2-amino-6-methyl-4-(3H)-oxopyrido<2,3-d>pyrimidine | 49739-04-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶并嘧啶类
• 英文名称: 2-amino-6-methyl-4-(3H)-oxopyrido<2,3-d>pyrimidine
• 英文别名: 6-Methyl-5-deazapterin；2-amino-6-methyl-3H-pyrido[2,3-d]pyrimidin-4-one；2-Amino-6-methylpyrido[2,3-d]pyrimidin-4(1h)-one；2-amino-6-methyl-3H-pyrido[2,3-d]pyrimidin-4-one
• CAS: 49739-04-0
• 化学式: C₈H₈N₄O
• 分子量: 176.178
• InChiKey: JEXWSTFWNVLWCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  80.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-amino-6-methyl-4-(3H)-oxopyrido<2,3-d>pyrimidine 在 sodium hydroxide 、 potassium permanganate 作用下， 以29%的产率得到(9CI)-2-氨基-1,4-二氢-4-氧代吡啶并[2,3-d]嘧啶-6-羧酸
  参考文献：
  名称：

  Pyrido[2,3-d]pyrimidines. The synthesis of the 5-deaza analogs of aminopterin, methotrexate, folic acid, and N10-methylfolic acid

  摘要：

  DOI：

  10.1021/jo00344a002
• 作为产物：
  描述：

  2-氨基-5-甲基吡啶-3-羧酸乙酯 、 胍 生成 2-amino-6-methyl-4-(3H)-oxopyrido<2,3-d>pyrimidine
  参考文献：
  名称：

  DEGRAW, J. I.;TAGAWA, HIROAKI, J. HETEROCYCL. CHEM., 1982, 19, N 6, 1461-1463

  摘要：

  DOI：

文献信息

• Work function-controlled carbon nanomaterial and metal nanowire hybrid transparent conductive film and method for manufacturing same
  申请人：KOREA ELECTROTECHNOLOGY RESEARCH INSTITUTE

  公开号：US10100209B2

  公开（公告）日：2018-10-16

  Disclosed is a method of manufacturing a work function-controlled carbon nanomaterial and metal nanowire hybrid transparent conductive film, including: a first step of modifying the surface of a carbon nanomaterial to introduce a functional group to a conductive carbon nanomaterial; a second step of forming a work function-reduced carbon nanomaterial dispersed solution by mixing and reacting the carbon nanomaterial, which is functionalized in the first step, with an isocyanate-based compound and a pyrimidine-based compound; a third step of forming a single-component coating solution by hybridizing the work function-reduced carbon nanomaterial dispersed solution obtained in the second step with a metal nanowire; and a fourth step of forming a film by applying the coating solution, which is formed in the third step, on a substrate.

  公开了一种制造功函数控制的碳纳米材料和金属纳米线混合透明导电薄膜的方法，包括：第一步，对碳纳米材料的表面进行改性，为导电碳纳米材料引入官能团； 第二步，将在第一步中被官能化的碳纳米材料与异氰酸酯基化合物和嘧啶基化合物混合并反应，形成功函数降低的碳纳米材料分散溶液；第三步：将第二步中得到的功函数还原碳纳米材料分散溶液与金属纳米线杂化，形成单组分涂层溶液；第四步：将第三步中形成的涂层溶液涂覆在基底上，形成薄膜。
• Nanometal-nanocarbon hybrid material and method of manufacturing the same
  申请人：KOREA ELECTROTECHNOLOGY RESEARCH INSTITUTE

  公开号：US10184059B2

  公开（公告）日：2019-01-22

  Disclosed are a nanometal-nanocarbon hybrid material and a method of manufacturing the same, the method including modifying the surface of nanocarbon to introduce a functional group to conductive nanocarbon; mixing the surface-modified nanocarbon with an isocyanate-based compound and a pyrimidine-based compound and allowing them to react, thus forming a nanocarbon dispersion reactive to metal ions; adding the nanocarbon dispersion with a metal salt precursor, a reducing agent and a solvent, thus manufacturing nanometal particles; and separating a hybrid of the nanometal particles having the nanocarbon bound thereto. Thereby, nanocarbon is mixed with an isocyanate-based compound and a pyrimidine-based compound and then allowed to react, whereby the nanocarbon reactive with metal ions is used as an additive, thus obtaining a nanometal having a low-dimensional shape having less than three dimensions. Also, a nanometal can be hybridized with nanocarbon simultaneously with the formation of the nanometal, and solvent dispersibility is ensured by a functional group formed by mixing and reacting an isocyanate-based compound and a pyrimidine-based compound, ultimately facilitating the preparation of conductive ink or paste.

  本发明公开了一种纳米金属-纳米碳杂化材料及其制造方法，该方法包括改性纳米碳表面，为导电纳米碳引入官能团；将表面改性的纳米碳与异氰酸酯基化合物和嘧啶基化合物混合并使其反应，从而形成对金属离子起反应的纳米碳分散体；在纳米碳分散液中加入金属盐前体、还原剂和溶剂，从而制造出纳米金属颗粒；分离出纳米金属颗粒的混合物，该混合物中结合有纳米碳。通过这种方法，将纳米碳与异氰酸酯基化合物和嘧啶基化合物混合，然后进行反应，将与金属离子反应的纳米碳用作添加剂，从而获得具有小于三维的低维形状的纳米金属。此外，在形成纳米金属的同时，还可将纳米碳与纳米金属杂化，并通过异氰酸酯基化合物和嘧啶基化合物混合反应形成的官能团确保溶剂分散性，最终促进导电墨水或浆料的制备。
• Conductive fiber comprising metal nanobelt and carbon nanomaterial composite, method for producing conductive fiber, fibrous strain sensor, and method for producing fibrous strain sensor
  申请人：Korea Electrotechnology Research Institute

  公开号：US11137242B2

  公开（公告）日：2021-10-05

  A conductive fiber including a metal-nanobelt-carbon-nanomaterial composite. A manufacturing method thereof includes preparing a composite including a carbon nanomaterial and metal nanobelts and manufacturing a conductive fiber by mixing the composite with a polymer. A fibrous strain sensor and a manufacturing method thereof are also provided. Thereby, a conductive fiber including a metal-nanobelt-carbon-nanomaterial composite, which is able to increase conductivity of the conductive fiber through synthesis of metal nanobelts enabling area contact and to exhibit good contact between the carbon nanomaterial and the metal nanobelts due to formation of the metal nanobelts on the surface of the carbon nanomaterial and superior dispersion uniformity, and a fibrous strain sensor including the conductive fiber can be obtained. The conductive fiber can be effectively applied to a strain sensor based on a principle by which resistance drastically increases with an increase in a distance between metal nanobelts aligned in a fiber direction upon tensile strain of metal nanobelts enabling area contact.

  一种导电纤维，包括金属纳米带-碳纳米材料复合材料。其制造方法包括制备包括碳纳米材料和金属纳米带的复合材料，并通过将该复合材料与聚合物混合制造导电纤维。此外，还提供了一种纤维状应变传感器及其制造方法。由此，可以获得一种包括金属纳米带-碳纳米材料复合材料的导电纤维，该导电纤维能够通过合成金属纳米颗粒增加导电率，使导电纤维能够实现区域接触，并且由于金属纳米颗粒在碳纳米材料表面的形成和优异的分散均匀性，碳纳米材料和金属纳米颗粒之间能够实现良好接触，还可以获得一种包括该导电纤维的纤维状应变传感器。该导电纤维可有效地应用于应变传感器，其原理是当金属纳米颗粒产生拉伸应变时，在纤维方向上排列的金属纳米颗粒之间的距离增加，电阻会急剧增加，从而实现区域接触。
• TEMPLE, C. ,, JR;ELLIOTT, R. D.;MONTGOMERY, J. A., J. ORG. CHEM., 1982, 47, N 5, 761-764
  作者：TEMPLE, C. ,, JR、ELLIOTT, R. D.、MONTGOMERY, J. A.

  DOI：——

  日期：——
• TEMPLE, C. G.;MONTGOMERY, J. A.;ELLIOTT, R. D.
  作者：TEMPLE, C. G.、MONTGOMERY, J. A.、ELLIOTT, R. D.

  DOI：——

  日期：——