9-Phenyl-9-phosphabicyclo <3,3,1> nonan-9-oxid | 57458-74-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 9-Phenyl-9-phosphabicyclo <3,3,1> nonan-9-oxid
• 英文别名: 9-phenyl-9-phospha-bicyclo[3.3.1]nonane 9-oxide；9-Phenyl-9lambda5-phosphabicyclo[3.3.1]nonane 9-oxide；9-phenyl-9λ5-phosphabicyclo[3.3.1]nonane 9-oxide
• CAS: 57458-74-9
• 化学式: C₁₄H₁₉OP
• 分子量: 234.278
• InChiKey: SKMLTBDWAJMIFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲基锂 、 碘甲烷 、 9-Phenyl-9-phosphabicyclo <3,3,1> nonan-9-oxid 以 乙醚 为溶剂， 生成 9-Aethyl-9-phosphabicyclo <3,3,1> nonan-9-oxid
  参考文献：
  名称：

  Stereochemistry, conformations, and carbon-13 nuclear magnetic resonance spectra of 9-phenyl-9-phosphabicyclo[3.3.1]nonane derivatives

  摘要：

  DOI：

  10.1021/jo00866a001
• 作为产物：
  描述：

  9-phenyl-9-phospha-bicyclo[3.3.1]non-2-ene 9-oxide 在 platinum(IV) oxide 氢气 作用下， 以 甲醇 为溶剂， 生成 9-Phenyl-9-phosphabicyclo <3,3,1> nonan-9-oxid
  参考文献：
  名称：

  Stereochemistry, conformations, and carbon-13 nuclear magnetic resonance spectra of 9-phenyl-9-phosphabicyclo[3.3.1]nonane derivatives

  摘要：

  DOI：

  10.1021/jo00866a001

文献信息

• Process for the preparation of carboxylic anhydrides
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0111949A1

  公开（公告）日：1984-06-27

  Process for the preparation of a carboxylic anhydride by reacting under virtually water-free conditions an ester having the formula R1COOCH2R2 or an ether having the formula R3OR4 in which R1, R3 and R4 represents substituted or non-substituted hydrocarbon groups and R2 represents hydrogen or a substituted or non-substituted hydrocarbon group with carbon monoxide in the presence of a nickel catalyst, an iodide and/or bromide source and at least one co-promoter, characterized in that the reaction is carried out in the presence of a compound having the formula in which X represents phosphorus, arsenic or antimony and Y oxygen, sulphur or selenium and a and b are 0 or 1 and R5 represents hydrogen or a substituted or non-substituted hydrocarbon group and R6 and R7 represent a substituted or non-substituted hydrocarbon group, or a and b are 0 and R6 and R7 form a heterocyclic group with X and R5 represents hydrogen or a substituted or non-substituted hydrocarbon group, or in the presence of a complex of a compound having the formula I with a hydrocarbon iodide or bromide, an acyl iodide or bromide or Hl or HBr.

  在几乎无水的条件下，使式 R1COOCH2R2 的酯或式 R3OR4 的醚（其中 R1、R3 和 R4 代表取代或非取代的烃基，R2 代表氢或取代或非取代的烃基）与一氧化碳在镍催化剂、碘化源和/或溴化源以及至少一种助促进剂存在下反应制备羧酸酐的工艺，其特征在于该反应是在一种式如下的化合物存在下进行的 其中 X 代表磷、砷或锑，Y 代表氧、硫或硒，a 和 b 为 0 或 1，R5 代表氢或取代或未取代的烃基，R6 和 R7 代表取代或未取代的烃基、或 a 和 b 为 0，R6 和 R7 与 X 形成杂环基团，R5 代表氢或取代或非取代的烃基，或在具有式 I 的化合物与烃碘化物或溴化物、酰基碘化物或溴化物或 Hl 或 HBr 的络合物存在的情况下。
• Process for the preparation of esters
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0117575A1

  公开（公告）日：1984-09-05

  Process for the preparation of an ester by reacting a carboxylic acid anhydride and/or 1,1-diester with hydrogen in the presence of carbon monoxide and a homogeneous ruthenium-containing catalyst, characterized in that the reaction is carried out in the presence of hydrogen chloride or hydrogen bromide.

  在一氧化碳和均相含钌催化剂存在下，使羧酸酐和/或 1,1-二酯与氢反应制备酯的工艺，其特征在于该反应是在氯化氢或溴化氢存在下进行的。
• Process for the preparation of carboxylic acids
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0118151A1

  公开（公告）日：1984-09-12

  A process for the preparation of a carboxylic acid RCOOH wherein R represents an alkyl, cycloalkyl or aralkyl group by heating an ester of formic acid HCOOR in the presence of carbon monoxide, a soluble rhodium catalyst and an iodide and/or bromide source, characterized in that a compound of the formula wherein X represents phosphorus, arsenic or antimony and Y oxygen, sulphur or selenium and R' represents hydrogen or an unsubstituted or substituted hydrocarbyl group and either a and b independently are 0 or 1 and R2 and R3 each represent an unsubstituted or substituted hydrocarbyl group, or a and b are both 0 and R2 and R3 together with X form a heterocylic group, or a complex of a compound of formula I with a hydrocarbon iodide or bromide, and acyl iodide or bromide or a hydrogen iodide or bromide is present in the reaction mixture as promoter.

  一种制备羧酸 RCOOH（其中 R 代表烷基、环烷基或芳烷基）的工艺，其方法是在一氧化碳、可溶性铑催化剂和碘源和/或溴源存在下加热甲酸酯 HCOOR，其特征在于式中的化合物 其中 X 代表磷、砷或锑，Y 代表氧、硫或硒，R'代表氢或未取代或取代的烃基，a 和 b 分别为 0 或 1，R2 和 R3 分别代表未取代或取代的烃基、或 a 和 b 均为 0，且 R2 和 R3 与 X 共同形成杂环基，或式 I 化合物与烃碘化物或溴化物的络合物，以及酰基碘化物或溴化物或氢碘化物或溴化物作为促进剂存在于反应混合物中。
• Process for the preparation of ethanol and/or ethyl acetate
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0131998A1

  公开（公告）日：1985-01-23

  Ethanol and/or ethyl acetate are prepared by reacting methanol with carbon monoxide or a mixture of carbon monoxide and hydrogen in the presence of a catalyst system comprising (a) a ruthenium compound and optionally a rhodium compound, (b) an iodide and/or bromide of an alkali metal or alkaline earth metal and (c) an aromatic heterocyclic amine or an oxide thereof or an organic nitrogen compound containing a group

  甲醇与一氧化碳或一氧化碳与氢的混合物在催化剂体系存在下反应制备乙醇和/或乙酸乙酯，催化剂体系包括：(a)钌化合物和可选的铑化合物；(b)碱金属或碱土金属的碘化物和/或溴化物；(c)芳香杂环胺或其氧化物或含有基团的有机氮化合物。
• Process for the preparation of acetic acid and/or methyl acetate
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0133331A1

  公开（公告）日：1985-02-20

  A process for the preparation of acetic acid and/or methyl acetate by reaction of methanol with carbon monoxide in the presence of a catalyst system comprising a palladium compound which is soluble in the reaction mixture and a compound RZ, wherein R represents hydrogen or an alkyl, cycloalkyl or aralkyl group, and Z is chlorine, bromine or iodine, characterized in that in addition there are present in the catalyst system an ionic bromine or iodine compound other than HBr or HB and a sulphone or sulphoxide.

  一种通过甲醇与一氧化碳在催化剂体系存在下反应制备乙酸和/或乙酸甲酯的工艺，该催化剂体系由可溶于反应混合物的钯化合物和化合物 RZ 组成，其中 R 代表氢或烷基、环烷基或芳烷基，Z 代表氯、溴或碘，其特征在于催化剂体系中还含有除 HBr 或 HB 以外的离子型溴或碘化合物以及砜或亚砜。