2-(3-hydroxy-3-methylbutyl)-4-(3-methylbut-2-enyl)phenol

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-(3-hydroxy-3-methylbutyl)-4-(3-methylbut-2-enyl)phenol
• 化学式: C₁₆H₂₄O₂
• 分子量: 248.365
• InChiKey: PHHVRUIBGWRBDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(3-hydroxy-3-methylbutyl)-4-(3-methylbut-2-enyl)phenol 在 platinum on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 反应 20.0h， 生成 2-(3-Hydroxy-3-methyl-butyl)-4-(3-methyl-butyl)-phenol
  参考文献：
  名称：

  Secondary metabolite chemistry of the Australian brown alga Encyothalia cliftonii: Evidence for herbivore chemical defence

  摘要：

  Two bis-prenylated phenols have been isolated from the Western Australian brown alga Encyothalia cliftonii Harvey. The structures of these compounds were determined by spectral and chemical methods. The major metabolite, 2,4-bis(3-methylbut-2-enyl)phenol, previously isolated as a minor metabolite from the related alga Perithalia caudata, showed significant feeding deterrence toward the herbivorous sea urchin Tripneustes esculentus (Leske). The minor metabolite is a new compound in which hydration of one of the isopentenyl olefinic bonds has taken place.

  DOI：

  10.1016/s0031-9422(00)90790-8