1,2,4-Triphenyl-3,5,6-tricarboxybenzol | 96176-07-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,4-Triphenyl-3,5,6-tricarboxybenzol
• 英文别名: 3,5,6-Triphenylbenzene-1,2,4-tricarboxylic acid
• CAS: 96176-07-7
• 化学式: C₂₇H₁₈O₆
• 分子量: 438.436
• InChiKey: HXIQMTHENSNMLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,2,4-Triphenyl-3,5,6-tricarboxybenzol 在 硫酸 作用下， 反应 0.08h， 以40%的产率得到9,14,15-Trioxo-14,15-dihydro-9H-diindeno<1,2-a;2',1'-c>fluoren
  参考文献：
  名称：

  Facile Multistep Synthesis of Isotruxene and Isotruxenone

  摘要：

  Three multistep approaches toward facile syntheses of isotruxene (1) and isotruxenone (3) are reported. The ortho-para conjugated backbone in the precursor 4 was constructed by either Co-catalyzed [2 + 2 + 2] cyclotrimerization or the [4 + 2] Diels-Alder reactions. The regioselectivity of the triple intramolecular Friedel-Crafts acylation of 4 plays the key role in determining the overall yield. Compared to the previous one-step method, the current approaches are more efficient in terms of product yield (27-36% vs 4-18%) and purification (i.e., free of column chromatography).

  DOI：

  10.1021/jo900299q
• 作为产物：
  描述：

  1,2,4-trimethyl-3,5,6-triphenylbenzene 在 吡啶 、 potassium permanganate 作用下， 以 水 为溶剂， 反应 19.5h， 以90%的产率得到1,2,4-Triphenyl-3,5,6-tricarboxybenzol
  参考文献：
  名称：

  Facile Multistep Synthesis of Isotruxene and Isotruxenone

  摘要：

  Three multistep approaches toward facile syntheses of isotruxene (1) and isotruxenone (3) are reported. The ortho-para conjugated backbone in the precursor 4 was constructed by either Co-catalyzed [2 + 2 + 2] cyclotrimerization or the [4 + 2] Diels-Alder reactions. The regioselectivity of the triple intramolecular Friedel-Crafts acylation of 4 plays the key role in determining the overall yield. Compared to the previous one-step method, the current approaches are more efficient in terms of product yield (27-36% vs 4-18%) and purification (i.e., free of column chromatography).

  DOI：

  10.1021/jo900299q

文献信息

• Preparation of branched polycarbonates
  申请人：THE COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH

  公开号：EP0801089A1

  公开（公告）日：1997-10-15

  The invention provides process for the preparation of a branched poly(arylcarbonate) suitable for use in blow molding, which process comprises subjecting a linear (arylcarbonate) crystallized oligomer derived from a dihydroxy diaryl compound and a diarylcarbonate to solid state polycondensation by heating the oligomer at a temperature, which is higher than its glass transition temperature but below its melting point, in the presence of a multifunctional phenol and, optionally, a catalyst, under an inert atmosphere.

  本发明提供了制备适用于吹塑成型的支化聚(芳基碳酸酯)的工艺，该工艺包括在惰性气氛下，将由二羟基二芳基化合物和二芳基碳酸酯衍生的线性(芳基碳酸酯)结晶低聚物在高于其玻璃化温度但低于其熔点的温度下加热，使其固态缩聚。
• Huebel,W.; Hoogzand,C., Chemische Berichte, 1960, vol. 93, p. 103 - 115
  作者：Huebel,W.、Hoogzand,C.

  DOI：——

  日期：——
• Thermoplastic Resin Composition and Optical Element Utilizing the Same
  申请人：Kikuchi Masako

  公开号：US20070265381A1

  公开（公告）日：2007-11-15

  A thermoplastic resin composition comprising a thermoplastic resin and inorganic particles dispersed in the thermoplastic resin, the thermoplastic resin being melt-moldable, wherein n d and v d of the thermoplastic resin composition satisfy Formula (1), provided that n d represents a refractive index measured at a wavelength of 588 nm and v d represents an Abbe's number: n d >1.82−0.0042 v d Formula (1)
• US5710238A
  申请人：——

  公开号：US5710238A

  公开（公告）日：1998-01-20
• Facile Multistep Synthesis of Isotruxene and Isotruxenone
  作者：Jye-Shane Yang、Hsin-Hau Huang、Shih-Hsun Lin

  DOI：10.1021/jo900299q

  日期：2009.5.15

  Three multistep approaches toward facile syntheses of isotruxene (1) and isotruxenone (3) are reported. The ortho-para conjugated backbone in the precursor 4 was constructed by either Co-catalyzed [2 + 2 + 2] cyclotrimerization or the [4 + 2] Diels-Alder reactions. The regioselectivity of the triple intramolecular Friedel-Crafts acylation of 4 plays the key role in determining the overall yield. Compared to the previous one-step method, the current approaches are more efficient in terms of product yield (27-36% vs 4-18%) and purification (i.e., free of column chromatography).