(Z)-3-(4-Hydroxy-3-methoxy-phenyl)-2-(4-nitro-phenyl)-acrylic acid

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (Z)-3-(4-Hydroxy-3-methoxy-phenyl)-2-(4-nitro-phenyl)-acrylic acid
• 英文别名: (Z)-3-(4-hydroxy-3-methoxyphenyl)-2-(4-nitrophenyl)prop-2-enoic acid
• 化学式: C₁₆H₁₃NO₆
• 分子量: 315.282
• InChiKey: DMJCQCBPKCADBV-JYRVWZFOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  113
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (Z)-3-(4-Hydroxy-3-methoxy-phenyl)-2-(4-nitro-phenyl)-acrylic acid 在 哌啶 作用下， 生成 2-methoxy-4-[(1E)-2-(4-nitrophenyl)ethenyl]phenol
  参考文献：
  名称：

  Photo-patterning of the quadratic optical properties of doped photopolymers

  摘要：

  We present ail original approach to structure the quadratic non-linear optical properties of doped polymers based on photopolymerizable resins. The orientation of the push-pull molecules incorporated in the material is locked by the polymerization process induced by an exposure to a visible light. The freeze of the orientation was investigated through second harmonic generation and infrared spectroscopy measurements. A mean relaxation time of over 4200 h was obtained with co-polymerizable chromophores. With the purely optical method we developed, one can durably photo-pattern the quadratic optical properties of photopolymers for applications in integrated optics. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2003.07.005
• 作为产物：
  描述：

  对硝基苯乙酸 、 香草醛 以 N,N-二甲基甲酰胺 为溶剂， 生成 (Z)-3-(4-Hydroxy-3-methoxy-phenyl)-2-(4-nitro-phenyl)-acrylic acid
  参考文献：
  名称：

  Photo-patterning of the quadratic optical properties of doped photopolymers

  摘要：

  We present ail original approach to structure the quadratic non-linear optical properties of doped polymers based on photopolymerizable resins. The orientation of the push-pull molecules incorporated in the material is locked by the polymerization process induced by an exposure to a visible light. The freeze of the orientation was investigated through second harmonic generation and infrared spectroscopy measurements. A mean relaxation time of over 4200 h was obtained with co-polymerizable chromophores. With the purely optical method we developed, one can durably photo-pattern the quadratic optical properties of photopolymers for applications in integrated optics. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2003.07.005

文献信息

• Photo-patterning of the quadratic optical properties of doped photopolymers
  作者：Fabrice Gillot、Loı̈c Mager、K.D Dorkenoo、Stéphane Méry、Christiane Carré、Alain Fort

  DOI：10.1016/j.cplett.2003.07.005

  日期：2003.9

  We present ail original approach to structure the quadratic non-linear optical properties of doped polymers based on photopolymerizable resins. The orientation of the push-pull molecules incorporated in the material is locked by the polymerization process induced by an exposure to a visible light. The freeze of the orientation was investigated through second harmonic generation and infrared spectroscopy measurements. A mean relaxation time of over 4200 h was obtained with co-polymerizable chromophores. With the purely optical method we developed, one can durably photo-pattern the quadratic optical properties of photopolymers for applications in integrated optics. (C) 2003 Elsevier B.V. All rights reserved.