Tris-<5-hydroxy-pentyl>-amin | 93868-25-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Tris-<5-hydroxy-pentyl>-amin
• 英文别名: 5-[Bis(5-hydroxypentyl)amino]pentan-1-ol
• CAS: 93868-25-8
• 化学式: C₁₅H₃₃NO₃
• 分子量: 275.432
• InChiKey: ZIOGOTUVVZEFMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  63.9
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(Bis-5-hydroxypentylamino)-tetrahydropyran 在 镍 氢气 作用下， 以 苯 为溶剂， 生成 Tris-<5-hydroxy-pentyl>-amin
  参考文献：
  名称：

  Glacet,C.; Couturier,J.-C., Bulletin de la Societe Chimique de France, 1962, p. 2097 - 2102

  摘要：

  DOI：

文献信息

• (METH)ACRYLIC ACID ESTER COMPOUND AND PRODUCTION METHOD THEREFOR
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20170008830A1

  公开（公告）日：2017-01-12

  Provided are a novel alicyclic ester compound and a method for producing a compound of general formula (1) at a high yield from a compound of general formula (2) and a compound of general formula (3). An adamantane compound expressed by general formula (2) and a hydroxyalkyl (meth)acrylate ester compound expressed by general formula (3) are reacted with each other by use of a dehydration condensation agent as a catalyst to obtain an alicyclic ester compound expressed by general formula

  提供了一种新的脂环酯化合物及从一般式(2)和一般式(3)的化合物高产得到一般式(1)化合物的方法。通过使用脱水缩合剂作为催化剂，将一般式(2)表示的金刚烷化合物和一般式(3)表示的羟基烷基（甲基）丙烯酸酯化合物相互反应，得到一种表示为一般式的脂环酯化合物。
• METHOD FOR PRODUCING NOVEL ALI CYCLIC ESTER COMPOUND, NOVEL ALICYCLIC ESTER COMPOUND, (METH)ACRYLIC COPOLYMER PRODUCED BY POLYMERIZING SAID COMPOUND, AND PHOTOSENSITIVE RESIN COMPOSITION USING SAID COPOLYMER
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20160355461A1

  公开（公告）日：2016-12-08

  Provided are a resist and a compound for the resist improving the sensitivity, the resolution and the line edge roughness (LER) in a good balance without spoiling basic properties of a chemical amplification resist such as pattern shape, dry etching resistance, heat resistance and the like. Provided are a method for producing an alicyclic ester compound expressed by general formula (1), an alicyclic ester compound expressed by general formula (1), a (meth)acrylic copolymer obtained by polymerization of the alicyclic ester compound, and a photosensitive resin composition containing the (meth)acrylic copolymer. A method for producing an alicyclic ester compound expressed by general formula (1) includes reacting an adamantane compound expressed by general formula (2) with hydroxyalkylamine expressed by general formula (3) to produce an adamantaneamide compound expressed by general formula (4), and then reacting the adamantaneamide compound expressed by general formula (4) with (meth)acrylic acid.

  提供了一种抗蚀剂和化合物，用于在不破坏化学放大抗蚀剂的基本性能（如图案形状、干法蚀刻抗性、耐热性等）的情况下，平衡提高敏感性、分辨率和线边粗糙度（LER）。提供了一种制备由通式（1）表示的脂环酯化合物的方法，一种由通式（1）表示的脂环酯化合物，通过聚合脂环酯化合物得到的（甲）基丙烯酸酯共聚物，以及含有（甲）基丙烯酸酯共聚物的光敏树脂组合物。制备由通式（1）表示的脂环酯化合物的方法包括将由通式（2）表示的金刚烷化合物与由通式（3）表示的羟基烷基胺反应，生成由通式（4）表示的金刚酰胺化合物，然后将由通式（4）表示的金刚酰胺化合物与（甲）基丙烯酸反应。
• Cross-linked polymer
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0856539A1

  公开（公告）日：1998-08-05

  A cross-linked polymer containing, in its molecule, recurring units represented by the following formula (1), and having biodegradability and high water-absorbency: wherein R1 is a pendant group having at least one functional group selected from the group consisting of acidic groups and salts thereof, a glycino group and salts thereof, cationic groups and betaine groups; X1 is NH, NR1', R1' being an alkyl, aralkyl or aryl group, O or S; and n1 is 1 or 2.

  一种交联聚合物，其分子中含有下式(1)所代表的循环单元，并具有生物降解性和高吸水性： 其中，R1 是具有至少一个官能团的悬垂基团，该官能团选自由酸性基团及其盐、甘氨酸基团及其盐、阳离子基团和甜菜碱基团组成的组；X1 是 NH、NR1'，R1' 是烷基、芳烷基或芳基、O 或 S；n1 是 1 或 2。
• Production process of cross-linked polyaspartic acid resin
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0866084A2

  公开（公告）日：1998-09-23

  A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced. The process may also include one or both of the following steps as needed: (d) a gel of the cross-linked polyaspartic acid resin is washed with water and/or a water-miscible organic solvent; and (e) the polysuccinimide is produced using a basic amino acid as a cross-linking agent.

  本发明公开了一种工艺，用于生产具有生物降解性和高吸水性的交联聚天冬氨酸树脂，生产效率高。该工艺的特点是包含以下步骤之一：(a) 通过分散剂使聚琥珀酰亚胺进入分散状态，并与交联剂反应，生成交联聚天冬氨酸树脂；(b) 将交联聚琥珀酰亚胺的酰亚胺环进行水解反应，同时控制所得凝胶的溶胀度，从而生成交联聚天冬氨酸树脂；(c) 将交联剂与聚琥珀酰亚胺在有机溶剂中的溶液反应而得到的交联聚琥珀酰亚胺凝胶分解，使交联聚琥珀酰亚胺的酰亚胺环发生水解反应，从而制得交联聚天冬氨酸树脂。根据需要，该工艺还可包括以下一个或两个步骤：(d) 用水和/或水混溶有机溶剂洗涤交联聚天冬氨酸树脂的凝胶；(e) 使用碱性氨基酸作为交联剂生产聚琥珀酰亚胺。
• PROCESSES FOR PRODUCING WATER-ABSORBING RESIN
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1142925A1

  公开（公告）日：2001-10-10

  Provided are a process for the production of a cross-linked superabsorbent polymer, which has excellent water absorbency and biodegradability, by using an economical maleic acid derivative as a raw material, and a process for the production of a biodegradable, cross-linked superabsorbent polymer by simper reaction steps. A process for the production of a superabsorbent resin, which contains a cross-linked superabsorbent polymer, is also provided. This process comprises the following steps: as step 1, conducting a polymerization reaction and a cross-linking reaction concurrently at 100 to 350°C in a reaction system to produce a cross-linked polymer, and as step 2, subjecting the cross-linked polymer, which has been produced in step 1, to hydrolysis to produce the cross-linked superabsorbent polymer. The reaction system contains (A) at least one monomer selected from the group consisting of (a-1) maleic anhydride and ammonia, (a-2) a dicarboxylic acid having 4 carbon atoms and ammonia, (a-3) a monoammonium salt and/or diammonium salt of a dicarboxylic acid having 4 carbon atoms, (a-4) a monoamide and/or diamide of a dicarboxylic acid having 4 carbon atoms, and (a-5) an imide having 4 carbon atoms, (B) a cross-linking agent, and (C) an acid.

  本发明提供了一种以经济的马来酸衍生物为原料生产具有优异吸水性和生物降解性的交联超吸收聚合物的工艺，以及一种通过简单反应步骤生产可生物降解的交联超吸收聚合物的工艺。此外，还提供了一种含有交联超吸收聚合物的超吸收树脂的生产工艺。该工艺包括以下步骤：作为步骤 1，在 100 至 350°C 的反应体系中同时进行聚合反应和交联反应，生成交联聚合物；作为步骤 2，将步骤 1 中生成的交联聚合物进行水解，生成交联超吸收聚合物。反应体系包含 (A) 至少一种选自以下组别的单体 (a-1) 马来酸酐和氨；(a-2) 具有 4 个碳原子的二羧酸和氨、(a-3) 具有 4 个碳原子的二羧酸的单铵盐和/或二铵盐， (a-4) 具有 4 个碳原子的二羧酸的单酰胺和/或二酰胺，以及 (a-5) 具有 4 个碳原子的亚胺， (B) 交联剂，以及 (C) 酸。