Acetic acid (3S,5S,6S,8S,9R,10S,13R,14S,15R,16R,17R)-3,6-diacetoxy-8,16-dihydroxy-17-((1R,5S)-6-hydroxy-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-15-yl ester | 94739-68-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: Acetic acid (3S,5S,6S,8S,9R,10S,13R,14S,15R,16R,17R)-3,6-diacetoxy-8,16-dihydroxy-17-((1R,5S)-6-hydroxy-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-15-yl ester
• CAS: 94739-68-1
• 化学式: C₃₃H₅₄O₉
• 分子量: 594.786
• InChiKey: SQJFSGCAOFQCRD-KVGJSRLOSA-N

反应信息

• 作为反应物：
  描述：

  (R)-methoxytrifluoromethylphenylacetyl chloride 、 Acetic acid (3S,5S,6S,8S,9R,10S,13R,14S,15R,16R,17R)-3,6-diacetoxy-8,16-dihydroxy-17-((1R,5S)-6-hydroxy-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-15-yl ester 以 吡啶 为溶剂， 生成 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (2S,6R)-2-methyl-6-((3S,5S,6S,8S,9R,10S,13R,14S,15R,16R,17R)-3,6,15-triacetoxy-8,16-dihydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-yl)-heptyl ester
  参考文献：
  名称：

  D'Auria, Maria Valeria; Minale, Luigi; Pizza, Cosimo, Gazzetta Chimica Italiana, 1984, vol. 114, # 9/10, p. 469 - 470

  摘要：

  DOI：
• 作为产物：
  描述：

  Acetic acid (3S,5S,6S,8S,9R,10S,13R,14S,15R,16R,17R)-3,6-diacetoxy-17-((1R,5S)-1,5-dimethyl-6-trityloxy-hexyl)-8,16-dihydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-15-yl ester 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 反应 12.0h， 生成 Acetic acid (3S,5S,6S,8S,9R,10S,13R,14S,15R,16R,17R)-3,6-diacetoxy-8,16-dihydroxy-17-((1R,5S)-6-hydroxy-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-15-yl ester
  参考文献：
  名称：

  D'Auria, Maria Valeria; Minale, Luigi; Pizza, Cosimo, Gazzetta Chimica Italiana, 1984, vol. 114, # 9/10, p. 469 - 470

  摘要：

  DOI：