癸胺氢碘酸盐 | 60734-65-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 癸胺氢碘酸盐
• 英文名称: decylammonium iodide
• 英文别名: Decan-1-amine hydroiodide；decan-1-amine;hydroiodide
• CAS: 60734-65-8
• 化学式: C₁₀H₂₃N*HI
• 分子量: 285.212
• InChiKey: ANGXTHKGHPNXFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  2
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  癸胺氢碘酸盐 、 lead(II) iodide 以 丙酮 为溶剂， 以70%的产率得到bis(decylammonium)tetraiodoplumbate(II)
  参考文献：
  名称：

  Systematic Studies on Chain Lengths, Halide Species, and Well Thicknesses for Lead Halide Layered Perovskite Thin Films

  摘要：

  二维层状钙钛矿化合物（CnH2n+1NH3）2（CH3NH3）m−1PbmX3m+1（n=2，3，4，6，10；X=Cl，Br，I；m=1，2，3）被系统地制备。研究了钙钛矿薄膜的势垒大小、卤素种类和阱厚对量子限域结构的影响。层状钙钛矿薄膜由于限制在无机量子阱中的激子而显示出强烈而清晰的吸收峰。随着卤素种类从Cl变为Br和I，激子峰向低能量方向移动。此外，通过改变旋涂条件制备了精细的多层钙钛矿化合物薄膜。

  DOI：

  10.1246/bcsj.79.1607

文献信息

• Production of carboxylic acids from organic formates using rhodium complex catalysts
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0171651A1

  公开（公告）日：1986-02-19

  A process for the production of organic carboxylic acids by the catalytic reaction of organic formate esters in contact with carbon monoxide and a homogeneous catalyst system of rhodium metal atom, a phosphorus containing ligand in which there is present at least one oxo oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the group in said Z group is located at least one carbon atom removed and preferably from 2-4 carbon atoms removed from the phosphorus atom of the molecules represented by the formulas and a halogen source, under mild reaction conditions, wherein R' is aryl, alkaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted; a is an integer from 0-4; b is an integer from 0-3; and Z is P(O)R'R'; -C(O)OR" or C(O)R", wherein R" is R' or -H.

  一种通过有机甲酸酯与一氧化碳和均相催化剂体系的催化反应生产有机羧酸的工艺，均相催化剂体系包括金属铑原子、含磷配体（其中至少有一个氧原子与磷原子或碳原子相连形成 Z 基团）以及 在所述 Z 基团中，至少有一个碳原子与下列式子所代表的分子中的磷原子相分离，最好分离 2-4 个碳原子 和卤素源，在温和的反应条件下，其中 R'为芳基、烷芳基、芳烷基或烷基，且其中 1 个或多个所述 R'基团可被 Z 基团取代，但分子中被如此取代的所述 R'基团不超过 3 个；a 为 0-4 的整数；b 为 0-3 的整数；Z 为 P(O)R'R'；-C(O)OR" 或 C(O)R"，其中 R" 为 R'或-H。
• Production of acetate esters from alcohols using rhodium complex catalysts
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0171804A2

  公开（公告）日：1986-02-19

  A process for the production of acetate esters by the catalytic reaction of an alcohol of the formula ROH and carbon monoxide in contact with a homogeneous catalyst system of rhodium metal atom, a phosphorus containing ligand in which there is present at least one oxo (=O) oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the and a halogen promoter, under mild reaction conditions, wherein R' is aryl, alkaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted: a is an integer from 0-4; b is an integer from 0-3; and Z is P(O)R'R'; - C(O)OR" or C(O)R", wherein R" is R' or -H; and wherein ROH is methanol or a mixture of methanol and at least one higher alcohol. group in said Z group is located at least one carbon atom removed and preferably from 2-4 carbon atoms removed from the phosphorus atom of the molecules represented by the formulas

  一种通过式 ROH 的醇和一氧化碳与由金属铑原子、含磷配体（其中至少有一个氧原子与磷原子或碳原子相连形成 Z 基团）和卤素促进剂组成的均相催化剂体系接触进行催化反应生产醋酸酯的工艺、在温和的反应条件下，其中 R'为芳基、烷芳基、芳烷基或烷基，且其中 1 个或多个所述 R'基团可被 Z 基团取代，但分子中被如此取代的所述 R'基团不超过 3 个：a 是 0-4 的整数；b 是 0-3 的整数；Z 是 P(O)R'R'；- C(O)OR "或 C(O)R"，其中 R "是 R'或-H；ROH 是甲醇或甲醇与至少一种高级醇的混合物。 在所述 Z 基团中，至少有一个碳原子与由以下公式表示的分子的磷原子相隔，最好是 2-4 个碳原子与磷原子相隔
• Production of carboxylic anhydrides from methyl carboxylates using rhodium complex catalysts
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0171802A1

  公开（公告）日：1986-02-19

  @ A process for the production of organic carboxylic anhydrides by the catalytic reaction of a methyl carboxylate and carbon monoxide in contact with a homogeneous catalyst system of rhodium metal atom, a phosphorus-containing ligand in which there is present at least one oxo (=0) oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the group in said Z group is located at least one carbon atom removed and preferably from 2-4 carbon atoms removed from the phosphorus atom of the molecules represented by the formulas or and a halogen source, under mild reaction conditions, wherein R' is aryl, alKaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted; a is an integer from 0-4; b is an integer from 0-3 and Z is P(O)R'R'; - C(O)OR" or C(O)R", wherein R" is R or -H.

  一种通过羧酸甲酯和一氧化碳与由金属铑原子、含磷配体组成的均相催化剂体系接触进行催化反应生产有机羧酸酐的工艺。 所述 Z 基团中的基团与下列分子的磷原子至少相差一个碳原子，最好相差 2-4 个碳原子 或 和卤素源，在温和的反应条件下，其中 R'为芳基、芳烷基、芳烷基或烷基，且其中 1 个或多个所述 R'基团可被 Z 基团取代，但分子中被如此取代的所述 R'基团不超过 3 个；a 为 0-4 的整数；b 为 0-3 的整数，且 Z 为 P(O)R'R'；- C(O)OR "或 C(O)R"，其中 R "为 R 或-H。
• Process for the preparation of anhydrous carboxylic acids from alcohols
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0173170A1

  公开（公告）日：1986-03-05

  A process for the production of organic carboxylic acids and organic carboxylic acid anhydrides by the catalytic reaction of an alcohol of the formula ROH and carbon monoxide in contact with an organic ester source and a homogeneous catalyst system of rhodium metal atom, a phosphorus containing ligand in which there is present at least one oxo (=0) oxygen atom attached to a phosphorus atom or a carbon atom to form a Z group and the group in said Z group is located at least one carbon atom removed and preferably from 2-4 carbon atoms removed from the phosphorus atom of the molecules represented by the formulas or and a halogen source, under mild reaction conditions, wherein R' is aryl, alkaryl, aralkyl or alkyl, and wherein 1 or more of said R' groups can be substituted with a Z group but not more than 3 of said R' groups in the molecule are so substituted; a is an integer from 0-4; b is an integer from 0-3; and Z is P(O)R'R'; -C(O)OR" or C(O)R", wherein R" is R' or -H; and wherein ROH is methanol or a mixture of methanol and at least one higher alcohol.

  一种生产有机羧酸和有机羧酸酐的工艺，该工艺通过式 ROH 的醇和一氧化碳与有机酯源、由金属铑原子、含磷配体组成的均相催化剂体系接触进行催化反应，在该催化剂体系中，至少有一个氧（＝0）氧原子连接到磷原子或碳原子上形成一个 Z 基团，所述 Z 基团中的基团位于从式 ROH 所代表的分子的磷原子上移去至少一个碳原子的位置，最好是移去 2-4 个碳原子的位置。 在所述 Z 基团中，至少有一个碳原子与下列式子所代表的分子中的磷原子相分离，最好分离 2-4 个碳原子 或 和卤素源，在温和的反应条件下，其中 R'为芳基、烷芳基、芳烷基或烷基，且其中 1 个或多个所述 R'基团可被 Z 基团取代，但分子中被如此取代的所述 R'基团不超过 3 个；a 是 0-4 的整数；b 是 0-3 的整数；Z 是 P(O)R'R'；-C(O)OR" 或 C(O)R"，其中 R" 是 R'或-H；ROH 是甲醇或甲醇与至少一种高级醇的混合物。
• Homologation process
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0283586A2

  公开（公告）日：1988-09-28

  A process for the homologation of an alkanol by reaction with synthesis gas in contact with a system containing rhodium atom, ruthenium atom, iodine atom and a bis(diorganophosphino) alkane to selectivity produce the next higher homologue.

  一种烷醇的同系化工艺，通过与含有铑原子、钌原子、碘原子和双(二(二)甘膦)烷烃的系统接触的合成气反应，选择性地生成下一级同系物。