4-(benzylideneimino)resorcinol hydrochloride | 286386-41-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-(benzylideneimino)resorcinol hydrochloride
• CAS: 286386-41-2
• 化学式: C₁₃H₁₁NO₂*ClH
• 分子量: 249.697
• InChiKey: WQDAJSYPWFVQMX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  bis(triphenylphosphane)copper(I) nitrate 、 4-(benzylideneimino)resorcinol hydrochloride 在 NaOCH₃ 作用下， 以 甲醇 为溶剂， 以78%的产率得到(P(C6H5)3)2copper(I)((4-benzylideneamino)resocinolate)
  参考文献：
  名称：

  Copper(I) complexes with N,O-donor Schiff base ligands related to intermediate forms of the TPQ cofactor in amine oxidases

  摘要：

  Neutral complexes (PPh3)(2)Cu(L) were obtained from (PPh3)(2)Cu(NO3) and the deprotonated forms of the three Schiff base ligands 2-(benzylideneimino)phenol (BimOH), 4-(benzylideneimino)resorcinol (Bim(OH)(2)) and N-(2,4-dihydroxy-5-isopropylphenyl)acetamide (DipaH(3)). The ligands were designed to model aminated intermediate forms of the topaquinone (TPQ) cofactor in the enzymatic cycle of copper-dependent amine oxidases. The ligands L are coordinated to the metal centers through imine-N and phenolate-O donor atoms to form five-membered chelate rings, in contrast to the six-membered chelate rings of salen-type Schiff base ligands. Compound (Bim(OH)O)Cu(PPh3)(2). 0.5CH(3)OH was structurally analyzed, it exhibits intramolecular aryl-aryl interactions between the ligands and intermolecular hydrogen bonds involving the free phenolic hydroxyl substituent, the coordinated phenolate oxygen atom and the methanol solvate molecule. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00612-x