Ditert-butyl 4-[5-[5-[2,5-bis[(2-methylpropan-2-yl)oxycarbonyl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrol-4-yl]thiophen-2-yl]thiophen-2-yl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrole-2,5-dicarboxylate | 1383956-09-9

分子结构分类

有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩

中文名称

——

中文别名

——

英文名称

Ditert-butyl 4-[5-[5-[2,5-bis[(2-methylpropan-2-yl)oxycarbonyl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrol-4-yl]thiophen-2-yl]thiophen-2-yl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrole-2,5-dicarboxylate

英文别名

ditert-butyl 4-[5-[5-[2,5-bis[(2-methylpropan-2-yl)oxycarbonyl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrol-4-yl]thiophen-2-yl]thiophen-2-yl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrole-2,5-dicarboxylate

CAS

1383956-09-9

化学式

C₁₀₄H₁₃₄N₄O₁₂S₈

mdl

——

分子量

1888.76

InChiKey

AFYPABUUVPWVNL-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

32.1
重原子数：

128
可旋转键数：

53
环数：

12.0
sp3杂化的碳原子比例：

0.54
拓扑面积：

385
氢给体数：

0
氢受体数：

20

上下游信息

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	4-[5-[5-[3,6-Dihydroxy-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]pyrrolo[3,4-c]pyrrol-4-yl]thiophen-2-yl]thiophen-2-yl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]pyrrolo[3,4-c]pyrrole-3,6-diol	1383956-11-3	C₈₄H₁₀₂N₄O₄S₈	1488.29

反应信息

作为反应物：

描述：

Ditert-butyl 4-[5-[5-[2,5-bis[(2-methylpropan-2-yl)oxycarbonyl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrol-4-yl]thiophen-2-yl]thiophen-2-yl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrole-2,5-dicarboxylate 反应 0.5h，生成 4-[5-[5-[3,6-Dihydroxy-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]pyrrolo[3,4-c]pyrrol-4-yl]thiophen-2-yl]thiophen-2-yl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]pyrrolo[3,4-c]pyrrole-3,6-diol

参考文献：

名称：

Ambipolar Behavior of Hydrogen-Bonded Diketopyrrolopyrrole–Thiophene Co-oligomers Formed from Their Soluble Precursors

摘要：

Organic field-effect transistors with hydrogen-bonded diketopyrrolopyrrole-thiophene co-oligomers were fabricated by a solution-process method with annealing at 200 degrees C, showing ambipolar charge-carrier transfer with field-effect mobilities up to mu(h) = 6.7 x 10(-3) cm(2) V-1 s(-1) mu(o). = 5.6 x 10(-3) cm(2) V-1 s(-1).

DOI：

10.1021/ol3013364
作为产物：

描述：

tributyl(5'-(2-octyldodecyl)-[2,2'-bithiophen]-5-yl)stannane 、在 bis-triphenylphosphine-palladium(II) chloride 作用下，以 1,4-二氧六环为溶剂，反应 4.0h，以73%的产率得到Ditert-butyl 4-[5-[5-[2,5-bis[(2-methylpropan-2-yl)oxycarbonyl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrol-4-yl]thiophen-2-yl]thiophen-2-yl]-1-[5-[5-[5-(2-octyldodecyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3,6-dioxopyrrolo[3,4-c]pyrrole-2,5-dicarboxylate

参考文献：

名称：

Ambipolar Behavior of Hydrogen-Bonded Diketopyrrolopyrrole–Thiophene Co-oligomers Formed from Their Soluble Precursors

摘要：

Organic field-effect transistors with hydrogen-bonded diketopyrrolopyrrole-thiophene co-oligomers were fabricated by a solution-process method with annealing at 200 degrees C, showing ambipolar charge-carrier transfer with field-effect mobilities up to mu(h) = 6.7 x 10(-3) cm(2) V-1 s(-1) mu(o). = 5.6 x 10(-3) cm(2) V-1 s(-1).

DOI：

10.1021/ol3013364

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文献信息

Ambipolar Behavior of Hydrogen-Bonded Diketopyrrolopyrrole–Thiophene Co-oligomers Formed from Their Soluble Precursors

作者：Yuki Suna、Jun-ichi Nishida、Yoshihide Fujisaki、Yoshiro Yamashita

DOI：10.1021/ol3013364

日期：2012.7.6

Organic field-effect transistors with hydrogen-bonded diketopyrrolopyrrole-thiophene co-oligomers were fabricated by a solution-process method with annealing at 200 degrees C, showing ambipolar charge-carrier transfer with field-effect mobilities up to mu(h) = 6.7 x 10(-3) cm(2) V-1 s(-1) mu(o). = 5.6 x 10(-3) cm(2) V-1 s(-1).

同类化合物

试剂2,2'-Thieno[3,2-b]thiophene-2,5-diylbis-3-thiophenecarboxylicacid 苯并[b]噻吩,3-(2-噻嗯基)- 甲基[2,3'-联噻吩]-5-羧酸甲酯牛蒡子醇 B 十四氟-Alpha-六噻吩三丁基(5''-己基-[2,2':5',2''-三联噻吩]-5-基)锡 α-四联噻吩 α-六噻吩 α-五联噻吩 α-七噻吩 α,ω-二己基四噻吩 5,5′-双(3-己基-2-噻吩基)-2,2′-联噻吩 α,ω-二己基六联噻吩 Α-八噻吩 alpha-三联噻吩甲醇 alpha-三联噻吩 [3,3-Bi噻吩]-2,2-二羧醛 [2,2’]-双噻吩-5,5‘-二甲醛 [2,2':5',2''-三联噻吩]-5,5''-二基双[三甲基硅烷] [2,2'-联噻吩]-5-甲醇,5'-(1-丙炔-1-基)- [2,2'-联噻吩]-5-甲酸甲酯 [2,2'-联噻吩]-5-乙酸,a-羟基-5'-(1-炔丙基)-(9CI) C-[2,2-二硫代苯-5-基甲基]胺 5’-己基-2,2’-联噻吩-5-硼酸频哪醇酯 5-辛基-1,3-二（噻吩-2-基）-4H-噻吩并[3,4-c]吡咯-4,6（5H）-二酮 5-苯基-2,2'-联噻吩 5-溴5'-辛基-2,2'-联噻吩 5-溴-5′-己基-2,2′-联噻吩 5-溴-5'-甲酰基-2,2':5'2'-三噻吩 5-溴-3,3'-二己基-2,2'-联噻吩 5-溴-3'-癸基-2,2':5',2''-三联噻吩 5-溴-2,2-双噻吩 5-溴-2,2'-联噻吩-5'-甲醛 5-氯-5'-苯基-2,2'-联噻吩 5-氯-2,2'-联噻吩 5-正辛基-2,2'-并噻吩 5-己基-5'-乙烯基-2,2'-联噻吩 5-己基-2,2-二噻吩 5-全氟己基-5'-溴-2,2'-二噻吩 5-全氟己基-2,2′-联噻吩 5-乙酰基-2,2-噻吩基 5-乙氧基-2,2'-联噻吩 5-丙酰基-2,2-二噻吩 5-{[[2,2'-联噻吩]-5-基}噻吩-2-腈 5-[5-(5-己基噻吩-2-基)噻吩-2-基]噻吩-2-羧酸 5-(羟甲基)-[2,2]-联噻吩 5-(噻吩-2-基)噻吩-2-甲腈 5-(5-甲酰基-3-己基噻吩-2-基)-4-己基噻吩-2-甲醛 5-(5-甲基噻吩-2-基)噻吩-2-甲醛 5-(5-噻吩-2-基噻吩-2-基)噻吩-2-羧酸 5-(5-乙炔基噻吩-2-基)噻吩-2-甲醛