Acetic acid (4S,5R,7S,8R,9R,10R,14S)-4,5,14,17-tetramethyl-3-oxo-2,3,4,5,6,7,8,9,10,11,12,14,15,16-tetradecahydro-1H-cyclopenta[a]phenanthren-7-yl ester | 79839-08-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: Acetic acid (4S,5R,7S,8R,9R,10R,14S)-4,5,14,17-tetramethyl-3-oxo-2,3,4,5,6,7,8,9,10,11,12,14,15,16-tetradecahydro-1H-cyclopenta[a]phenanthren-7-yl ester
• CAS: 79839-08-0
• 化学式: C₂₃H₃₄O₃
• 分子量: 358.521
• InChiKey: TUQFJOALELKICY-VREQWWOWSA-N

反应信息

• 作为产物：
  描述：

  2-((3E,7E)-5-Hydroxy-7-methyl-trideca-3,7-dien-11-ynyl)-1,3-dimethyl-cyclopent-2-enol 、 乙酸酐 在 吡啶 、 氢氧化钾 作用下， 生成 Acetic acid (4S,5R,7S,8R,9R,10R,14S)-4,5,14,17-tetramethyl-3-oxo-2,3,4,5,6,7,8,9,10,11,12,14,15,16-tetradecahydro-1H-cyclopenta[a]phenanthren-7-yl ester 、 Acetic acid (3aS,3bR,4S,5aS,8aR,8bR)-6-acetyl-1,3a,5a-trimethyl-2,3,3a,3b,4,5,5a,6,7,8,8a,8b,9,10-tetradecahydro-dicyclopenta[a,f]naphthalen-4-yl ester 、 Acetic acid (3aS,3bR,4S,5aR,8aR,8bR)-6-acetyl-1,3a,5a-trimethyl-2,3,3a,3b,4,5,5a,6,7,8,8a,8b,9,10-tetradecahydro-dicyclopenta[a,f]naphthalen-4-yl ester
  参考文献：
  名称：

  Corticoid synthesis via vinylic fluoride-terminated biomimetic polyene cyclizations

  摘要：

  DOI：

  10.1021/jo00340a040