9-isopropylidene-5-nitro-benzonorbornene | 935772-51-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 9-isopropylidene-5-nitro-benzonorbornene
• 英文别名: 3-Nitro-11-propan-2-ylidenetricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
• CAS: 935772-51-3
• 化学式: C₁₄H₁₅NO₂
• 分子量: 229.279
• InChiKey: ALAIBKFUGAIPNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-isopropylidene-5-nitro-benzonorbornene 在 5% rhodium-on-charcoal 氢气 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 2.5h， 生成 9-isopropylidene-5-amino-benzonorbornene
  参考文献：
  名称：

  WO2007/31323

  摘要：

  公开号：
• 作为产物：
  描述：

  9-isopropylidene-5-nitro-benzonorbornadiene 在 Wilkinson's catalyst 氢气 作用下， 以 四氢呋喃 为溶剂， 以98%的产率得到9-isopropylidene-5-nitro-benzonorbornene
  参考文献：
  名称：

  WO2007/48556

  摘要：

  公开号：

文献信息

• PROCESS FOR THE PREPARATION OF PYRAZOLE CARBOXYLIC ACID AMIDES
  申请人：Gribkov Denis

  公开号：US20120136162A1

  公开（公告）日：2012-05-31

  The invention relates to a process for the preparation of 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid (9-dichloromethylene-1,2,3,4-tetrahydro-1,4-methano-naphthalen-5-yl)-amide.

  这项发明涉及一种制备3-二氟甲基-1-甲基-1H-吡唑-4-羧酸(9-二氯甲亚甲基-1,2,3,4-四氢-1,4-甲基-萘-5-基)-酰胺的过程。
• FUNGICIDAL COMPOSITIONS
  申请人：Tobler Hans

  公开号：US20100216640A1

  公开（公告）日：2010-08-26

  A composition suitable for control of diseases caused by phytopathogens comprising (A) a compound of Formula (I) wherein R 1 is difluoromethyl or trifluoromethyl and X is chloro, fluoro or bromo; and (B) at least one compound selected from compounds known for their fungicidal activity; and a method of controlling diseases on useful plants, especially rust diseases on soybean plants.

  适用于控制由植物病原体引起的疾病的组合物，包括（A）式（I）中R1为二氟甲基或三氟甲基，X为氯、氟或溴的化合物；和（B）至少一种选择自具有杀真菌活性的化合物；以及一种在有用植物上控制疾病的方法，特别是在大豆植物上控制锈病。
• Heterocyclic Amide Derivatives Useful as Microbiocides
  申请人：Tobler Hans

  公开号：US20080227835A1

  公开（公告）日：2008-09-18

  The invention relates to a fungicidally active compound of formula (I): where Het is a 5- or 6-membered heterocyclic ring containing one to three heteroatoms, each independently selected from oxygen, nitrogen and sulphur, the ring being substituted by the groups R 6 , R 7 and R 8 ; R 1 is hydrogen, C 1-4 alkyl, C 1-4 haloalkyl, C 1-4 alkoxy, C 1-4 haloalkoxy, CH 2 C≡CR 9 , CH 2 CR 10 ═CHR 11 , CH═C═CH 2 or COR 12 ; R 2 and R 3 are each, independently, hydrogen, halo, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl or C 1-4 haloalkoxy; R 4 and R 5 are each independently selected from halo, cyano and nitro; or one of R 4 and R 5 is hydrogen and the other is selected from halo, cyano and nitro; R 6 , R 7 and R 8 are each, independently, hydrogen, halo, cyano, nitro, C 1-4 alkyl, C 1-4 haloalkyl, C 1-4 alkoxy(C 1-4 )alkyl, C 1-4 haloalkoxy(C 1-4 )alkyl or C 1-4 haloalkoxy, provided that at least one of R 6 , R 7 and R 8 is not hydrogen; R 9 , R 10 and R 11 are each, independently, hydrogen, halo, C 1-4 alkyl, C 1-4 haloalkyl or C 1-4 alkoxy(C 1-4 )alkyl; and R 12 is hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 1-4 alkoxy(C 1-4 )alkyl, C 1-4 alkylthio(C 1-4 )-alkyl, C 1-4 alkoxy or aryl; to the preparation of these compounds, to novel intermediates used in the preparation of these compounds, to agrochemical compositions which comprise at least one of the novel compounds as active ingredient, to the preparation of the compositions mentioned and to the use of the active ingredients or compositions in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.
• HETEROCYCLIC AMIDE DERIVATIVES USEFUL AS MICROBIOCIDES
  申请人：Tobler Hans

  公开号：US20100204482A1

  公开（公告）日：2010-08-12

  The invention relates to a fungicidally active compound of formula (I): where Het is a 5- or 6-membered heterocyclic ring containing one to three heteroatoms, each independently selected from oxygen, nitrogen and sulphur, the ring being substituted by the groups R 6 , R 7 and R 8 ; R 1 is hydrogen, C 1-4 alkyl, C 1-4 haloalkyl, C 1-4 alkoxy, C 1-4 haloalkoxy, CH 2 C≡CR 9 , CH 2 CR 10 ═CHR 11 , CH═C═CH 2 or COR 12 ; R 2 and R 3 are each, independently, hydrogen, halo, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl or C 1-4 haloalkoxy; R 4 and R 5 are each independently selected from halo, cyano and nitro; or one of R 4 and R 5 is hydrogen and the other is selected from halo, cyano and nitro; R 6 , R 7 and R 8 are each, independently, hydrogen, halo, cyano, nitro, C 1-4 alkyl, C 1-4 haloalkyl, C 1-4 alkoxy(C 1-4 )alkyl, C 1-4 haloalkoxy(C 1-4 )alkyl or C 1-4 haloalkoxy, provided that at least one of R 6 , R 7 and R 8 is not hydrogen; R 9 , R 10 and R 11 are each, independently, hydrogen, halo, C 1-4 alkyl, C 1-4 haloalkyl or C 1-4 alkoxy(C 1-4 )alkyl; and R 12 is hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 1-4 alkoxy(C 1-4 )alkyl, C 1-4 alkylthio(C 1-4 )-alkyl, C 1-4 alkoxy or aryl; to the preparation of these compounds, to novel intermediates used in the preparation of these compounds, to agrochemical compositions which comprise at least one of the novel compounds as active ingredient, to the preparation of the compositions mentioned and to the use of the active ingredients or compositions in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.
• PROCESS FOR THE PREPARATION OF BENZONORGORNENES
  申请人：Gribkov Denis

  公开号：US20110207958A1

  公开（公告）日：2011-08-25

  The present invention relates to a novel a process for the preparation of 9-dichloromethylene-1,2,3,4-tetrahydro-1,4-methano-naphthalen-5-ylamine which process comprises a) reacting cyclopentadiene in the presence of a radical initiator and CXCI 3 , wherein X is chloro or bromo, to a compound of formula I1, or aa) reacting cyclopentadiene with CXCI 3 , wherein X is chloro, in the presence of a metal catalyst to a compound of formula I1, wherein X is chloro, b) reacting the compound of formula I1 with a base in the presence of an appropriate solvent to the compound of formula III, c) and converting the compound of formula III in the presence of 1,2-dehydro-6-nitrobenzene to the compound of formula IV, and d) hydrogenating the compound of formula IV in the presence of a metal catalyst.