4-(3-formylpropyl)-4'-methyl-2,2'-bipyridine | 115008-01-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4-(3-formylpropyl)-4'-methyl-2,2'-bipyridine
• 英文别名: 4-[2-(4-Methylpyridin-2-yl)pyridin-4-yl]butanal
• CAS: 115008-01-0
• 化学式: C₁₅H₁₆N₂O
• 分子量: 240.305
• InChiKey: NNWVDBYHZYLEJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  42.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(3-formylpropyl)-4'-methyl-2,2'-bipyridine 在 potassium permanganate 作用下， 以 丙酮 为溶剂， 以52%的产率得到4-甲基-4'-(3-羟丙基)-2,2'-双吡啶
  参考文献：
  名称：

  Synthesis of side-chain derivatives of 2,2'-bipyridine

  摘要：

  DOI：

  10.1021/jo00268a042
• 作为产物：
  描述：

  4-<3-(1,3-dioxolan-2-yl)propyl>-4'-methyl-2,2'-bipyridine 在 盐酸 作用下， 以 水 为溶剂， 生成 4-(3-formylpropyl)-4'-methyl-2,2'-bipyridine
  参考文献：
  名称：

  使用大分子钌络合物的可见光光氧化还原催化：在连续流中通过尺寸排阻纳米过滤进行反应和回收†

  摘要：

  基于[Ru（bpy）3 ] 2+的新型大分子光氧化还原催化剂已锚定在第二代PAMAM树枝状大分子上。在连续流动条件下，已探究了其在可见光照射下的催化活性以及使用有机溶剂纳米过滤和尺寸排阻膜的可回收性。

  DOI：

  10.1039/c6cy00070c

文献信息

• Compounds and methods for nucleic acid mismatch detection
  申请人：Barton K. Jacqueline

  公开号：US20070224612A1

  公开（公告）日：2007-09-27

  In accordance with the present invention there are provided sterically demanding intercalators. These compounds are useful for detection of a base-pair mismatch, such as by measuring fluorescence of complexes formed by the compounds of the invention and nucleic acid duplexes. The compounds are also capable of catalyzing photolytic cleavage of nucleic acids.

  根据本发明，提供了具有立体位阻的插入剂。这些化合物可用于检测碱基对不匹配，例如通过测量本发明化合物和核酸双链形成的复合物的荧光。这些化合物还能够催化光解核酸。
• An Acetylacetonate-Based Semiconductor−Sensitizer Linkage
  作者：Todd A. Heimer、Samuel T. D'Arcangelis、Fereshteh Farzad、Jeremy M. Stipkala、Gerald J. Meyer

  DOI：10.1021/ic960419j

  日期：1996.1.1

  Coordination compounds of the general type Ru(dmb)(2)(LL)(PF6)(2), where dmb is 4,4'-(CH3)(2)-2,2'-bipyridine and LL is 4-(CH3)-4'-(COOH)-2,2'-bipyridine, or 4-(CH3)-4'-((CH2)(3)COOH)-2,2'-bipyridine, or 4-(CH3)-4'-((CH2)(3)-COCH2COOC2H5)-2,2'-bipyridine were prepared for the attachment to semiconductor metal oxide surfaces. The optical and redox properties of these compounds in dichloromethane solution are reported. Binding to porous nanostructured TiO2 films was analyzed with the Langmuir adsorption isotherm model. Photoelectrochemical measurements of the modified TiO2 electrodes in regenerative solar cells are reported. The results indicate that intimate electronic coupling between the surface link and the chromophoric ligand is not a strict requirement in the design of sensitizers for photovoltaic applications. Interfacial kinetics for recombination of the electron in the solid with the oxidized form of the sensitizer were quantitated by excited state absorption spectroscopy.
• CIANA, LEOPOLDO DELLA;HAMACHI, ITARU;MEYER, THOMAS J., J. ORG. CHEM., 54,(1989) N, C. 1731-1735
  作者：CIANA, LEOPOLDO DELLA、HAMACHI, ITARU、MEYER, THOMAS J.

  DOI：——

  日期：——
• US7786298B2
  申请人：——

  公开号：US7786298B2

  公开（公告）日：2010-08-31
• Visible-light photoredox catalysis using a macromolecular ruthenium complex: reactivity and recovery by size-exclusion nanofiltration in continuous flow
  作者：Javier Guerra、David Cantillo、C. Oliver Kappe

  DOI：10.1039/c6cy00070c

  日期：——

  A novel macromolecular photoredox catalyst based on [Ru(bpy)3]2+ anchored to a 2nd-generation PAMAM dendrimer has been developed. Its catalytic activity under visible light irradiation and recyclability using organic solvent nanofiltration with a size-exclusion membrane have been explored under continuous flow conditions.

  基于[Ru（bpy）3 ] 2+的新型大分子光氧化还原催化剂已锚定在第二代PAMAM树枝状大分子上。在连续流动条件下，已探究了其在可见光照射下的催化活性以及使用有机溶剂纳米过滤和尺寸排阻膜的可回收性。