bis[1-(2-naphthyliminomethyl)-2-naphtholato-N,O]nickel(II) | 195527-72-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis[1-(2-naphthyliminomethyl)-2-naphtholato-N,O]nickel(II)
• 英文别名: bis[N-(β-naphthyl)-2-oxy-1-naphthaldiminato]nickel(II)
• CAS: 195527-72-1
• 化学式: C₄₂H₂₈N₂NiO₂
• 分子量: 651.387
• InChiKey: CBVIKAOCVDAXOZ-VMERTWADSA-L

反应信息

• 作为产物：
  描述：

  2-萘胺 、 2-羟基-1-萘甲醛 、 nickel(II) chloride hexahydrate 以 not given 为溶剂， 生成 bis[1-(2-naphthyliminomethyl)-2-naphtholato-N,O]nickel(II)
  参考文献：
  名称：

  Bis[N-(β-naphthyl)-2-oxy-1-naphthaldiminato]nickel(II)

  摘要：

  There is a remarkable stereochemical difference between the free ligand and that coordinated to the Ni atom in the title compound {systematic name: bis[1-(2-naphthyliminomethyl)-2-naphtholato-N,O]nickel(II), [Ni(C21H14NO)(2)]}. Upon coordination, the orientation of the N-(beta-naphthyl)-2-oxy-1-naphthaldimine ligand (which is almost planar in the solid state when uncomplexed) is changed so that the plane of the N-beta-naphthyl substituent is almost normal to the plane of the naphthaldiminato moiety. Two bidentate ligands coordinate to the Ni atom (which lies on an inversion centre) with their O and N atoms in a (necessarily) trans arrangement and forming a stepped conformation with a mean chelate-plane vertical separation of 0.639 (2) Angstrom. Main dimensions are Ni-O 1.820 (2), Ni-N 1.901 (2) Angstrom and O-Ni-N 91.75 (7)degrees.

  DOI：

  10.1107/s0108270197007038