| 130918-21-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• CAS: 130918-21-7
• 化学式: C₅₄H₄₉N₃O₂₀
• 分子量: 1059.99
• InChiKey: QTDOGWABANLNLG-UFNHZTLPSA-N

反应信息

• 作为反应物：
  描述：

  sodium methylate 、 以 甲醇 为溶剂， 生成 4-methoxy-3-(2,3,4-trimethoxy-6-methoxycarbonyl-phenyl)-phenazine-2-carboxylic acid methyl ester 、 dimethyl (R)-4,4',5,5',6,6'-hexamethoxybiphenyl-2,2'-dicarboxylate
  参考文献：
  名称：

  Tannins and related compounds. XCII. Isolation and characterization of cyanogenic ellagitannins, aleurinins A and B, and a related O-glycosidic ellagitannin, aleurinin C, from Aleurites fordii Hemsley.

  摘要：

  A chemical examination of the tannin ingredients in the leaves of the wood oil tree, Aleurites fordii HEMSLEY (Euphorbiaceae), has led to the isolation of three new ellagitannins named aleurinins A (4), B(5) and C(6), together with corilagin (1), geraniin (2) and chebulagic acid (3). on the basis of chemical and spectroscpic evidence, the structures of aleurinins A (4) and B (5) have been established as ellagitannins possessing a novel cyanopropylene alcohol glucoside core, while aleurinin C (6) has been characterized as an ellagitannin based on a hydroxyacetone glucoside core.

  DOI：

  10.1248/cpb.38.861
• 作为产物：
  描述：

  重氮甲烷 、 2-[[(1S,2R,27R,28R,30R)-17,20,21,22,36,37,38,41,42,43-decahydroxy-4,25,33,46-tetraoxo-3,26,29,32,47-pentaoxa-8,15-diazanonacyclo[25.20.0.02,30.05,18.07,16.09,14.019,24.034,39.040,45]heptatetraconta-5,7,9,11,13,15,17,19,21,23,34,36,38,40,42,44-hexadecaen-28-yl]oxymethyl]prop-2-enenitrile 以 甲醇 、 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Tannins and related compounds. XCII. Isolation and characterization of cyanogenic ellagitannins, aleurinins A and B, and a related O-glycosidic ellagitannin, aleurinin C, from Aleurites fordii Hemsley.

  摘要：

  A chemical examination of the tannin ingredients in the leaves of the wood oil tree, Aleurites fordii HEMSLEY (Euphorbiaceae), has led to the isolation of three new ellagitannins named aleurinins A (4), B(5) and C(6), together with corilagin (1), geraniin (2) and chebulagic acid (3). on the basis of chemical and spectroscpic evidence, the structures of aleurinins A (4) and B (5) have been established as ellagitannins possessing a novel cyanopropylene alcohol glucoside core, while aleurinin C (6) has been characterized as an ellagitannin based on a hydroxyacetone glucoside core.

  DOI：

  10.1248/cpb.38.861