gold(I) O,O'-di(methyl)dithiophosphate dimer | 468712-93-8

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: gold(I) O,O'-di(methyl)dithiophosphate dimer
• CAS: 468712-93-8
• 化学式: C₄H₁₂Au₂O₄P₂S₄
• 分子量: 708.281
• InChiKey: VGZQERPWTPWTEA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  氯(二甲基硫化)金(I) 、 以 二氯甲烷 为溶剂， 生成 gold(I) O,O'-di(methyl)dithiophosphate dimer
  参考文献：
  名称：

  Multiple Emissions and Brilliant White Luminescence from Gold(I) O,O‘-Di(alkyl)dithiophosphate Dimers

  摘要：

  The Au(I) dimers Au(2)[S(2)P(OR)(2)](2) for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au...Au chains with intermolecular contacts (3.09-3.16 A) similar to the Au...Au distances within the dimers (3.10-3.18 A). The dimers are luminescent in the solid state and become brilliantly emissive at low temperatures. At 77 K, Au(2)[S(2)P(OMe)(2)](2) shows multiple emission bands. The two higher energy bands at 415 and 456 nm are assigned to (1)MC and (3)MC on the basis of lifetime measurements (20 ns and 2.16 micros, respectively) and concentration-related effects, while the lower energy band at 560 nm is attributed to a LMCT excited state. In frozen glasses of different solvents, Au(2)[S(2)P(OMe)(2)](2) as well as the Et and n-Pr derivatives exhibit a bright luminescence of different colors and striking thermochromism of the emission.

  DOI：

  10.1021/ja0267876