trimethyl-(14-trimethylsilyl-12,14-diaza-13λ2-stannapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-12-yl)silane | 183143-25-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: trimethyl-(14-trimethylsilyl-12,14-diaza-13λ2-stannapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-12-yl)silane
• CAS: 183143-25-1
• 化学式: C₂₆H₃₀N₂Si₂Sn
• 分子量: 545.419
• InChiKey: QKSNMVRYWFJYOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.49
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trimethyl-(14-trimethylsilyl-12,14-diaza-13λ2-stannapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-12-yl)silane 、 氧气 以 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Dilithium diamides [{Li(OC₄H₈)}₂{C₂₀H₁₂(NR)₂}](R = SiMe₃or CH₂Bu^t) derived from R-, S- or R,S-2,2′-diamino-1,1′-binaphthyl derivatives

  摘要：

  The dilithium diamides [{Li(thf)}(2){C20H12(NR)(2)}] (R = SiMe(3) 1 or CH(2)Bu(t) 2, thf = tetrahydrofuran) were prepared from R,S-2,2'-diamino-1,1'-binaphthyl, C20H12(NH2)(2), via C20H12[N(H)SiMe(3)](2) or C20H12[NHC(O)Bu(t)](2) and C20H12[N(H)CH(2)Bu(t)](2), respectively, and were transformed into SiCl2[C20H12(NR)(2)] by treatment with SiCl4. The crystal structures of 1 and 2 were determined. They are monomers, having a Li(1)N(1)Li(2)N(2) buckled ring, with Li(1)-N(2) ca. 0.2 Angstrom shorter than Li(1)-N(1), the two groups R cis to one another, and N(1)-C(1) eta(2) bonded to Li(1). The R and S enantiomers were similarly prepared and their optical stability was demonstrated by their hydrolysis to R- and S-C20H12(NH2)(2), respectively. Evidence is provided for the structures of [M{C20H12[N(SiMe(3))](2)}] (M = Ge or Sn), obtained by conversion of the stannylene into the crystallographically characterised [{Sn[(NSiMe(3))(2)C20H12](mu-O)}(3)].

  DOI：

  10.1039/dt9960003595
• 作为产物：
  描述：

  tin(ll) chloride 、 以 四氢呋喃 、 正己烷 为溶剂， 生成 trimethyl-(14-trimethylsilyl-12,14-diaza-13λ2-stannapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-12-yl)silane
  参考文献：
  名称：

  Dilithium diamides [{Li(OC₄H₈)}₂{C₂₀H₁₂(NR)₂}](R = SiMe₃or CH₂Bu^t) derived from R-, S- or R,S-2,2′-diamino-1,1′-binaphthyl derivatives

  摘要：

  The dilithium diamides [{Li(thf)}(2){C20H12(NR)(2)}] (R = SiMe(3) 1 or CH(2)Bu(t) 2, thf = tetrahydrofuran) were prepared from R,S-2,2'-diamino-1,1'-binaphthyl, C20H12(NH2)(2), via C20H12[N(H)SiMe(3)](2) or C20H12[NHC(O)Bu(t)](2) and C20H12[N(H)CH(2)Bu(t)](2), respectively, and were transformed into SiCl2[C20H12(NR)(2)] by treatment with SiCl4. The crystal structures of 1 and 2 were determined. They are monomers, having a Li(1)N(1)Li(2)N(2) buckled ring, with Li(1)-N(2) ca. 0.2 Angstrom shorter than Li(1)-N(1), the two groups R cis to one another, and N(1)-C(1) eta(2) bonded to Li(1). The R and S enantiomers were similarly prepared and their optical stability was demonstrated by their hydrolysis to R- and S-C20H12(NH2)(2), respectively. Evidence is provided for the structures of [M{C20H12[N(SiMe(3))](2)}] (M = Ge or Sn), obtained by conversion of the stannylene into the crystallographically characterised [{Sn[(NSiMe(3))(2)C20H12](mu-O)}(3)].

  DOI：

  10.1039/dt9960003595