2-(2,3-dihydro-benzothiazol-2-yl)-4-methyl-phenol | 41570-01-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2-(2,3-dihydro-benzothiazol-2-yl)-4-methyl-phenol
• 英文别名: 2-(2,3-Dihydro-1,3-benzothiazol-2-yl)-4-methylphenol
• CAS: 41570-01-8
• 化学式: C₁₄H₁₃NOS
• 分子量: 243.329
• InChiKey: IOTSIYCAGJRKRP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  57.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  5-甲基水杨醛 、 2-氨基苯硫醇 以 甲醇 为溶剂， 反应 0.25h， 生成 2-(2,3-dihydro-benzothiazol-2-yl)-4-methyl-phenol
  参考文献：
  名称：

  Fee,W.W. et al., Australian Journal of Chemistry, 1973, vol. 26, p. 675 - 680

  摘要：

  DOI：

文献信息

• METHOD FOR PREPARING 2-(2-HYDROXYPHENYL)-2H-BENZOTRIAZOLE
  申请人：LG Chem Ltd.

  公开号：EP1351944A1

  公开（公告）日：2003-10-15
• CANDLE WAX COMPOSITIONS STABILIZED WITH UV ABSORBER-METAL COMBINATIONS
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1399507A1

  公开（公告）日：2004-03-24
• [EN] METHOD FOR PREPARING 2-(2-HYDROXYPHENYL)-2H-BENZOTRIAZOLE<br/>[FR] PROCEDE POUR PREPARER DU 2-(2-HYDROXYPHENYL)-2H-BENZOTRIAZOLE
  申请人：LG CHEMICAL LTD

  公开号：WO2002055508A1

  公开（公告）日：2002-07-18

  This invention provides a method for preparing 2-(2-hydroxyphenyl)-2H-benzotriazole of formula (I) below, consisting of steps of: a) performing a first reduction in which hydrazine hydrate is added to a compound of formula (II) below with or without a phase transition catalyst in the presence of solvents which include a nonpolar solvent, water, and an alkaline compound, thereby preparing a compound of formula (III) below; and b) performing a second reduction in which water is added to the compound of formula (III) prepared in step a), and then zinc powder and sulfuric acid are added thereto with or without the phase transition catalyst, wherein, X is halogen or hydrogen; R is hydrogen, C1-C12 alkyl, C5-C8 cycloalkyl, phenyl, or phenyl-C1-C4 alkyl; and R' is C1-C12 alkyl, C5-C8 cycloalkyl, phenyl, or phenyl-C1-C4 alkyl.
• [EN] CANDLE WAX COMPOSITIONS STABILIZED WITH UV ABSORBER-METAL COMBINATIONS<br/>[FR] COMPOSITIONS POUR CIRE DE BOUGIE STABILISEES AVEC DES COMBINAISONS DE METAUX ABSORBEURS D'UV
  申请人：CIBA SC HOLDING AG

  公开号：WO2002098968A1

  公开（公告）日：2002-12-12

  Dyes and pigments present in candle wax compositions are particularly well stabilized against color fade or color change by a combination of a UV absorber and a metal compound, particularly a tin compound. The further addition of a hindered amine or antioxidant is highly beneficial.