2-((E)-1-Methyl-propenyl)-benzothiazole | 134641-83-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2-((E)-1-Methyl-propenyl)-benzothiazole
• 英文别名: 2-[(E)-but-2-en-2-yl]-1,3-benzothiazole
• CAS: 134641-83-1
• 化学式: C₁₁H₁₁NS
• 分子量: 189.281
• InChiKey: OAESUPJTJYQRQT-FPYGCLRLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  41.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-((E)-1-Methyl-propenyl)-benzothiazole 在 sodium hydroxide 、 N-溴代丁二酰亚胺(NBS) 作用下， 以 1,4-二氧六环 、 水 、 异丙醇 为溶剂， 反应 6.0h， 生成 2-((2R,3S)-2,3-Dimethyl-oxiranyl)-benzothiazole
  参考文献：
  名称：

  Stereoselective synthesis of vinylbenzothiazoles and their epoxides.

  摘要：

  Vinylbenzothiazoles 2 were stereoselectively prepared through isomerization of allylbenzothiazoles 1. Oxiranes 5 and 8 were synthesized from 2 and 1 via cyclization of the corresponding bromohydrins 3, 4, 6 and 7.

  DOI：

  10.1016/s0040-4020(01)86401-2
• 作为产物：
  描述：

  2-(1-methyl-2-propenyl)benzothiazole 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 96.0h， 以57%的产率得到2-((E)-1-Methyl-propenyl)-benzothiazole
  参考文献：
  名称：

  Stereoselective synthesis of vinylbenzothiazoles and their epoxides.

  摘要：

  Vinylbenzothiazoles 2 were stereoselectively prepared through isomerization of allylbenzothiazoles 1. Oxiranes 5 and 8 were synthesized from 2 and 1 via cyclization of the corresponding bromohydrins 3, 4, 6 and 7.

  DOI：

  10.1016/s0040-4020(01)86401-2

文献信息

• Binaphthalene derivatives, preparation method thereof and organic electronic device using the same
  申请人：Bae Soon Jae

  公开号：US20070108892A1

  公开（公告）日：2007-05-17

  The present invention relates to a new binaphthalene derivative, a preparation method thereof, and an organic electronic device using the same. The binaphthalene derivative according to the present invention can perform functions of hole injection and transportation, electron injection and transportation, or light emission in an organic electronic device including an organic light-emitting device, and the device according to the present invention has excellent characteristics in terms of efficiency, drive voltage and stability, and in particular excellent effects such as a low voltage and a long life time.
• HELICAL-POLYACETYLENE AND DEVICE HAVING THE HELICAL-POLYACETYLENE
  申请人：Mitsutake Kunihiro

  公开号：US20120219812A1

  公开（公告）日：2012-08-30

  A helical-polyacetylene whose main chain has a helical structure includes a carbon double bond constituting the main chain and a side chain composed of an aromatic five- or six-membered ring that binds to one carbon atom of the carbon double bond. In the atoms constituting the five- or six-membered ring, two atoms binding to the atom that directly binds to the carbon atom of the main chain bind only any of five or six atoms constituting the five- or six-membered ring, and in the atoms constituting the five- or six-membered ring, at least one atom located most distant from the atom that directly binds to the carbon atom of the main chain is carbon.
• BINAPHTHALENE DERIVATIVES, PREPARATION METHOD THEREOF AND ORGANIC ELECTRONIC DEVICE USING THE SAME
  申请人：LG CHEM, LTD.

  公开号：US20140183505A1

  公开（公告）日：2014-07-03

  The present invention relates to a new binaphthalene derivative, a preparation method thereof, and an organic electronic device using the same. The binaphthalene derivative according to the present invention can perform functions of hole injection and transportation, electron injection and transportation, or light emission in an organic electronic device including an organic light-emitting device, and the device according to the present invention has excellent characteristics in terms of efficiency, drive voltage and stability, and in particular excellent effects such as a low voltage and a long life time.
• US8674138B2
  申请人：——

  公开号：US8674138B2

  公开（公告）日：2014-03-18
• US8951831B2
  申请人：——

  公开号：US8951831B2

  公开（公告）日：2015-02-10