben Hua、Xiulin Zhu、Hongjun Liang

  DOI：10.1016/j.polymer.2012.05.058

  日期：2012.7

  A facile "one-pot" emulsion polymerization is reported to prepare surface-functionalized sub-micron spheres using novel amphiphilic comonomer as the reactive emulsifier. Specifically, amphiphilic 3-[2-(acryloyloxy)ethoxy]-3-oxopropyl(phenyl) phosphinic sodium (AEOPS) was used not only as a comonomer, but also as a good emulsifier for the polymerization due to the relatively long chain of amphiphilic structure. Nearly monodisperse polystyrene sub-micron spheres with tunable sizes and zeta potentials were obtained. The phosphinic group-functionalized surfaces were demonstrated by the use of these particles to remove heavy metal ions (such as Cd2+, Pb2+) from water with a high efficiency. (C) 2012 Elsevier Ltd. All rights reserved.