1,10-phenanthroline-2,9-dicarboxaldehyde-di-picolinohydrazone | 1217204-98-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1,10-phenanthroline-2,9-dicarboxaldehyde-di-picolinohydrazone
• CAS: 1217204-98-2
• 化学式: C₂₆H₁₈N₈O₂
• 分子量: 474.481
• InChiKey: OQLXGAFGSNGWID-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  硫氰酸铵 、 cadmium(II) perchlorate hexahydrate 、 1,10-phenanthroline-2,9-dicarboxaldehyde-di-picolinohydrazone 以 甲醇 、 氯仿 为溶剂， 以56%的产率得到Cd(1,10-phenanthroline-2,9-dicarboxaldehyde-di-picolinohydrazone)(SCN)2
  参考文献：
  名称：

  One Cadmium(II) Complex of a New Polydentate Double Schiff Base Ligand Derived from 1,10-phenanthroline: Syntheses, Structures, and Fluorescent Property

  摘要：

  One Cd(II) complex of a new polydentate double Schiff base ligand 1,10-phenanthroline-2,9-dicarboxaldehyde-di-picolinohydrazone (L), [Cd(L)(SCN)2], was synthesized and structurally characterized. This compound belongs to a monoclinic system with space group C2/c. In this monomer, the cadmium metal center is coordinated to four nitrogen atoms and two oxygen atoms from one organic ligand L acting as a hexadentate chelate, and two nitrogen atoms from two distinct SCN- anions, forming an uncommon distorted hexagonal bipyramid coordination geometry. Furthermore, fluorescent and thermal properties of the complex were performed on the powder sample. The complex strongly emits at 467 nm with the excitation of 410 nm and is thermally stable up to 300 degrees C, and thus can be utilized as one potential fluorescent material.

  DOI：

  10.1080/15533170903492853