{2-[2-(5,6-Dimethoxy-1H-inden-2-yl)-4,5-dimethoxy-phenyl]-ethyl}-dimethyl-amine | 57085-39-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: {2-[2-(5,6-Dimethoxy-1H-inden-2-yl)-4,5-dimethoxy-phenyl]-ethyl}-dimethyl-amine
• CAS: 57085-39-9
• 化学式: C₂₃H₂₉NO₄
• 分子量: 383.488
• InChiKey: SJXJCWPXXPHDLI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  {2-[2-(5,6-Dimethoxy-1H-inden-2-yl)-4,5-dimethoxy-phenyl]-ethyl}-dimethyl-amine 生成 2-(2-ethenyl-4,5-dimethoxyphenyl)-5,6-dimethoxy-1H-indene
  参考文献：
  名称：

  Synthesis of the ochotensine type 1-spiroisoquinoline. Dimsylsodiuminduced rearrangement of N-methyltetrahydroprotoberberinium salts.

  摘要：

  The Stevens rearrangement of the N-methyltetrahydroprotoberberinium iodide (3) in the presence of sodium methylsulfinylmethanide afforded the ochotensine type 1-spiroisoquinoline (4), the structure of which was determined by the chemical and spectroscopic methods.

  DOI：

  10.1248/cpb.23.1171
• 作为产物：
  描述：

  在 dimsylsodium 作用下， 以 二甲基亚砜 为溶剂， 生成 {2-[2-(5,6-Dimethoxy-1H-inden-2-yl)-4,5-dimethoxy-phenyl]-ethyl}-dimethyl-amine
  参考文献：
  名称：

  Synthesis of the ochotensine type 1-spiroisoquinoline. Dimsylsodiuminduced rearrangement of N-methyltetrahydroprotoberberinium salts.

  摘要：

  The Stevens rearrangement of the N-methyltetrahydroprotoberberinium iodide (3) in the presence of sodium methylsulfinylmethanide afforded the ochotensine type 1-spiroisoquinoline (4), the structure of which was determined by the chemical and spectroscopic methods.

  DOI：

  10.1248/cpb.23.1171