4'-nitro-3-oxy-stilbene | 65819-31-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4'-nitro-3-oxy-stilbene
• 英文别名: 4'-Nitro-3-oxy-stilben；3-Hydroxy-4'-nitrostilbene；3-[(E)-2-(4-nitrophenyl)ethenyl]phenol
• CAS: 65819-31-0
• 化学式: C₁₄H₁₁NO₃
• 分子量: 241.246
• InChiKey: KSHDNGNLHTYEAS-SNAWJCMRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4'-nitro-3-oxy-stilbene 在 溴 作用下， 以 四氯化碳 为溶剂， 反应 4.0h， 生成 α,α'-Dibromo-4'-nitro-3-acetoxybibenzyl
  参考文献：
  名称：

  Synthesis and antimicrobial activity of (E)-acetoxystilbenes and α,α′-dibromoacetoxybibenzyls

  摘要：

  The synthesis of 13 new (E)-acetoxystilbenes and alpha,alpha-dibromoacetoxybibenzyls and their antimicrobial activity are reported. The results of microbiological screening of 17 (E)-stilbenols and (E)-acetoxystilbenes, unknown in the literature, have also been discussed. In particular, coumpounds 1c, 1g, 2a, 3a, 3b, 4a, 6a, 6b showed good antibacterial activity against Staphylococcus aureus and 1c also against Bacillus subtilis. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0014-827x(99)00127-5
• 作为产物：
  描述：

  二乙基(4-硝基苯甲基)磷酸盐 、 间羟基苯甲醛 在 (aminomethyl)polystyrene 、 四溴化碳 、 N,N′-二叔丁基碳二亚胺 、 sodium methylate 、 双(三甲基硅烷基)氨基钾 、 1-羟基苯并三唑 、 4-(羟基甲基)苯氧基乙酸 、 三苯基膦 、 三氟乙酸 作用下， 生成 4'-nitro-3-oxy-stilbene
  参考文献：
  名称：

  A Reinvestigation of the Preparation, Properties, and Applications of Aminomethyl and 4-Methylbenzhydrylamine Polystyrene Resins¹

  摘要：

  Mild, efficient conditions have been developed for the preparation of 4-methylbenzhydrylamine polystyrene (MBHA) and aminomethyl polystyrene (AMPS) resins by a two-step procedure with synthons 1a and 1c. The products possess excellent swelling characteristics and acylate readily with linkers yielding useful derivatives, which retain good swelling and reactivity. Comparative studies with these resins, and their poly(ethylene glycol) (PEG) derivatives, yield insights into the role of spacer arm and environment effects in synthesis facilitation.

  DOI：

  10.1021/jo9802269

文献信息

• Cullinane, Journal of the Chemical Society, 1923, vol. 123, p. 2060
  作者：Cullinane

  DOI：——

  日期：——
• OPTICAL FILMS COMPRISING PHENYL ETHYLENE (METH)ACRYLATE MONOMERS
  申请人：Hunt Bryan V.

  公开号：US20110086972A1

  公开（公告）日：2011-04-14

  Presently described are (e.g. microstructured) optical films and polymerizable resin compositions comprising at least one (meth)acrylate monomer comprising an unsubstituted or substituted phenyl ethylene group referred to as phenyl ethylene (meth)acrylate monomers.
• [EN] OPTICAL FILMS COMPRISING PHENYL ETHYLENE (METH)ACRYLATE MONOMERS<br/>[FR] FILMS OPTIQUES COMPRENANT DES MONOMÈRES PHÉNYLE ÉTHYLÈNE(MÉTH)ACRYLATES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2009148818A1

  公开（公告）日：2009-12-10

  Presently described are (e.g. microstructured) optical films and polymerizable resin compositions comprising at least one (meth)acrylate monomer comprising an unsubstituted or substituted phenyl ethylene group referred to as phenyl ethylene (meth)acrylate monomers.