methyl isobutyl ketoxime O-methyl ether | 75039-28-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: methyl isobutyl ketoxime O-methyl ether
• 英文别名: (E)-N-methoxy-4-methylpentan-2-imine
• CAS: 75039-28-0
• 化学式: C₇H₁₅NO
• 分子量: 129.202
• InChiKey: WOGULMJSOBEFFD-BQYQJAHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  21.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  对羟基苯甲醛 、 methyl isobutyl ketoxime O-methyl ether 生成 (E)-4-hydroxybenzaldehyde O-methyloxime
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Insecticidal Benzenedicarboxamide Derivative
  申请人：Wada Katsuaki

  公开号：US20110184188A1

  公开（公告）日：2011-07-28

  The present invention relates to a novel benzenedicarboxamide derivative and the use thereof as an insecticide having the formula (I) wherein the chemical groups W 1 to W 9 , and R 1 to R 3 are as defined here-in.

  本发明涉及一种新型苯二甲酰胺衍生物及其作为杀虫剂的用途，其化学式为(I)，其中化学基团W1至W9，以及R1至R3如本文所定义。
• Process for the preparation of hydroxybenzaldoxime O-ethers
  申请人：Bayer Aktiengesellschaft

  公开号：US04739118A1

  公开（公告）日：1988-04-19

  A process for the preparation of a hydroxybenzaldoxime O-ether of the formula ##STR1## in which R.sup.1 is alkyl, alkenyl or alkynyl comprising reacting a hydroxybenzaldehyde of the formula ##STR2## in the presence of an acid catalyst at a temperature between 50.degree. to 150.degree. C. with a ketoxime O-ether of the formula ##STR3## in which R.sup.2 and R.sup.3 each independently is an aliphatic cycloaliphatic or aromatic radical, or R.sup.2 and R.sup.3, together with the carbon atom to which they are bonded are cycloalkyl. Advantageously, the hydroxybenzaldehyde is 4-hydroxybenzaldehyde, the acid catalyst is a Lewis acid, the reaction is effected in a diluent at a temperature between 50.degree. and 100.degree. C., 1 to 10 mols of the ketoxime O-ether are present per mol of hydroxybenzaldehyde and the catalyst is present in 0.01 to 10 mol % based on the ketoxime O-ether. The products are intermediates for agricultural and pharmaceutical chemicals.

  一种制备羟基苯甲醛肟O-醚的方法，其化学式为##STR1##其中R.sup.1为烷基、烯基或炔基，包括在存在酸催化剂下，在50℃至150℃的温度下，使化学式为##STR2##的羟基苯甲醛与化学式为##STR3##的肟O-醚发生反应，其中R.sup.2和R.sup.3各自独立地是脂肪环脂或芳香基，或者R.sup.2和R.sup.3连同它们结合的碳原子一起是环烷基。优选，羟基苯甲醛是4-羟基苯甲醛，酸催化剂是路易斯酸，反应在50℃至100℃的温度下在稀释剂中进行，每摩尔羟基苯甲醛中存在1至10摩尔的肟O-醚，并且催化剂以基于肟O-醚的0.01至10摩尔%的浓度存在。产物是农药和制药化学品的中间体。
• 5-PHENYLPYRIMIDINES, THEIR PREPARATION, COMPOSITIONS COMPRISING THEM AND THEIR USE
  申请人：GYPSER Andreas

  公开号：US20070149551A1

  公开（公告）日：2007-06-28

  5-Phenylpyrimidines of the formula I in which the substituents and the index are as defined below: R 1 ,R 2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, and R 1 and R 2 together with the nitrogen atom to which they are attached may also form a saturated or unsaturated ring which may be interrupted by an ether, thio, sulfoxyl or sulfonyl group and may be substituted by one to four groups R a and/or R b ; R 3 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy or alkenyloxy; R 4 is hydrogen, halogen, cyano, hydroxyl, mercapto, azido, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, alkylthio, alkenylthio, alkynylthio, haloalkylthio, —ON═CRN a R b , —CR c ═NOR a , —NR c N═CR a R b , —NR a R b , —NR c NR a R b , —NOR a , —NR c C (═NR c′ )NR a R b , —NR c C(═O)NR a R b , —NR a C(═O)R c , —NR a C(═NOR c )R c′ , —OC (═O)R c , —C(═NOR c )NR a R b , —CR c (═NNR a R b ), —C (═O)NR a R b or —C(═O) R c ; in which R a , R b and R c are as defined in the description; X is halogen, alkyl, alkoxy or haloalkyl; and m is an integer from 1 to 5; processes for preparing these compounds, compositions comprising them and their use for controlling harmful fungi are described.

  公式I中的5-苯基嘧啶化合物，其中取代基和指数定义如下：R1、R2为氢、烷基、卤代烷基、环烷基、卤代环烷基、烯基、卤代烯基、炔基或卤代炔基，且R1和R2与它们附着的氮原子也可以形成饱和或不饱和环，该环可以被醚、硫、亚硫酰基或磺酰基中断，并且可以被一个到四个基团Ra和/或Rb取代；R3为氢、卤素、氰基、烷基、卤代烷基、烷氧基、卤代烷氧基或烯氧基；R4为氢、卤素、氰基、羟基、巯基、叠氮基、烷基、烯基、炔基、卤代烷基、烷氧基、烯氧基、炔氧基、卤代烷氧基、烷硫基、烯硫基、炔硫基、卤代烷硫基、-ON═CRNaRb，-CRc═NORa，-NRcN═CRaRb，-NRaRb，-NRcNRaRb，-NORa，-NRcC（═NRc'）NRaRb，-NRcC（═O）NRaRb，-NRaC（═O）Rc，-NRaC（═NORc）Rc'，-OC（═O）Rc，-C（═NORc）NRaRb，-CRc（═NNRaRb），-C（═O）NRaRb或-C（═O）Rc；其中Ra、Rb和Rc如描述中所定义；X为卤素、烷基、烷氧基或卤代烷基；m为1至5的整数；描述了制备这些化合物的过程、包含它们的组合物以及它们用于控制有害真菌的用途。
• ——
  作者：ELBE H. -L.

  DOI：——

  日期：——
• Verfahren zur Herstellung von Hydroxy-benzaldoxim-O-ethern
  申请人：BAYER AG

  公开号：EP0218123B1

  公开（公告）日：1989-03-22