2,7-Bis[7-(9,9-dioctylfluoren-2-yl)-9,9-dioctylfluoren-2-yl]-9,9-bis(2-ethylhexyl)fluorene | 1263093-70-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2,7-Bis[7-(9,9-dioctylfluoren-2-yl)-9,9-dioctylfluoren-2-yl]-9,9-bis(2-ethylhexyl)fluorene
• 英文别名: 2,7-bis[7-(9,9-dioctylfluoren-2-yl)-9,9-dioctylfluoren-2-yl]-9,9-bis(2-ethylhexyl)fluorene
• CAS: 1263093-70-4
• 化学式: C₁₄₅H₂₀₂
• 分子量: 1945.2
• InChiKey: YYNHZMGNNLLULN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  58.3
• 重原子数：
  145
• 可旋转键数：
  72
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  [9,9-二(2-乙基己基)-9H-芴-2,7-二基]二硼酸 、 7-bromo-9,9,9',9'-tetraoctyl-9H,9'H-2,2'-bifluorene 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 甲苯 为溶剂， 以71%的产率得到2,7-Bis[7-(9,9-dioctylfluoren-2-yl)-9,9-dioctylfluoren-2-yl]-9,9-bis(2-ethylhexyl)fluorene
  参考文献：
  名称：

  Oligofluorene blue emitters for cholesteric liquid crystal lasers

  摘要：

  We present the synthesis and characterization of an oligofluorene series whose chemical structure has been tuned to have amorphous nature, compatibility with liquid crystalline matrices and intrinsic chirality. Oligofluorenes are good blue emitters and the emission quantum yield is around 0.8 in the violet-blue range. The prepared materials are suitable for mirror-less laser applications based on a dye-doped liquid crystal resonator. We propose to use fluorene-based compounds to combine two necessary properties to achieve laser emission from cholesteric liquid crystal mixtures: chirality and luminescence. A good intensity emission and a fine tuning of the laser emission are demonstrated. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2010.01.006

文献信息

• Oligofluorene blue emitters for cholesteric liquid crystal lasers
  作者：L.S. Chinelatto、J. del Barrio、M. Piñol、L. Oriol、M.A. Matranga、M.P. De Santo、R. Barberi

  DOI：10.1016/j.jphotochem.2010.01.006

  日期：2010.2

  We present the synthesis and characterization of an oligofluorene series whose chemical structure has been tuned to have amorphous nature, compatibility with liquid crystalline matrices and intrinsic chirality. Oligofluorenes are good blue emitters and the emission quantum yield is around 0.8 in the violet-blue range. The prepared materials are suitable for mirror-less laser applications based on a dye-doped liquid crystal resonator. We propose to use fluorene-based compounds to combine two necessary properties to achieve laser emission from cholesteric liquid crystal mixtures: chirality and luminescence. A good intensity emission and a fine tuning of the laser emission are demonstrated. (C) 2010 Elsevier B.V. All rights reserved.