2-<1-Hydroxy-2-methyl-propyl>-tetrahydrofuran | 98560-53-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: 2-<1-Hydroxy-2-methyl-propyl>-tetrahydrofuran
• 英文别名: 2-methyl-1-tetrahydrofuran-2-yl-propan-1-ol；Tetrahydro-I+/--(1-methylethyl)-2-furanmethanol；2-methyl-1-(oxolan-2-yl)propan-1-ol
• CAS: 98560-53-3
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: KQVYEXTYADJAFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• METHOD FOR THE PRODUCTION OF ALIPHATIC ALCOHOLS AND/OR THEIR ETHERS, IN PARTICULAR, 1-OCTANOL
  申请人：Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen

  公开号：US20150141704A1

  公开（公告）日：2015-05-21

  A method for the production of aliphatic alcohols and/or their ethers, comprising the step of reacting a substrate of the general formula (I): in which m is 0, 1, 2, 3, 4, 5, 6, 7, 8 or 9 and n is 1 or 2; R1 is hydrogen, a linear, branched or cyclic alkyl rest, a primary alkanol rest, an aryl rest or one of the following radicals: and R2 is hydrogen or —CH 2 OH; with hydrogen in the presence of a hydrogenation catalyst system, wherein the hydrogenation catalyst system comprises: a hydrogenation catalyst comprising Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and/or Pt; and an acidic additive selected from the group of organoperfluorocarboxylic acids, hydrochloric acid, formic acid, acetic acid, phosphoric acid, sulfuric acid, sulfonic acid and/or organic compounds comprising sulfonic acid groups, phosphoric acid groups and/or phosphonic acid groups; with the proviso that the acidic additive is a liquid and/or at least partially dissolved in the substrate (I) during the reaction of (I) with hydrogen in the case that R2 is CH 2 OH.
• US9162949B2
  申请人：——

  公开号：US9162949B2

  公开（公告）日：2015-10-20