| 1097721-83-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 1097721-83-9
• 化学式: C₄₀H₅₁NSi
• 分子量: 573.937
• InChiKey: HWGIYEXXHGYUNA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  42.0
• 可旋转键数：
  0.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  在 水 、 potassium hydroxide 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 2.0h， 以98%的产率得到5,11-Ditert-butyl-17-ethynyl-8,8,14,14,22,22-hexamethyl-1-azahexacyclo[11.7.1.13,19.02,7.09,21.015,20]docosa-2,4,6,9,11,13(21),15(20),16,18-nonaene
  参考文献：
  名称：

  Bridged Triphenylamine-Based Dendrimers: Tuning Enhanced Two-Photon Absorption Performance with Locked Molecular Planarity

  摘要：

  Triphenylamine derivatives bridged by methylene units afford a near planar molecular platform In a series of one dimer and two oligomers exhibiting Increased structural rigidity compared to that of their parent triphenylamines. This series of dendrimers show significantly enhanced two-photon absorptions that are up to 3-fold that of triphenylamines with similar molecular size and structure.

  DOI：

  10.1021/ol801238n
• 作为产物：
  描述：

  2-bromo-6,10-di-tert-butyl-4,4,8,8,12,12-hexamethyl-4H,8H,12H-benzo-[1,9]quinolizino[3,4,5,6,7-defg]acridine 、 三甲基乙炔基硅 在 copper(l) iodide 、 四(三苯基膦)钯 、 三乙胺 作用下， 反应 15.0h， 以53%的产率得到
  参考文献：
  名称：

  Bridged Triphenylamine-Based Dendrimers: Tuning Enhanced Two-Photon Absorption Performance with Locked Molecular Planarity

  摘要：

  Triphenylamine derivatives bridged by methylene units afford a near planar molecular platform In a series of one dimer and two oligomers exhibiting Increased structural rigidity compared to that of their parent triphenylamines. This series of dendrimers show significantly enhanced two-photon absorptions that are up to 3-fold that of triphenylamines with similar molecular size and structure.

  DOI：

  10.1021/ol801238n