N-[2-(乙基苯基氨基)乙基]-3-(甲酰氨基)-N,N-二甲基-1-丙基氯化铵 | 40948-38-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-[2-(乙基苯基氨基)乙基]-3-(甲酰氨基)-N,N-二甲基-1-丙基氯化铵
• 英文名称: 2-(N-ethylanilino)ethyl-(3-formamidopropyl)-dimethylazanium;chloride
• CAS: 40948-38-7
• 化学式: C16H28ClN3O
• 分子量: 313.9
• InChiKey: RTDKRCWLXSHODV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.27
• 重原子数：
  21
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  32.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  盐酸 、 N-[2-(乙基苯基氨基)乙基]-3-(甲酰氨基)-N,N-二甲基-1-丙基氯化铵 以above gives N,N-dimethyl-N-2-(N'-ethylanilino)ethyl-N-3-aminopropylammonium chloride的产率得到N,N-dimethyl-N-2-(N'-ethylanilino)ethyl-N-3-aminopropylammonium chloride
  参考文献：
  名称：

  N,N-Dialkyl-N-aminoalkyl-N-(amino or nitro)phenylalkyl- and

  摘要：

  N,N-二烷基-N-氨基烷基-N-氨基苯基烷基季铵盐和N-甲基-N-(3-氨基苯氧基-2-羟基-1-丙基)-N,N-双(3-氨基丙基)季铵盐以及它们的N-硝基苯基烷基和N-(3-硝基苯氧基)前体季铵盐是水溶性偶氮染料的中间体，可用于染色天然纤维、合成纤维形成材料和纤维素材料。这些染料可使棉和纸以不同的黄、红和橙色染色，不易褪色，在次氯酸或氯漂白剂漂白时具有高度的脱色能力。

  公开号：

  US04206144A1
• 作为产物：
  描述：

  、 N-[3-(二甲氨基)丙基]甲酰胺 、 N-乙基-N-氯乙基苯胺 以 水 为溶剂， 反应 8.5h， 以there was obtained N,N-dimethyl-N-2-(N'-ethylanilino)ethyl-N-3-formamidopropylammonium chloride in the form of an aqueous solution的产率得到N-[2-(乙基苯基氨基)乙基]-3-(甲酰氨基)-N,N-二甲基-1-丙基氯化铵
  参考文献：
  名称：

  Azo dyestuff intermediate nitro- or aminobenzenes ring-substituted by a

  摘要：

  公式为## STR1 ##的水溶性阳离子染料，其中R.sup.0是氢，较低烷基或羟基较低烷基; R.sup.1是较低烷基，较低烯基或羟基较低烷基; R.sup.2是较低烷基，较低烯基，羟基较低烷基或-(较低烷基) -NR.sup.0 Y或R.sup.1和R.sup.2连同氮原子，是吡咯烷基，哌嗪基或4-较低酰基哌嗪基; Y是氢或## STR2 ##其中R是氢，较低烷基，较低烯基，苯基或苯基较低烷基; A是从含有芳香偶氮染料残基的组中选择的一员，通过较低烷基桥连接到季铵氮原子上。K是小整数，其值取决于A的性质，因此其范围从1到2; R.sup.8是较低烷基，较低烯基或羟基较低烷基; R.sup.9是较低烷基，羟基较低烷基或NH.sub.2; R.sup.10是较低烷基或较低烯基; A.sup.1是从含有芳香偶氮染料残基的组中选择的一员，通过较低烷基桥连接到季铵氮原子上; G是小整数，其值取决于A.sup.1的性质，因此其范围从1到2; R.sup.8'是较低烷基; R.sup.9'是较低烷基，较低烯基或羟基较低烷基; R.sup.10'是较低烷基，较低烯基或羟基较低烷基或R.sup.9'和R.sup.10'连同氮原子是吗啡基; A.sup.2是从含有芳香偶氮染料残基的组中选择的一员，通过较低烷基桥连接到季铵氮原子上; h是小整数，其值取决于A.sup.2的性质，因此其范围从1到2; An是阴离子，特别适用于染色天然纤维，合成纤维形成材料和纤维素材料。这些染料染棉和纸各种稳定的黄色，红色和橙色。这些染料在纸上的染色不太容易出血，并且漂白时具有高度的色彩排放。

  公开号：

  US04146558A1

文献信息

• Azo dyestuff intermediate nitro- or aminobenzenes ring-substituted by a
  申请人：Sterling Drug Inc.

  公开号：US04146558A1

  公开（公告）日：1979-03-27

  Water-soluble cationic dyestuffs of the formulae ##STR1## WHEREIN R.sup.0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R.sup.1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or -(lower-alkylene)-NR.sup.0 Y or R.sup.1 and R.sup.2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##STR2## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a member selected from the group consisting of an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge. K is a small integer whose value is dependent on the nature of A such that it has a range from one to two; R.sup.8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.9 is lower-alkyl, hydroxy-lower-alkyl or NH.sub.2 ; R.sup.10 is lower-alkyl or lower-alkenyl; A.sup.1 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; G is a small integer whose value is dependent on the nature of A.sup.1 such that it has a range from one to two; R.sup.8 ' is lower-alkyl; R.sup.9 ' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.10 ' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R.sup.9 ' and R.sup.10 ' together with the nitrogen atom are morpholino; A.sup.2 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A.sup.2 such that it has a range from one to two; and An is an anion are particularly useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials. These dyes dye cotton and paper various shades of stable yellows, reds and oranges. The dyeing from these dyes on paper are less prone to bleed and have a high degree of color discharge when bleached with hypochlorite or chlorine bleaches.

  公式为## STR1 ##的水溶性阳离子染料，其中R.sup.0是氢，较低烷基或羟基较低烷基; R.sup.1是较低烷基，较低烯基或羟基较低烷基; R.sup.2是较低烷基，较低烯基，羟基较低烷基或-(较低烷基) -NR.sup.0 Y或R.sup.1和R.sup.2连同氮原子，是吡咯烷基，哌嗪基或4-较低酰基哌嗪基; Y是氢或## STR2 ##其中R是氢，较低烷基，较低烯基，苯基或苯基较低烷基; A是从含有芳香偶氮染料残基的组中选择的一员，通过较低烷基桥连接到季铵氮原子上。K是小整数，其值取决于A的性质，因此其范围从1到2; R.sup.8是较低烷基，较低烯基或羟基较低烷基; R.sup.9是较低烷基，羟基较低烷基或NH.sub.2; R.sup.10是较低烷基或较低烯基; A.sup.1是从含有芳香偶氮染料残基的组中选择的一员，通过较低烷基桥连接到季铵氮原子上; G是小整数，其值取决于A.sup.1的性质，因此其范围从1到2; R.sup.8'是较低烷基; R.sup.9'是较低烷基，较低烯基或羟基较低烷基; R.sup.10'是较低烷基，较低烯基或羟基较低烷基或R.sup.9'和R.sup.10'连同氮原子是吗啡基; A.sup.2是从含有芳香偶氮染料残基的组中选择的一员，通过较低烷基桥连接到季铵氮原子上; h是小整数，其值取决于A.sup.2的性质，因此其范围从1到2; An是阴离子，特别适用于染色天然纤维，合成纤维形成材料和纤维素材料。这些染料染棉和纸各种稳定的黄色，红色和橙色。这些染料在纸上的染色不太容易出血，并且漂白时具有高度的色彩排放。
• Water-soluble quaternary ammonium heterocyclic azo dyestuffs
  申请人：Sterling Drug Inc.

  公开号：US03935182A1

  公开（公告）日：1976-01-27

  Water-soluble cationic dyestuffs of the formulae ##SPC1## Wherein R.sup.0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R.sup.1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or -(lower-alkylene)-NRO Y or R.sup.1 and R.sup.2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##EQU1## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a member selected from the group consisting of an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge. k is a small integer whose value is dependent on the nature or A such that it has a range from one to two; R.sup.8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.9 is lower-alkyl, hydroxy-lower-alkyl or NH.sub.2 ; R.sup.10 is lower-alkyl or lower-alkenyl; A.sup.1 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; g is a small integer whose value is dependent on the nature of A.sup.1 such that it has a range from one to two; R.sup.8.sup.' is lower-alkyl; R.sup.9.sup.' is lower-alkyl, lower alkenyl or hydroxy-lower-alkyl; R.sup.10.sup.' is lower-alkyl, lower -alkenyl or hydroxy-lower-alkyl or R.sup.9.sup.' and R.sup.10.sup.' together with the nitrogen atom are morpholino; A.sup.2 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A.sup.2 such that it has a range from one to two; and An is an anion Are particularly useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials.

  具有以下公式的水溶性阳离子染料：##SPC1## 其中R.sup.0是氢，低烷基或羟基低烷基；R.sup.1是低烷基，低烯基或羟基低烷基；R.sup.2是低烷基，低烯基，羟基低烷基或-(低烷基)-NRO Y或R.sup.1和R.sup.2与氮原子一起，为吡咯烷基，哌嗪基或4-低烷酰基哌嗪基；Y是氢或##EQU1## 其中R是氢，低烷基，低烯基，苯基或苯基-低烷基；A是选自由芳香偶氮染料残基的一种，通过低烷基桥连接到季铵氮原子。k是小整数，其值取决于A的性质，范围从一到二；R.sup.8是低烷基，低烯基或羟基低烷基；R.sup.9是低烷基，羟基低烷基或NH.sub.2；R.sup.10是低烷基或低烯基；A.sup.1是通过低烷基桥连接到季铵氮原子上的芳香偶氮染料残基；g是小整数，其值取决于A.sup.1的性质，范围从一到二；R.sup.8.sup.'是低烷基；R.sup.9.sup.'是低烷基，低烯基或羟基低烷基；R.sup.10.sup.'是低烷基，低烯基或羟基低烷基或R.sup.9.sup.'和R.sup.10.sup.'与氮原子一起是吗啡基；A.sup.2是通过低烷基桥连接到季铵氮原子上的芳香偶氮染料残基；h是小整数，其值取决于A.sup.2的性质，范围从一到二；An是阴离子。这些染料特别适用于着色天然纤维，合成纤维成型材料和纤维素材料。
• Water-soluble quaternary ammonium dyestuffs
  申请人：Sterling Drug Inc.

  公开号：US03996282A1

  公开（公告）日：1976-12-07

  Water-soluble cationic dyestuffs of the formulae ##STR1## WHEREIN R.sup.0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R.sup.1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or -(lower-alkylene)-NR.sup.0 Y or R.sup.1 and R.sup.2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##STR2## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a member selected from the group consisting of an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge. K is a small integer whose value is dependent on the nature of A such that it has a range from one to two; R.sup.8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.9 is lower-alkyl, hydroxy-lower-alkyl or NH.sub.2 ; R.sup.10 is lower-alkyl or lower-alkenyl; A.sup.1 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; g is a small integer whose value is dependent on the nature of A.sup.1 such that it has a range from one to two; R.sup.8.sup.' is lower-alkyl; R.sup.9.sup.' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; Rk.sup.10.sup.' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R.sup.9.sup.' and R.sup.10.sup.' together with the nitrogen atom are morpholino; A.sup.2 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A.sup.2 such that it has a range from one to two; and An is an anion Are particularly useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials.

  水溶性阳离子染料的化学式为 ##STR1## 其中R.sup.0是氢、低烷基或羟基低烷基；R.sup.1是低烷基、低烯基或羟基低烷基；R.sup.2是低烷基、低烯基、羟基低烷基或-(低烷基)-NR.sup.0 Y或R.sup.1和R.sup.2与氮原子一起是吡咯烷基、哌嗪基或4-低烷酰基哌嗪基；Y是氢或##STR2## 其中R是氢、低烷基、低烯基、苯基或苯基低烷基；A是从芳香偶氮染料残基中选择的一种，通过低烷基桥连接到季铵氮原子上。K是一个小整数，其值取决于A的性质，范围从1到2；R.sup.8是低烷基、低烯基或羟基低烷基；R.sup.9是低烷基、羟基低烷基或NH.sub.2；R.sup.10是低烷基或低烯基；A.sup.1是从芳香偶氮染料残基中选择的一种，通过低烷基桥连接到季铵氮原子上；g是一个小整数，其值取决于A.sup.1的性质，范围从1到2；R.sup.8.sup.'是低烷基；R.sup.9.sup.'是低烷基、低烯基或羟基低烷基；Rk.sup.10.sup.'是低烷基、低烯基或羟基低烷基或R.sup.9.sup.'和R.sup.10.sup.'与氮原子一起是吗啡基；A.sup.2是从芳香偶氮染料残基中选择的一种，通过低烷基桥连接到季铵氮原子上；h是一个小整数，其值取决于A.sup.2的性质，范围从1到2；An是一个阴离子。这些染料特别适用于染色天然纤维、合成纤维形成材料和纤维素材料。
• Water-soluble quaternary ammonium azo dyestuffs
  申请人：Sterling Drug Inc.

  公开号：US04065500A1

  公开（公告）日：1977-12-27

  Water-soluble cationic dyestuffs of the formulae ##STR1## WHEREIN R.degree. is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R.sup.1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or -(lower-alkylene)-NR.degree.Y or R.sup.1 and R.sup.2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##STR2## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a member selected from the group consisting of an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge. k is a small integer whose value is dependent on the nature of A such that it has a range from one to two; R.sup.8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.9 is lower-alkyl, hydroxy-lower-alkyl or NH.sub.2 ; R.sup.10 is lower-alkyl or lower-alkenyl; A.sup.1 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; g is a small integer whose value is dependent on the nature of A.sup.1 such that it has a range from one to two; R.sup.8' is lower alkyl; R.sup.9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R.sup.9' and R.sup.10' together with the nitrogen atom are morpholino; A.sup.2 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A.sup.2 such that it has a range from one to two; and An is an anion Are particularly useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials. These dyes dye cotton and paper various shades of stable yellows, reds and oranges. The dyeing from these dyes on paper are less prone to bleed and have a high degree of color discharge when bleached with hypochlorite or chlorine bleaches.

  该文本描述了一系列水溶性阳离子染料的化学结构公式，其中R.degree.为氢、低碳基或羟基低碳基；R.sup.1为低碳基、低烯基或羟基低碳基；R.sup.2为低碳基、低烯基、羟基低碳基或-(低碳基烷基)-NR.degree.Y或R.sup.1和R.sup.2与氮原子一起为吡咯烷基、哌嗪基或4-低酰基哌嗪基；Y为氢或##STR2##其中R为氢、低碳基、低烯基、苯基或苯基低碳基；A为从芳香偶氮染料残基中选择的一个成员，通过低碳基桥连接到季铵氮原子。k是一个小整数，其值取决于A的性质，范围从1到2；R.sup.8为低碳基、低烯基或羟基低碳基；R.sup.9为低碳基、羟基低碳基或NH.sub.2；R.sup.10为低碳基或低烯基；A.sup.1是通过低碳基桥连接到季铵氮原子的芳香偶氮染料残基；g是一个小整数，其值取决于A.sup.1的性质，范围从1到2；R.sup.8'为低碳基；R.sup.9'为低碳基、低烯基或羟基低碳基；R.sup.10'为低碳基、低烯基或羟基低碳基或R.sup.9'和R.sup.10'与氮原子一起为吗啡基；A.sup.2是通过低碳基桥连接到季铵氮原子的芳香偶氮染料残基；h是一个小整数，其值取决于A.sup.2的性质，范围从1到2；An是一个阴离子。这些染料特别适用于着色天然纤维、合成纤维形成材料和纤维素材料。这些染料在棉花和纸张上染出各种稳定的黄色、红色和橙色。这些染料在纸张上的染色不太容易渗透，并且在漂白时具有高度的色彩排放。
• Water-soluble quaternary ammonium non-heterocyclic azo dyestuffs
  申请人：Sterling Drug Inc.

  公开号：US04103092A1

  公开（公告）日：1978-07-25

  Water-soluble cationic dyestuffs of the formulae ##STR1## WHEREIN R.sup.0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; R.sup.1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or -(lower-alkylene)-NR.sup.0 Y or R.sup.1 and R.sup.2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; Y is hydrogen or ##STR2## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; A is a member selected from the group consisting of an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge. k is a small integer whose value is dependent on the nature or A such that it has a range from one to two; R.sup.8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.9 is lower-alkyl, hydroxy-lower-alkyl or NH.sub.2 ; R.sup.10 is lower-alkyl or lower-alkenyl; A.sup.1 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; g is a small integer whose value is dependent on the nature of A.sup.1 such that it has a range from one to two; R.sup.8' is lower-alkyl; R.sup.9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; R.sup.10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R.sup.9' and R.sup.10' together with the nitrogen atom are morpholino; A.sup.2 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; h is a small integer whose value is dependent on the nature of A.sup.2 such that it has a range from one to two; and An is an anion Are particularly useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials. These dyes dye cotton and paper various shades of stable yellows, reds and oranges. The dyeing from these dyes on paper are less prone to bleed and have a high degree of color discharge when bleached with hypochlorite or chlorine bleaches.

  水溶性阳离子染料的化学式为##STR1## 其中R.sup.0是氢、低碳基或羟基低碳基；R.sup.1是低碳基、低烯基或羟基低碳基；R.sup.2是低碳基、低烯基、羟基低碳基或-(低碳基亚硝基)-NR.sup.0 Y或R.sup.1和R.sup.2与氮原子一起是吡咯烷基、哌啶基或4-低脂肪酰基哌嗪基；Y是氢或##STR2## 其中R是氢、低碳基、低烯基、苯基或苯基低碳基；A是选自芳香偶氮染料残基的一种，通过低碳基桥接连接到季铵氮原子。k是一个小整数，其值取决于A的性质，范围从一到二；R.sup.8是低碳基、低烯基或羟基低碳基；R.sup.9是低碳基、羟基低碳基或NH.sub.2；R.sup.10是低碳基或低烯基；A.sup.1是选自芳香偶氮染料残基的一种，通过低碳基桥接连接到季铵氮原子；g是一个小整数，其值取决于A.sup.1的性质，范围从一到二；R.sup.8'是低碳基；R.sup.9'是低碳基、低烯基或羟基低碳基；R.sup.10'是低碳基、低烯基或羟基低碳基，或R.sup.9'和R.sup.10'与氮原子一起是吗啡基；A.sup.2是选自芳香偶氮染料残基的一种，通过低碳基桥接连接到季铵氮原子；h是一个小整数，其值取决于A.sup.2的性质，范围从一到二；An是一个阴离子。这些染料特别适用于着色天然纤维、合成纤维形成材料和纤维素材料。这些染料可以将棉花和纸张染成各种稳定的黄色、红色和橙色。这些染料在纸张上的染色不易出血，在漂白次氯酸盐或氯漂白剂的作用下具有高度的色彩排放。