1,4-dioxo-3,6-bis-[2,2';5',2"]terthiophen-5-yl-pyrrolo[3,4-c]pyrrole-2,5-dicarboxylic acid di-tert-butyl ester | 1383956-08-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 1,4-dioxo-3,6-bis-[2,2';5',2"]terthiophen-5-yl-pyrrolo[3,4-c]pyrrole-2,5-dicarboxylic acid di-tert-butyl ester
• 英文别名: Ditert-butyl 1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-4-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrole-2,5-dicarboxylate；ditert-butyl 1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-4-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrole-2,5-dicarboxylate
• CAS: 1383956-08-8
• 化学式: C₈₀H₁₁₂N₂O₆S₆
• 分子量: 1390.18
• InChiKey: ZJKXDOCDKOMDRP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  28.3
• 重原子数：
  94
• 可旋转键数：
  46
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  235
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,4-dioxo-3,6-bis-[2,2';5',2"]terthiophen-5-yl-pyrrolo[3,4-c]pyrrole-2,5-dicarboxylic acid di-tert-butyl ester 反应 0.5h， 生成 1,4-Bis[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]pyrrolo[3,4-c]pyrrole-3,6-diol
  参考文献：
  名称：

  Ambipolar Behavior of Hydrogen-Bonded Diketopyrrolopyrrole–Thiophene Co-oligomers Formed from Their Soluble Precursors

  摘要：

  Organic field-effect transistors with hydrogen-bonded diketopyrrolopyrrole-thiophene co-oligomers were fabricated by a solution-process method with annealing at 200 degrees C, showing ambipolar charge-carrier transfer with field-effect mobilities up to mu(h) = 6.7 x 10(-3) cm(2) V-1 s(-1) mu(o). = 5.6 x 10(-3) cm(2) V-1 s(-1).

  DOI：

  10.1021/ol3013364
• 作为产物：
  描述：

  3,6-双（5-溴噻吩-2-基）-1,4-二氧杂吡咯并[3,4-c]吡咯二叔丁基-2,5（1H，4H）-二羧酸二叔丁基酯 、 tributyl(5'-(2-octyldodecyl)-[2,2'-bithiophen]-5-yl)stannane 在 bis-triphenylphosphine-palladium(II) chloride 作用下， 以 1,4-二氧六环 为溶剂， 反应 4.0h， 以41%的产率得到1,4-dioxo-3,6-bis-[2,2';5',2"]terthiophen-5-yl-pyrrolo[3,4-c]pyrrole-2,5-dicarboxylic acid di-tert-butyl ester
  参考文献：
  名称：

  Ambipolar Behavior of Hydrogen-Bonded Diketopyrrolopyrrole–Thiophene Co-oligomers Formed from Their Soluble Precursors

  摘要：

  Organic field-effect transistors with hydrogen-bonded diketopyrrolopyrrole-thiophene co-oligomers were fabricated by a solution-process method with annealing at 200 degrees C, showing ambipolar charge-carrier transfer with field-effect mobilities up to mu(h) = 6.7 x 10(-3) cm(2) V-1 s(-1) mu(o). = 5.6 x 10(-3) cm(2) V-1 s(-1).

  DOI：

  10.1021/ol3013364

文献信息

• Ambipolar Behavior of Hydrogen-Bonded Diketopyrrolopyrrole–Thiophene Co-oligomers Formed from Their Soluble Precursors
  作者：Yuki Suna、Jun-ichi Nishida、Yoshihide Fujisaki、Yoshiro Yamashita

  DOI：10.1021/ol3013364

  日期：2012.7.6

  Organic field-effect transistors with hydrogen-bonded diketopyrrolopyrrole-thiophene co-oligomers were fabricated by a solution-process method with annealing at 200 degrees C, showing ambipolar charge-carrier transfer with field-effect mobilities up to mu(h) = 6.7 x 10(-3) cm(2) V-1 s(-1) mu(o). = 5.6 x 10(-3) cm(2) V-1 s(-1).