[(2S,3R,6S)-6-Allyl-3-(tetrahydro-pyran-2-yloxy)-3,6-dihydro-2H-pyran-2-ylmethoxy]-tert-butyl-dimethyl-silane | 97102-58-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 英文名称: [(2S,3R,6S)-6-Allyl-3-(tetrahydro-pyran-2-yloxy)-3,6-dihydro-2H-pyran-2-ylmethoxy]-tert-butyl-dimethyl-silane
• CAS: 97102-58-4
• 化学式: C₂₀H₃₆O₄Si
• 分子量: 368.589
• InChiKey: MSFOLYGFDGBRMS-TUVJXNFZSA-N

反应信息

• 作为反应物：
  描述：

  [(2S,3R,6S)-6-Allyl-3-(tetrahydro-pyran-2-yloxy)-3,6-dihydro-2H-pyran-2-ylmethoxy]-tert-butyl-dimethyl-silane 在 sodium hydroxide 、 9-borabicyclo[3.3.1]nonane dimer 、 双氧水 作用下， 生成 3-[(2S,5R,6S)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-5-(tetrahydro-pyran-2-yloxy)-5,6-dihydro-2H-pyran-2-yl]-propan-1-ol
  参考文献：
  名称：

  Methods for pyranoannulation: an approach to a new class of polyethers

  摘要：

  Several methods have been developed for fusing a pyran ring to an existing pyran ring structure such that the ring oxygens assume a vicinal (ethylene glycol) relationship. The tricyclic structure 13, a previously unknown substance, was prepared through a combination of these methods.

  DOI：

  10.1021/jo00216a049