1-amino-6-methyl-5-heptene | 61755-54-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-amino-6-methyl-5-heptene
• 英文别名: 6-Methyl-5-heptenylamin；5-Hepten-1-amine, 6-methyl-；6-methylhept-5-en-1-amine
• CAS: 61755-54-2
• 化学式: C₈H₁₇N
• mdl: MFCD19205315
• 分子量: 127.23
• InChiKey: IXUTXMRIALJDSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-amino-6-methyl-5-heptene 在 sodium sulfate 、 ytterbium(III) triflate 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 生成 (5aS,8aS)-6,6-Dimethyl-octahydro-furo[3,4-b]azepin-8-one
  参考文献：
  名称：

  三氟乙磺酸tter（III）催化乙二酸酯衍生的不饱和亚胺的亲电环化

  摘要：

  发现三氟甲磺酸（（III）催化某些乙二酸衍生的不饱和亚胺的亲电环化。环化反应产生具有良好立体选择性的仅稠合的氨基γ-内酯产物。此外，镧系元素催化的反应的固相形式具有内酯化作用，同时从固体载体上裂解产物。

  DOI：

  10.1016/s0040-4039(02)00262-9

文献信息

• Hydrochinone und deren Herstellung
  申请人：CIBA-GEIGY AG

  公开号：EP0069068A1

  公开（公告）日：1983-01-05

  Es werden neue Hydrochinone der Formel 1 und Salze davon mit Säuren oder Basen beschrieben, worin p 1 oder 2 und q 0 oder 1 sind, mit der Massgabe, dass p + q 1 der 2 sind, R einen Rest der Formel II Q -COOR4, -CONR4R5, -OR5, -OCOR7, -NR8R9, -PO(OR10)([O]xR11), -SO2OH, -SO2Cl, -SO2NR5R7 oder -CN, n eine ganze Zahl von 1 bis 20, k die Zahl 1 oder 2 bedeuten und R1, R2, R3, R4, R5, R7, R8, R9, R10 und R11 die im Patentanspruch 1 angegebene Bedeutung haben. Die Verbindungen der Formel I finden Anwendung als schwarze Farbkuppler in photographischen Materialien.

  式 1 的新对苯二酚 及其与酸或碱的盐，其中 p 为 1 或 2，q 为 0 或 1，但 p + q 为 1 或 2，R 为式 II 的基团 Q是-COOR4、-CONR4R5、-OR5、-OCOR7、-NR8R9、-PO(OR10)([O]xR11)、-SO2OH、-SO2Cl、-SO2NR5R7或-CN，n是1至20的整数，k是数字1或2，R1、R2、R3、R4、R5、R7、R8、R9、R10和R11具有权利要求1中给出的含义。式 I 的化合物可用作摄影材料中的黑色耦合剂。
• Method for measuring hematocrit value of blood sample, method for measuring concentration of analyte in blood sample, sensor chip and sensor unit
  申请人：Panasonic Healthcare Holdings Co., Ltd.

  公开号：US10866205B2

  公开（公告）日：2020-12-15

  Voltage is applied across a counter electrode and a working electrode, with which a blood sample is in contact, in such a state that an oxidant in a redox substance is not substantially in contact with a working electrode but is in contact with a counter electrode and a reductant is not substantially in contact with the counter electrode but is in contact with the working electrode, whereby the reductant and the oxidant are respectively oxidized and reduced to measure current produced upon the oxidation and reduction. According to the above constitution, while lowering the voltage applied across the working electrode and the counter electrode, the Hct value of the blood sample can be measured stably with a satisfactory detection sensitivity. This measurement can be carried out with a sensor chip comprising a working electrode (11), a counter electrode (12), and a blood sample holding part (14) having branch parts (18a, 18b). A first reagent (13) consisting essentially of an oxidant in a redox substance is disposed in contact with the surface of a counter electrode which faces the branch part (18b), and a second reagent (19) consisting essentially of a reductant is disposed in contact with the surface of a working electrode that faces the branch part (18a).

  在与血样接触的对电极和工作电极上施加电压，使氧化还原物质中的氧化剂基本上不与工作电极接触，而是与对电极接触，还原剂基本上不与对电极接触，而是与工作电极接触，从而还原剂和氧化剂分别被氧化和还原，测量氧化和还原时产生的电流。根据上述构成，在降低施加在工作电极和对电极上的电压的同时，可以稳定地测量血样的 Hct 值，并具有令人满意的检测灵敏度。该测量可通过传感器芯片进行，该芯片包括一个工作电极 (11)、一个对电极 (12) 和一个具有分支部件 (18a, 18b) 的血样容纳部件 (14)。主要由氧化还原物质中的氧化剂组成的第一试剂 (13) 与面向分支部分 (18b) 的对电极表面接触，而主要由还原剂组成的第二试剂 (19) 则与面向分支部分 (18a) 的工作电极表面接触。
• Tietze, Lutz F.; Bratz, Matthias, Liebigs Annalen der Chemie, 1989, p. 559 - 564
  作者：Tietze, Lutz F.、Bratz, Matthias

  DOI：——

  日期：——
• METHOD FOR MEASURING HEMATOCRIT VALUE OF BLOOD SAMPLE, METHOD FOR MEASURING CONCENTRATION OF ANALYTE IN BLOOD SAMPLE, SENSOR CHIP AND SENSOR UNIT
  申请人：Panasonic Healthcare Holdings Co., Ltd.

  公开号：US20180217081A1

  公开（公告）日：2018-08-02

  Voltage is applied across a counter electrode and a working electrode, with which a blood sample is in contact, in such a state that an oxidant in a redox substance is not substantially in contact with a working electrode but is in contact with a counter electrode and a reductant is not substantially in contact with the counter electrode but is in contact with the working electrode, whereby the reductant and the oxidant are respectively oxidized and reduced to measure current produced upon the oxidation and reduction. According to the above constitution, while lowering the voltage applied across the working electrode and the counter electrode, the Hct value of the blood sample can be measured stably with a satisfactory detection sensitivity. This measurement can be carried out with a sensor chip comprising a working electrode ( 11 ), a counter electrode ( 12 ), and a blood sample holding part ( 14 ) having branch parts ( 18 a, 18 b ). A first reagent ( 13 ) consisting essentially of an oxidant in a redox substance is disposed in contact with the surface of a counter electrode which faces the branch part ( 18 b ), and a second reagent ( 19 ) consisting essentially of a reductant is disposed in contact with the surface of a working electrode that faces the branch part ( 18 a ).
• US9958411B2
  申请人：——

  公开号：US9958411B2

  公开（公告）日：2018-05-01