2,2,5,5-Tetraphenylhexanedinitrile | 72108-25-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2,5,5-Tetraphenylhexanedinitrile
• CAS: 72108-25-9
• 化学式: C₃₀H₂₄N₂
• 分子量: 412.5
• InChiKey: NSANGDFWEISFLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二苯乙腈 、 1,2-二氯乙烷 生成 2,2,5,5-Tetraphenylhexanedinitrile
  参考文献：
  名称：

  GALL M. U.; SALMON-LEGAGNEUR F.; LE MOAL H., J. CHEM. RES. SYNOP., 1978, NO 6, 198-199

  摘要：

  DOI：

文献信息

• Method for the production of a polymerisation reaction product
  申请人：——

  公开号：US20040034182A1

  公开（公告）日：2004-02-19

  A process for the preparation of a reaction product (A) comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction, in the presence of at least one compound of the formula (I) 1 where R 1 to R 4 , independently of one another, are each hydrogen, methyl or a group which stabilizes radicals and/or is bulky and which is selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, a cycloalkyl, alcohol, ether, polyether, amine or aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another, are each defined in the same way as R 1 to R 4 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 4 are a group which stabilizes radicals and/or is bulky, as defined above, and diphenylethylene, dinaphthylethylene, 4,4′-vinylidenebis(N,N′-dimethylaniline), 4,4′-vinylidenebis(aminobenzene), cis- and trans-stilbene and mixtures of two or more thereof are excluded as compounds of the formula (I), and a process for the preparation of a reaction product (A′) comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction, in the presence of at least one compound of the formula (II) 2 where R 1 to R 4 and R 11 and R 12 , independently of one another, are each hydrogen, methyl or a group which stabilizes radicals and/or is bulky and which is selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, a cycloalkyl, alcohol, ether, polyether, amine or aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another, are each defined in the same way as R 1 to R 4 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 4 are a group which stabilizes radicals and/or is bulky, as defined above.

  一种制备反应产物（A）的方法包括以下步骤（i）：（i）在自由基条件下，反应混合物至少包括一种自由基反应的单体（a），在至少一种化合物（I）1的存在下反应，其中R1至R4独立地是氢、甲基或稳定自由基和/或是笨重的基团，选择自未取代或取代的、线性或支链的含有两个或更多碳原子的烷基、环烷基、醇、醚、聚醚、胺或芳基烷基、取代或未取代的芳香、杂环或烯烃烃基、卤素原子、取代或未取代的、线性或支链的烯基或炔基、—C（O）R5、—C（O）OR5、—CR5R6—O—R7、—O—C（O）R5、—CN、—O—CN、—S—CN、—O—C═NR5、—S—C═NR5、—O—CR5R6—CR7R8NR9R10、—N═C═O、—C═NR5、—CR5R6-Hal、—C（S）R5、—CR5R6—P（O）R7R8、—CR5R6—PR7R8、—CR5R6—NR7R8、—CR5R6（OR7）（OR8）、—CR5R6（OR7）（NR8）、—CR5R6（NR7）（NR8）、酐、缩醛或缩酮基团、—SO2R5、酰胺基团、—NR5C（S）NR6、—NR5C（S）—OR6、—N═C═S、—NO2、—C═N—OH、—N（R5）═NR6、—PR5R6R7、—OSiR5R6R7或—SiR5R6R7，其中R5至R10独立地与R1至R4的定义相同，或者R1至R4中的两个基团形成一个C4-C7环，该环可以被取代或未取代，并且可能含有一个或多个杂原子，但需注意至少有两个基团R1至R4是稳定自由基和/或笨重的基团，如上所定义，而联苯乙烯、二萘乙烯、4,4′-乙烯基双（N,N′-二甲基苯胺）、4,4′-乙烯基双（氨基苯）和顺式和反式的蒽烯及其混合物被排除在化合物（I）的定义之外，以及一种制备反应产物（A′）的方法包括以下步骤（i）：（i）在自由基条件下，反应混合物至少包括一种自由基反应的单体（a），在至少一种化合物（II）2的存在下反应，其中R1至R4和R11和R12独立地是氢、甲基或稳定自由基和/或是笨重的基团，选择自未取代或取代的、线性或支链的含有两个或更多碳原子的烷基、环烷基、醇、醚、聚醚、胺或芳基烷基、取代或未取代的芳香、杂环或烯烃烃基、卤素原子、取代或未取代的、线性或支链的烯基或炔基、—C（O）R5、—C（O）OR5、—CR5R6—O—R7、—O—C（O）R5、—CN、—O—CN、—S—CN、—O—C═NR5、—S—C═NR5、—O—CR5R6—CR7R8NR9R10、—N═C═O、—C═NR5、—CR5R6-Hal、—C（S）R5、—CR5R6—P（O）R7R8、—CR5R6—PR7R8、—CR5R6—NR7R8、—CR5R6（OR7）（OR8）、—CR5R6（OR7）（NR8）、—CR5R6（NR7）（NR8）、酐、缩醛或缩酮基团、—SO2R5、酰胺基团、—NR5C（S）NR6、—NR5C（S）—OR6、—N═C═S、— 、—C═N—OH、—N（R5）═NR6、—PR5R6R7、—OSiR5R6R7或—SiR5R6R7，其中R5至R10独立地与R1至R4的定义相同，或者R1至R4中的两个基团形成一个C4-C7环，该环可以被取代或未取代，并且可能含有一个或多个杂原子，但需注意至少有两个基团R1至R4是稳定自由基和/或笨重的基团，如上所定义。
• Inks for inkjet printers
  申请人：LAMBERTI SPA

  公开号：US10190006B2

  公开（公告）日：2019-01-29

  Method for decorating green or fired ceramic bodies by inkjet printing including the use of a ceramic inkjet ink which is prepared by milling a ceramic inorganic pigment in an organic medium in the presence of a dispersing agent which is the reaction product of a polyethyleneimine and a 12-hydroxystearic acid and ε-caprolactone co-polyester, until the average particle size of the pigment is between 0.1 and 0.8 μm.

  用喷墨打印装饰绿色或烧成陶瓷体的方法，包括使用陶瓷喷墨墨水，该墨水是在有机介质中，在聚乙烯亚胺和 12-羟基硬脂酸和ε-己内酯共聚聚酯的反应产物的分散剂存在下，研磨陶瓷无机颜料制备的，直到颜料的平均粒径在 0.1 至 0.8 μm 之间。
• Polyvinyl acetal resin composition, film for laminated glass, and laminated glass
  申请人：SKC Co., Ltd.

  公开号：US11248146B2

  公开（公告）日：2022-02-15

  The polyvinyl acetal resin composition includes: a polyvinyl acetal resin, a plasticizer, a metal salt compound, and a benzotriazole-based compound, wherein the metal salt compound is a metal salt of hydroxyl carboxyl acid having two to sixteen carbon atoms, wherein the metal salt compound is included in an amount of less than 0.05 wt % based on a total weight of the polyvinyl acetal resin composition, and wherein the metal salt compound is included in an amount of 16 parts by weight or less based on the benzotriazole-based compound of 100 parts by weight.

  聚乙烯醇缩醛树脂组合物包括：聚乙烯醇缩醛树脂、增塑剂、金属盐化合物和苯并三唑基化合物，其中金属盐化合物是具有 2 至 16 个碳原子的羟基羧酸的金属盐，其中金属盐化合物的加入量小于 0.05 重量％，其中金属盐化合物的加入量为 100 重量份苯并三唑基化合物的 16 重量份或以下。
• Composition and method for manufacturing a film comprising thiourethane layer
  申请人：SKC Co., Ltd.

  公开号：US11434336B2

  公开（公告）日：2022-09-06

  A film for glass bonding includes a thiourethane layer comprising a heterocyclo-alkanediyl-based repeat unit indicated by Formula 1, and a linear alkanediyl-based repeat unit indicated by Formula 2, and a base layer, disposed on a surface of the thiourethane layer, comprising a polyvinyl acetal resin and a plasticizer. In the Formula 1, R1 is —O— or —S—, and X is a heterocyclo-alkanediyl group having carbon atoms of 3 to 10 and sulfur atoms of 1 to 5, and in the Formula 2, R2 is —O— or —S—, and n2 is an integer of 4 to 10.

  用于玻璃粘接的薄膜包括一层硫代氨基甲酸乙酯，该层由式 1 所示的杂环烷二基重复单元组成、 和式 2 所示的线性烷二基重复单元、 和底层，底层置于硫氨酯层的表面，由聚乙烯醇缩醛树脂和增塑剂组成。在式 1 中，R1 是-O-或-S-，X 是具有 3 至 10 个碳原子和 1 至 5 个硫原子的杂环烷二基，在式 2 中，R2 是-O-或-S-，n2 是 4 至 10 的整数。
• Method for making polymers of alpha-hydroxy acids
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0627453B1

  公开（公告）日：1998-02-04